Nanographenes as electron-deficient cores of donor-acceptor systems View Full Text


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Article Info

DATE

2018-12

AUTHORS

Yu-Min Liu, Hao Hou, Yan-Zhen Zhou, Xin-Jing Zhao, Chun Tang, Yuan-Zhi Tan, Klaus Müllen

ABSTRACT

Conjugation of nanographenes (NGs) with electro-active molecules can establish donor-acceptor π-systems in which the former generally serve as the electron-donating moieties due to their electronic-rich nature. In contrast, here we report a series of reversed donor-acceptor structures are obtained by C-N coupling of electron-deficient perchlorinated NGs with electron-rich anilines. Selective amination at the vertexes of the NGs is unambiguously shown through X-ray crystallography. By varying the donating ability of the anilino groups, the optical and assembly properties of donor-acceptor NGs can be finely modulated. The electron-deficient concave core of the resulting conjugates can host electron-rich guest molecules by intermolecular donor-acceptor interactions and gives rise to charge-transfer supramolecular architectures. More... »

PAGES

1901

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/s41467-018-04321-6

DOI

http://dx.doi.org/10.1038/s41467-018-04321-6

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1103911318

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/29765041


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51 schema:description Conjugation of nanographenes (NGs) with electro-active molecules can establish donor-acceptor π-systems in which the former generally serve as the electron-donating moieties due to their electronic-rich nature. In contrast, here we report a series of reversed donor-acceptor structures are obtained by C-N coupling of electron-deficient perchlorinated NGs with electron-rich anilines. Selective amination at the vertexes of the NGs is unambiguously shown through X-ray crystallography. By varying the donating ability of the anilino groups, the optical and assembly properties of donor-acceptor NGs can be finely modulated. The electron-deficient concave core of the resulting conjugates can host electron-rich guest molecules by intermolecular donor-acceptor interactions and gives rise to charge-transfer supramolecular architectures.
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