Ontology type: schema:ScholarlyArticle Open Access: True
2017-12
AUTHORSBenedict M. Gardner, Christos E. Kefalidis, Erli Lu, Dipti Patel, Eric J. L. McInnes, Floriana Tuna, Ashley J. Wooles, Laurent Maron, Stephen T. Liddle
ABSTRACTReversible single-metal two-electron oxidative addition and reductive elimination are common fundamental reactions for transition metals that underpin major catalytic transformations. However, these reactions have never been observed together in the f-block because these metals exhibit irreversible one- or multi-electron oxidation or reduction reactions. Here we report that azobenzene oxidises sterically and electronically unsaturated uranium(III) complexes to afford a uranium(V)-imido complex in a reaction that satisfies all criteria of a single-metal two-electron oxidative addition. Thermolysis of this complex promotes extrusion of azobenzene, where H-/D-isotopic labelling finds no isotopomer cross-over and the non-reactivity of a nitrene-trap suggests that nitrenes are not generated and thus a reductive elimination has occurred. Though not optimally balanced in this case, this work presents evidence that classical d-block redox chemistry can be performed reversibly by f-block metals, and that uranium can thus mimic elementary transition metal reactivity, which may lead to the discovery of new f-block catalysis. More... »
PAGES1898
http://scigraph.springernature.com/pub.10.1038/s41467-017-01363-0
DOIhttp://dx.doi.org/10.1038/s41467-017-01363-0
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1093031862
PUBMEDhttps://www.ncbi.nlm.nih.gov/pubmed/29196691
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Inorganic Chemistry",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "University of Manchester",
"id": "https://www.grid.ac/institutes/grid.5379.8",
"name": [
"School of Chemistry, The University of Manchester, Oxford Road, M13 9PL, Manchester, UK"
],
"type": "Organization"
},
"familyName": "Gardner",
"givenName": "Benedict M.",
"id": "sg:person.01003637471.40",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01003637471.40"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Laboratoire de Physique et Chimie des Nano-Objets",
"id": "https://www.grid.ac/institutes/grid.462768.9",
"name": [
"LPCNO, CNRS & INSA, Universit\u00e9 Paul Sabatier, 135 Avenue de Rangueil, 31077, Toulouse, France"
],
"type": "Organization"
},
"familyName": "Kefalidis",
"givenName": "Christos E.",
"id": "sg:person.01240452511.54",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01240452511.54"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "University of Manchester",
"id": "https://www.grid.ac/institutes/grid.5379.8",
"name": [
"School of Chemistry, The University of Manchester, Oxford Road, M13 9PL, Manchester, UK"
],
"type": "Organization"
},
"familyName": "Lu",
"givenName": "Erli",
"id": "sg:person.01365043574.13",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01365043574.13"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "University of Nottingham",
"id": "https://www.grid.ac/institutes/grid.4563.4",
"name": [
"School of Chemistry, University of Nottingham, University Park, NG7 2RD, Nottingham, UK"
],
"type": "Organization"
},
"familyName": "Patel",
"givenName": "Dipti",
"id": "sg:person.01244542505.51",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01244542505.51"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "University of Manchester",
"id": "https://www.grid.ac/institutes/grid.5379.8",
"name": [
"EPSRC National UK EPR Facility, School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, M13 9PL, Manchester, UK"
],
"type": "Organization"
},
"familyName": "McInnes",
"givenName": "Eric J. L.",
"id": "sg:person.015541514657.63",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015541514657.63"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "University of Manchester",
"id": "https://www.grid.ac/institutes/grid.5379.8",
"name": [
"EPSRC National UK EPR Facility, School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, M13 9PL, Manchester, UK"
],
"type": "Organization"
},
"familyName": "Tuna",
"givenName": "Floriana",
"id": "sg:person.0750046556.15",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0750046556.15"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "University of Manchester",
"id": "https://www.grid.ac/institutes/grid.5379.8",
"name": [
"School of Chemistry, The University of Manchester, Oxford Road, M13 9PL, Manchester, UK"
],
"type": "Organization"
},
"familyName": "Wooles",
"givenName": "Ashley J.",
"id": "sg:person.0627703471.90",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0627703471.90"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Laboratoire de Physique et Chimie des Nano-Objets",
"id": "https://www.grid.ac/institutes/grid.462768.9",
"name": [
"LPCNO, CNRS & INSA, Universit\u00e9 Paul Sabatier, 135 Avenue de Rangueil, 31077, Toulouse, France"
],
"type": "Organization"
},
"familyName": "Maron",
"givenName": "Laurent",
"id": "sg:person.01170107561.43",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01170107561.43"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "University of Manchester",
"id": "https://www.grid.ac/institutes/grid.5379.8",
"name": [
"School of Chemistry, The University of Manchester, Oxford Road, M13 9PL, Manchester, UK"
],
"type": "Organization"
},
"familyName": "Liddle",
"givenName": "Stephen T.",
"id": "sg:person.0701217443.37",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0701217443.37"
],
"type": "Person"
}
],
"citation": [
{
"id": "https://doi.org/10.1039/b513755c",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1001117397"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1039/b513755c",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1001117397"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1039/c5cc07140b",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1002224850"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1073/pnas.1203417109",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1004980414"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/om900088z",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1005888656"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/(sici)1521-3773(19980420)37:7<959::aid-anie959>3.0.co;2-d",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1007057610"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1126/science.1223488",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1008287423"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/nchem.2009",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1008868796",
"https://doi.org/10.1038/nchem.2009"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1039/c2cc37193f",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1009296705"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/anie.201104110",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1013778566"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1039/b108584k",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1014274217"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/anie.201405031",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1017721283"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0022-328x(93)80193-f",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1017946921"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0022-328x(93)80193-f",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1017946921"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/s0277-5387(97)00244-1",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1018628184"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1039/b922507b",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1020183286"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1039/b922507b",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1020183286"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/nchem.1642",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1021720433",
"https://doi.org/10.1038/nchem.1642"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/s0020-1693(00)90225-1",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1022904940"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/nature16530",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1024258315",
"https://doi.org/10.1038/nature16530"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/jacs.6b00710",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1025224758"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.ccr.2006.01.017",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1025352993"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.ccr.2004.02.018",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1027467330"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1039/b508612d",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1029987505"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1039/b508612d",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1029987505"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/nature07372",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1031311554",
"https://doi.org/10.1038/nature07372"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/ejic.200400133",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1031549077"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/anie.201412168",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1032069524"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/ncomms3323",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1032524255",
"https://doi.org/10.1038/ncomms3323"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1039/c5dt00608b",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1035245938"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1039/c39810000232",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1036307762"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1039/c4cc03355h",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1036768877"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ja103988d",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1037485329"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ja103988d",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1037485329"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0022-328x(90)85163-s",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1038416041"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1039/c6dt02698b",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1038683626"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1107/s2052520616003954",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1039303532"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/nchem.1028",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1040056200",
"https://doi.org/10.1038/nchem.1028"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf00699181",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1045143394",
"https://doi.org/10.1007/bf00699181"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf00699181",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1045143394",
"https://doi.org/10.1007/bf00699181"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/chem.201503133",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1046116863"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/chem.201602505",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1046371783"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.ccr.2007.10.023",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1046440017"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1039/c5sc01561h",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1050466299"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1039/j19710001931",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1050974468"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1039/c5cs00907c",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1051300296"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/cr60261a004",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1053766471"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/cr010298r",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1053799912"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/cr010298r",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1053799912"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/acs.inorgchem.6b01488",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055094195"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/acs.inorgchem.6b01922",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055094419"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/acs.organomet.5b00565",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055122721"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/acs.organomet.5b00884",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055122864"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ar50035a004",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055150766"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ic00088a030",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055541732"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ic2002805",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055562025"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ic2002805",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055562025"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ic202163m",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055563099"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ic4009812",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055565388"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ic901581r",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055584939"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ic901581r",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055584939"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ja00223a016",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055715550"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ja00359a023",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055726257"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ja00397a065",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055729244"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ja00412a021",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055730465"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ja106902s",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055848318"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ja106902s",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055848318"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ja209524u",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055851296"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ja5038337",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055856454"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ja504528n",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055856515"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ja805107v",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055859103"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ja805107v",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055859103"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ja900880z",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055860724"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ja900880z",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055860724"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ja9844581",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055871371"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ja994484e",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055873516"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ja994484e",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055873516"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/jacs.6b06989",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055875982"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/jacs.6b06989",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055875982"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/om00061a028",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056265694"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/om060963s",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056275321"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/om200970s",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056277203"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/om301016j",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056278155"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/om7003139",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056280213"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/om950756k",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056282816"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/om990019e",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056285622"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1126/science.1141474",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1062455961"
],
"type": "CreativeWork"
}
],
"datePublished": "2017-12",
"datePublishedReg": "2017-12-01",
"description": "Reversible single-metal two-electron oxidative addition and reductive elimination are common fundamental reactions for transition metals that underpin major catalytic transformations. However, these reactions have never been observed together in the f-block because these metals exhibit irreversible one- or multi-electron oxidation or reduction reactions. Here we report that azobenzene oxidises sterically and electronically unsaturated uranium(III) complexes to afford a uranium(V)-imido complex in a reaction that satisfies all criteria of a single-metal two-electron oxidative addition. Thermolysis of this complex promotes extrusion of azobenzene, where H-/D-isotopic labelling finds no isotopomer cross-over and the non-reactivity of a nitrene-trap suggests that nitrenes are not generated and thus a reductive elimination has occurred. Though not optimally balanced in this case, this work presents evidence that classical d-block redox chemistry can be performed reversibly by f-block metals, and that uranium can thus mimic elementary transition metal reactivity, which may lead to the discovery of new f-block catalysis.",
"genre": "research_article",
"id": "sg:pub.10.1038/s41467-017-01363-0",
"inLanguage": [
"en"
],
"isAccessibleForFree": true,
"isFundedItemOf": [
{
"id": "sg:grant.4850485",
"type": "MonetaryGrant"
},
{
"id": "sg:grant.2767439",
"type": "MonetaryGrant"
},
{
"id": "sg:grant.3797781",
"type": "MonetaryGrant"
},
{
"id": "sg:grant.4057637",
"type": "MonetaryGrant"
},
{
"id": "sg:grant.2751574",
"type": "MonetaryGrant"
}
],
"isPartOf": [
{
"id": "sg:journal.1043282",
"issn": [
"2041-1723"
],
"name": "Nature Communications",
"type": "Periodical"
},
{
"issueNumber": "1",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "8"
}
],
"name": "Evidence for single metal two electron oxidative addition and reductive elimination at uranium",
"pagination": "1898",
"productId": [
{
"name": "readcube_id",
"type": "PropertyValue",
"value": [
"922db5f17f469912ea6260db8389fd66226c81318676adcf0da04461bd72a7f0"
]
},
{
"name": "pubmed_id",
"type": "PropertyValue",
"value": [
"29196691"
]
},
{
"name": "nlm_unique_id",
"type": "PropertyValue",
"value": [
"101528555"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1038/s41467-017-01363-0"
]
},
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1093031862"
]
}
],
"sameAs": [
"https://doi.org/10.1038/s41467-017-01363-0",
"https://app.dimensions.ai/details/publication/pub.1093031862"
],
"sdDataset": "articles",
"sdDatePublished": "2019-04-10T19:07",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8678_00000509.jsonl",
"type": "ScholarlyArticle",
"url": "https://www.nature.com/articles/s41467-017-01363-0"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1038/s41467-017-01363-0'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1038/s41467-017-01363-0'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1038/s41467-017-01363-0'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1038/s41467-017-01363-0'
This table displays all metadata directly associated to this object as RDF triples.
367 TRIPLES
21 PREDICATES
102 URIs
21 LITERALS
9 BLANK NODES