Hydrophobic poly(3,4-ethylenedioxythiophene) particles synthesized by aqueous oxidative coupling polymerization and their use as near-infrared-responsive liquid marble stabilizer View Full Text


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Article Info

DATE

2019-04-02

AUTHORS

Natsuko Shimogama, Makoto Uda, Keigo Oyama, Haruka Hanochi, Tomoyasu Hirai, Yoshinobu Nakamura, Syuji Fujii

ABSTRACT

The aqueous oxidative coupling polymerization of 3,4-ethylenedioxythiophene was conducted in the presence of heptadecafluorooctane sulfonic acid, which was used as a perfluoroalkyl dopant to synthesize hydrophobic poly(3,4-ethylenedioxythiophene) particles. The poly(3,4-ethylenedioxythiophene) particles were characterized in terms of their size, morphology, surface and bulk chemical compositions, conductivity, hydrophilic–hydrophobic balance and (photo)thermal properties. The electron microscopy studies confirmed that poly(3,4-ethylenedioxythiophene) consisted of aggregates of primary atypical particles of a submicrometer size. X-ray photoelectron spectroscopy and the contact angle measurement indicated that the perfluoroalkyl dopants were present on the surface of the poly(3,4-ethylenedioxythiophene) particles, which caused them to have a hydrophobic character. The electrical conductivity of the pressed pellet was 15.5 S cm−1, which was one order of magnitude higher than that of the poly(3,4-ethylenedioxythiophene) that was synthesized in the absence of the perfluoroalkyl dopant. The dried poly(3,4-ethylenedioxythiophene) particles could be used as a near-infrared-responsive liquid marble stabilizer exhibiting light-to-heat conversion properties. The movement of the poly(3,4-ethylenedioxythiophene) particle-coated liquid marbles on a planar water surface was driven by near-infrared laser-induced Marangoni propulsion. The inner liquid could be released by the disruption of the liquid marbles via an application of an external stimulus. The aqueous oxidative coupling polymerization of 3,4-ethylenedioxythiophene was conducted in the presence of heptadecafluorooctane sulfonic acid, which was used as a perfluoroalkyl dopant to synthesize hydrophobic poly(3,4-ethylenedioxythiophene) particles. The dried poly(3,4-ethylenedioxythiophene) particles could be used as a near-infrared-responsive liquid marble stabilizer exhibiting light-to-heat conversion properties. The movement of the poly(3,4-ethylenedioxythiophene) particle-coated liquid marbles on a planar water surface was driven by near-infrared laser-induced Marangoni propulsion. More... »

PAGES

1-10

References to SciGraph publications

Journal

TITLE

Polymer Journal

ISSUE

N/A

VOLUME

N/A

Author Affiliations

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  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1038/s41428-019-0189-0

    DOI

    http://dx.doi.org/10.1038/s41428-019-0189-0

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1113202571


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