Preparation of a soluble polysilsesquioxane containing a macrocyclic structure and capture of palladium ions View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2019-04

AUTHORS

Daisuke Maeda, Kimihiro Matsukawa, Yasunari Kusaka, Yoshiro Kaneko

ABSTRACT

In this study, a soluble polysilsesquioxane containing a macrocyclic structure (PSQ-MC) was successfully prepared by the hydrolytic condensation of a dual site-type silane coupling agent, i.e., bis{3-[3-(trimethoxysilyl)propylthio]propyl}phthalate (BTPP), using hydrochloric acid as the catalyst in an acetone/ethyl acetate mixed solvent. Based on the results of 29Si NMR and gel permeation chromatography and the fact that the dimer of the cyclized BTPP was present in the intermediate after the reaction of BTPP in a dilute solution at room temperature, PSQ-MC was assumed to be a polymer in which an 8-membered cyclic siloxane with two 23-membered rings was linked by a single siloxane bond. In addition, PSQ-MC was able to capture palladium ions. A soluble polysilsesquioxane containing macrocyclic structure (PSQ-MC) is successfully prepared by the hydrolytic condensation of a dual site-type silane coupling agent, i.e., bis{3-[3-(trimethoxysilyl)propylthio]propyl}phthalate (BTPP). PSQ-MC is assumed to be a polymer in which an 8-membered cyclic siloxane having two 23-membered rings is linked by a single siloxane bond. In addition, PSQ-MC could capture palladium ions. More... »

PAGES

439-447

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/s41428-018-0151-6

DOI

http://dx.doi.org/10.1038/s41428-018-0151-6

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1110097859


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Kagoshima University", 
          "id": "https://www.grid.ac/institutes/grid.258333.c", 
          "name": [
            "Graduate School of Science and Engineering, Kagoshima University, 1-21-40 Korimoto, 890-0065, Kagoshima, Japan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Maeda", 
        "givenName": "Daisuke", 
        "id": "sg:person.015004610356.13", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015004610356.13"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Kyoto Institute of Technology", 
          "id": "https://www.grid.ac/institutes/grid.419025.b", 
          "name": [
            "Materials Science and Technology, Kyoto Institute of Technology, Matsugasaki Hashigami-cho, Sakyo-ku, 606-8585, Kyoto, Japan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Matsukawa", 
        "givenName": "Kimihiro", 
        "id": "sg:person.011761570117.96", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011761570117.96"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Sekisui Chemical (Japan)", 
          "id": "https://www.grid.ac/institutes/grid.471315.5", 
          "name": [
            "Sekisui Chemical Co., Ltd., 2-1 Hyakuyama, Shimamoto-cho, Mishima-gun, 618-0021, Osaka, Japan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kusaka", 
        "givenName": "Yasunari", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Kagoshima University", 
          "id": "https://www.grid.ac/institutes/grid.258333.c", 
          "name": [
            "Graduate School of Science and Engineering, Kagoshima University, 1-21-40 Korimoto, 890-0065, Kagoshima, Japan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kaneko", 
        "givenName": "Yoshiro", 
        "id": "sg:person.01210561635.77", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01210561635.77"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1039/c2jm32355a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000961791"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c0jm02561e", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001120449"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c0jm02561e", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001120449"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1524/zkri.2007.222.11.656", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004351742"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/asia.201300222", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006434150"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1155/2012/684278", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006853596"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.polymer.2004.12.038", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009384126"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/pj.2016.66", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011920109", 
          "https://doi.org/10.1038/pj.2016.66"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c3cc43256d", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1016286947"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/marc.1985.030060308", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1016294211"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja1078305", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020049449"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja1078305", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020049449"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/pola.22848", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022867015"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/ncomms3321", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023810841", 
          "https://doi.org/10.1038/ncomms3321"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/chem.201103684", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026958159"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/pola.10572", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1029765347"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.2494/photopolymer.27.261", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030225119"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.polymer.2012.10.052", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032345775"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c4ra17113f", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034931369"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b211030j", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039751086"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jorganchem.2010.02.008", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043250468"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c3tc32292k", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044441001"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c5py01262g", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045073125"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/pj.2016.45", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047094104", 
          "https://doi.org/10.1038/pj.2016.45"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c5py00192g", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047848409"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/pola.27004", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048268137"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/chem.201402011", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050941076"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr00037a012", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053862323"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr900201r", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1054045584"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr900201r", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1054045584"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/acs.macromol.5b02340", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055119014"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cm000451i", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055407392"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cm000451i", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055407392"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cm0495212", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055411131"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cm0495212", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055411131"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja010720l", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055765847"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja010720l", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055765847"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja01508a054", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055802833"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja801491m", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055858064"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja801491m", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055858064"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja8070978", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055859618"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja8070978", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055859618"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma00032a033", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056173893"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma00045a004", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056174472"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma0116452", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056186250"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma0116452", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056186250"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma0496448", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056190317"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma0496448", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056190317"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma070547z", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056193233"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma070547z", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056193233"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1246/bcsj.20130246", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1064471419"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1246/bcsj.20160170", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1064471815"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1246/bcsj.78.1105", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1064477505"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1246/cl.140515", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1064479281"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/pj.2016.128", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1074190494", 
          "https://doi.org/10.1038/pj.2016.128"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c7ra00656j", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1083760274"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/acs.inorgchem.7b00131", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1084122482"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.polymer.2017.06.025", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1086000105"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/pj.2017.56", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1091927106", 
          "https://doi.org/10.1038/pj.2017.56"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/s41428-017-0021-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1100830598", 
          "https://doi.org/10.1038/s41428-017-0021-7"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c8py00354h", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1101898260"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.polymer.2018.03.059", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1103159313"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.polymer.2018.03.059", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1103159313"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1246/cl.180258", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1103696556"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1246/bcsj.20180092", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1103705414"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/s41428-018-0071-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1104099439", 
          "https://doi.org/10.1038/s41428-018-0071-5"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/s41428-018-0068-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1104140462", 
          "https://doi.org/10.1038/s41428-018-0068-0"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1246/bcsj.20180066", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1105183319"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2019-04", 
    "datePublishedReg": "2019-04-01", 
    "description": "In this study, a soluble polysilsesquioxane containing a macrocyclic structure (PSQ-MC) was successfully prepared by the hydrolytic condensation of a dual site-type silane coupling agent, i.e., bis{3-[3-(trimethoxysilyl)propylthio]propyl}phthalate (BTPP), using hydrochloric acid as the catalyst in an acetone/ethyl acetate mixed solvent. Based on the results of 29Si NMR and gel permeation chromatography and the fact that the dimer of the cyclized BTPP was present in the intermediate after the reaction of BTPP in a dilute solution at room temperature, PSQ-MC was assumed to be a polymer in which an 8-membered cyclic siloxane with two 23-membered rings was linked by a single siloxane bond. In addition, PSQ-MC was able to capture palladium ions. A soluble polysilsesquioxane containing macrocyclic structure (PSQ-MC) is successfully prepared by the hydrolytic condensation of a dual site-type silane coupling agent, i.e., bis{3-[3-(trimethoxysilyl)propylthio]propyl}phthalate (BTPP). PSQ-MC is assumed to be a polymer in which an 8-membered cyclic siloxane having two 23-membered rings is linked by a single siloxane bond. In addition, PSQ-MC could capture palladium ions. ", 
    "genre": "research_article", 
    "id": "sg:pub.10.1038/s41428-018-0151-6", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1043822", 
        "issn": [
          "0032-3896", 
          "1349-0540"
        ], 
        "name": "Polymer Journal", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "4", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "51"
      }
    ], 
    "name": "Preparation of a soluble polysilsesquioxane containing a macrocyclic structure and capture of palladium ions", 
    "pagination": "439-447", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "3b65ed628db488d77841392443a958a45fd1ccd18e0c8e2e5ac3c70eb5e0ee9f"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1038/s41428-018-0151-6"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1110097859"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1038/s41428-018-0151-6", 
      "https://app.dimensions.ai/details/publication/pub.1110097859"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T12:27", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000362_0000000362/records_87117_00000001.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://www.nature.com/articles/s41428-018-0151-6"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1038/s41428-018-0151-6'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1038/s41428-018-0151-6'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1038/s41428-018-0151-6'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1038/s41428-018-0151-6'


 

This table displays all metadata directly associated to this object as RDF triples.

263 TRIPLES      21 PREDICATES      83 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1038/s41428-018-0151-6 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author Nb8ab42d443c0496db5073e63b10561ce
4 schema:citation sg:pub.10.1038/ncomms3321
5 sg:pub.10.1038/pj.2016.128
6 sg:pub.10.1038/pj.2016.45
7 sg:pub.10.1038/pj.2016.66
8 sg:pub.10.1038/pj.2017.56
9 sg:pub.10.1038/s41428-017-0021-7
10 sg:pub.10.1038/s41428-018-0068-0
11 sg:pub.10.1038/s41428-018-0071-5
12 https://doi.org/10.1002/asia.201300222
13 https://doi.org/10.1002/chem.201103684
14 https://doi.org/10.1002/chem.201402011
15 https://doi.org/10.1002/marc.1985.030060308
16 https://doi.org/10.1002/pola.10572
17 https://doi.org/10.1002/pola.22848
18 https://doi.org/10.1002/pola.27004
19 https://doi.org/10.1016/j.jorganchem.2010.02.008
20 https://doi.org/10.1016/j.polymer.2004.12.038
21 https://doi.org/10.1016/j.polymer.2012.10.052
22 https://doi.org/10.1016/j.polymer.2017.06.025
23 https://doi.org/10.1016/j.polymer.2018.03.059
24 https://doi.org/10.1021/acs.inorgchem.7b00131
25 https://doi.org/10.1021/acs.macromol.5b02340
26 https://doi.org/10.1021/cm000451i
27 https://doi.org/10.1021/cm0495212
28 https://doi.org/10.1021/cr00037a012
29 https://doi.org/10.1021/cr900201r
30 https://doi.org/10.1021/ja010720l
31 https://doi.org/10.1021/ja01508a054
32 https://doi.org/10.1021/ja1078305
33 https://doi.org/10.1021/ja801491m
34 https://doi.org/10.1021/ja8070978
35 https://doi.org/10.1021/ma00032a033
36 https://doi.org/10.1021/ma00045a004
37 https://doi.org/10.1021/ma0116452
38 https://doi.org/10.1021/ma0496448
39 https://doi.org/10.1021/ma070547z
40 https://doi.org/10.1039/b211030j
41 https://doi.org/10.1039/c0jm02561e
42 https://doi.org/10.1039/c2jm32355a
43 https://doi.org/10.1039/c3cc43256d
44 https://doi.org/10.1039/c3tc32292k
45 https://doi.org/10.1039/c4ra17113f
46 https://doi.org/10.1039/c5py00192g
47 https://doi.org/10.1039/c5py01262g
48 https://doi.org/10.1039/c7ra00656j
49 https://doi.org/10.1039/c8py00354h
50 https://doi.org/10.1155/2012/684278
51 https://doi.org/10.1246/bcsj.20130246
52 https://doi.org/10.1246/bcsj.20160170
53 https://doi.org/10.1246/bcsj.20180066
54 https://doi.org/10.1246/bcsj.20180092
55 https://doi.org/10.1246/bcsj.78.1105
56 https://doi.org/10.1246/cl.140515
57 https://doi.org/10.1246/cl.180258
58 https://doi.org/10.1524/zkri.2007.222.11.656
59 https://doi.org/10.2494/photopolymer.27.261
60 schema:datePublished 2019-04
61 schema:datePublishedReg 2019-04-01
62 schema:description In this study, a soluble polysilsesquioxane containing a macrocyclic structure (PSQ-MC) was successfully prepared by the hydrolytic condensation of a dual site-type silane coupling agent, i.e., bis{3-[3-(trimethoxysilyl)propylthio]propyl}phthalate (BTPP), using hydrochloric acid as the catalyst in an acetone/ethyl acetate mixed solvent. Based on the results of 29Si NMR and gel permeation chromatography and the fact that the dimer of the cyclized BTPP was present in the intermediate after the reaction of BTPP in a dilute solution at room temperature, PSQ-MC was assumed to be a polymer in which an 8-membered cyclic siloxane with two 23-membered rings was linked by a single siloxane bond. In addition, PSQ-MC was able to capture palladium ions. A soluble polysilsesquioxane containing macrocyclic structure (PSQ-MC) is successfully prepared by the hydrolytic condensation of a dual site-type silane coupling agent, i.e., bis{3-[3-(trimethoxysilyl)propylthio]propyl}phthalate (BTPP). PSQ-MC is assumed to be a polymer in which an 8-membered cyclic siloxane having two 23-membered rings is linked by a single siloxane bond. In addition, PSQ-MC could capture palladium ions.
63 schema:genre research_article
64 schema:inLanguage en
65 schema:isAccessibleForFree false
66 schema:isPartOf Ncc8fb270e63b4722acfe85ac6a761ad0
67 Ne494a7c708404d1b9bc685f378770c96
68 sg:journal.1043822
69 schema:name Preparation of a soluble polysilsesquioxane containing a macrocyclic structure and capture of palladium ions
70 schema:pagination 439-447
71 schema:productId N96385847c85744d197eb9eaeb2aa9af1
72 N98aecb2287404c27a7a665bbf8f875b8
73 N9a4d2b9587954ad8bbdfbef61ead8484
74 schema:sameAs https://app.dimensions.ai/details/publication/pub.1110097859
75 https://doi.org/10.1038/s41428-018-0151-6
76 schema:sdDatePublished 2019-04-11T12:27
77 schema:sdLicense https://scigraph.springernature.com/explorer/license/
78 schema:sdPublisher N2ea2e528a0a14f78bfe951c52b50bf27
79 schema:url https://www.nature.com/articles/s41428-018-0151-6
80 sgo:license sg:explorer/license/
81 sgo:sdDataset articles
82 rdf:type schema:ScholarlyArticle
83 N13ed7cdd5a5344fc83f4a276e273df1f rdf:first sg:person.011761570117.96
84 rdf:rest N27581e19254741a4a484afa92cbcaa78
85 N27581e19254741a4a484afa92cbcaa78 rdf:first N3616566b1210493fae95a79d675ce686
86 rdf:rest N3bcbb3b7289f4715b3e858789ec5915e
87 N2ea2e528a0a14f78bfe951c52b50bf27 schema:name Springer Nature - SN SciGraph project
88 rdf:type schema:Organization
89 N3616566b1210493fae95a79d675ce686 schema:affiliation https://www.grid.ac/institutes/grid.471315.5
90 schema:familyName Kusaka
91 schema:givenName Yasunari
92 rdf:type schema:Person
93 N3bcbb3b7289f4715b3e858789ec5915e rdf:first sg:person.01210561635.77
94 rdf:rest rdf:nil
95 N96385847c85744d197eb9eaeb2aa9af1 schema:name dimensions_id
96 schema:value pub.1110097859
97 rdf:type schema:PropertyValue
98 N98aecb2287404c27a7a665bbf8f875b8 schema:name readcube_id
99 schema:value 3b65ed628db488d77841392443a958a45fd1ccd18e0c8e2e5ac3c70eb5e0ee9f
100 rdf:type schema:PropertyValue
101 N9a4d2b9587954ad8bbdfbef61ead8484 schema:name doi
102 schema:value 10.1038/s41428-018-0151-6
103 rdf:type schema:PropertyValue
104 Nb8ab42d443c0496db5073e63b10561ce rdf:first sg:person.015004610356.13
105 rdf:rest N13ed7cdd5a5344fc83f4a276e273df1f
106 Ncc8fb270e63b4722acfe85ac6a761ad0 schema:issueNumber 4
107 rdf:type schema:PublicationIssue
108 Ne494a7c708404d1b9bc685f378770c96 schema:volumeNumber 51
109 rdf:type schema:PublicationVolume
110 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
111 schema:name Chemical Sciences
112 rdf:type schema:DefinedTerm
113 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
114 schema:name Physical Chemistry (incl. Structural)
115 rdf:type schema:DefinedTerm
116 sg:journal.1043822 schema:issn 0032-3896
117 1349-0540
118 schema:name Polymer Journal
119 rdf:type schema:Periodical
120 sg:person.011761570117.96 schema:affiliation https://www.grid.ac/institutes/grid.419025.b
121 schema:familyName Matsukawa
122 schema:givenName Kimihiro
123 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011761570117.96
124 rdf:type schema:Person
125 sg:person.01210561635.77 schema:affiliation https://www.grid.ac/institutes/grid.258333.c
126 schema:familyName Kaneko
127 schema:givenName Yoshiro
128 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01210561635.77
129 rdf:type schema:Person
130 sg:person.015004610356.13 schema:affiliation https://www.grid.ac/institutes/grid.258333.c
131 schema:familyName Maeda
132 schema:givenName Daisuke
133 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015004610356.13
134 rdf:type schema:Person
135 sg:pub.10.1038/ncomms3321 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023810841
136 https://doi.org/10.1038/ncomms3321
137 rdf:type schema:CreativeWork
138 sg:pub.10.1038/pj.2016.128 schema:sameAs https://app.dimensions.ai/details/publication/pub.1074190494
139 https://doi.org/10.1038/pj.2016.128
140 rdf:type schema:CreativeWork
141 sg:pub.10.1038/pj.2016.45 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047094104
142 https://doi.org/10.1038/pj.2016.45
143 rdf:type schema:CreativeWork
144 sg:pub.10.1038/pj.2016.66 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011920109
145 https://doi.org/10.1038/pj.2016.66
146 rdf:type schema:CreativeWork
147 sg:pub.10.1038/pj.2017.56 schema:sameAs https://app.dimensions.ai/details/publication/pub.1091927106
148 https://doi.org/10.1038/pj.2017.56
149 rdf:type schema:CreativeWork
150 sg:pub.10.1038/s41428-017-0021-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1100830598
151 https://doi.org/10.1038/s41428-017-0021-7
152 rdf:type schema:CreativeWork
153 sg:pub.10.1038/s41428-018-0068-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1104140462
154 https://doi.org/10.1038/s41428-018-0068-0
155 rdf:type schema:CreativeWork
156 sg:pub.10.1038/s41428-018-0071-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1104099439
157 https://doi.org/10.1038/s41428-018-0071-5
158 rdf:type schema:CreativeWork
159 https://doi.org/10.1002/asia.201300222 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006434150
160 rdf:type schema:CreativeWork
161 https://doi.org/10.1002/chem.201103684 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026958159
162 rdf:type schema:CreativeWork
163 https://doi.org/10.1002/chem.201402011 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050941076
164 rdf:type schema:CreativeWork
165 https://doi.org/10.1002/marc.1985.030060308 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016294211
166 rdf:type schema:CreativeWork
167 https://doi.org/10.1002/pola.10572 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029765347
168 rdf:type schema:CreativeWork
169 https://doi.org/10.1002/pola.22848 schema:sameAs https://app.dimensions.ai/details/publication/pub.1022867015
170 rdf:type schema:CreativeWork
171 https://doi.org/10.1002/pola.27004 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048268137
172 rdf:type schema:CreativeWork
173 https://doi.org/10.1016/j.jorganchem.2010.02.008 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043250468
174 rdf:type schema:CreativeWork
175 https://doi.org/10.1016/j.polymer.2004.12.038 schema:sameAs https://app.dimensions.ai/details/publication/pub.1009384126
176 rdf:type schema:CreativeWork
177 https://doi.org/10.1016/j.polymer.2012.10.052 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032345775
178 rdf:type schema:CreativeWork
179 https://doi.org/10.1016/j.polymer.2017.06.025 schema:sameAs https://app.dimensions.ai/details/publication/pub.1086000105
180 rdf:type schema:CreativeWork
181 https://doi.org/10.1016/j.polymer.2018.03.059 schema:sameAs https://app.dimensions.ai/details/publication/pub.1103159313
182 rdf:type schema:CreativeWork
183 https://doi.org/10.1021/acs.inorgchem.7b00131 schema:sameAs https://app.dimensions.ai/details/publication/pub.1084122482
184 rdf:type schema:CreativeWork
185 https://doi.org/10.1021/acs.macromol.5b02340 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055119014
186 rdf:type schema:CreativeWork
187 https://doi.org/10.1021/cm000451i schema:sameAs https://app.dimensions.ai/details/publication/pub.1055407392
188 rdf:type schema:CreativeWork
189 https://doi.org/10.1021/cm0495212 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055411131
190 rdf:type schema:CreativeWork
191 https://doi.org/10.1021/cr00037a012 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053862323
192 rdf:type schema:CreativeWork
193 https://doi.org/10.1021/cr900201r schema:sameAs https://app.dimensions.ai/details/publication/pub.1054045584
194 rdf:type schema:CreativeWork
195 https://doi.org/10.1021/ja010720l schema:sameAs https://app.dimensions.ai/details/publication/pub.1055765847
196 rdf:type schema:CreativeWork
197 https://doi.org/10.1021/ja01508a054 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055802833
198 rdf:type schema:CreativeWork
199 https://doi.org/10.1021/ja1078305 schema:sameAs https://app.dimensions.ai/details/publication/pub.1020049449
200 rdf:type schema:CreativeWork
201 https://doi.org/10.1021/ja801491m schema:sameAs https://app.dimensions.ai/details/publication/pub.1055858064
202 rdf:type schema:CreativeWork
203 https://doi.org/10.1021/ja8070978 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055859618
204 rdf:type schema:CreativeWork
205 https://doi.org/10.1021/ma00032a033 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056173893
206 rdf:type schema:CreativeWork
207 https://doi.org/10.1021/ma00045a004 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056174472
208 rdf:type schema:CreativeWork
209 https://doi.org/10.1021/ma0116452 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056186250
210 rdf:type schema:CreativeWork
211 https://doi.org/10.1021/ma0496448 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056190317
212 rdf:type schema:CreativeWork
213 https://doi.org/10.1021/ma070547z schema:sameAs https://app.dimensions.ai/details/publication/pub.1056193233
214 rdf:type schema:CreativeWork
215 https://doi.org/10.1039/b211030j schema:sameAs https://app.dimensions.ai/details/publication/pub.1039751086
216 rdf:type schema:CreativeWork
217 https://doi.org/10.1039/c0jm02561e schema:sameAs https://app.dimensions.ai/details/publication/pub.1001120449
218 rdf:type schema:CreativeWork
219 https://doi.org/10.1039/c2jm32355a schema:sameAs https://app.dimensions.ai/details/publication/pub.1000961791
220 rdf:type schema:CreativeWork
221 https://doi.org/10.1039/c3cc43256d schema:sameAs https://app.dimensions.ai/details/publication/pub.1016286947
222 rdf:type schema:CreativeWork
223 https://doi.org/10.1039/c3tc32292k schema:sameAs https://app.dimensions.ai/details/publication/pub.1044441001
224 rdf:type schema:CreativeWork
225 https://doi.org/10.1039/c4ra17113f schema:sameAs https://app.dimensions.ai/details/publication/pub.1034931369
226 rdf:type schema:CreativeWork
227 https://doi.org/10.1039/c5py00192g schema:sameAs https://app.dimensions.ai/details/publication/pub.1047848409
228 rdf:type schema:CreativeWork
229 https://doi.org/10.1039/c5py01262g schema:sameAs https://app.dimensions.ai/details/publication/pub.1045073125
230 rdf:type schema:CreativeWork
231 https://doi.org/10.1039/c7ra00656j schema:sameAs https://app.dimensions.ai/details/publication/pub.1083760274
232 rdf:type schema:CreativeWork
233 https://doi.org/10.1039/c8py00354h schema:sameAs https://app.dimensions.ai/details/publication/pub.1101898260
234 rdf:type schema:CreativeWork
235 https://doi.org/10.1155/2012/684278 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006853596
236 rdf:type schema:CreativeWork
237 https://doi.org/10.1246/bcsj.20130246 schema:sameAs https://app.dimensions.ai/details/publication/pub.1064471419
238 rdf:type schema:CreativeWork
239 https://doi.org/10.1246/bcsj.20160170 schema:sameAs https://app.dimensions.ai/details/publication/pub.1064471815
240 rdf:type schema:CreativeWork
241 https://doi.org/10.1246/bcsj.20180066 schema:sameAs https://app.dimensions.ai/details/publication/pub.1105183319
242 rdf:type schema:CreativeWork
243 https://doi.org/10.1246/bcsj.20180092 schema:sameAs https://app.dimensions.ai/details/publication/pub.1103705414
244 rdf:type schema:CreativeWork
245 https://doi.org/10.1246/bcsj.78.1105 schema:sameAs https://app.dimensions.ai/details/publication/pub.1064477505
246 rdf:type schema:CreativeWork
247 https://doi.org/10.1246/cl.140515 schema:sameAs https://app.dimensions.ai/details/publication/pub.1064479281
248 rdf:type schema:CreativeWork
249 https://doi.org/10.1246/cl.180258 schema:sameAs https://app.dimensions.ai/details/publication/pub.1103696556
250 rdf:type schema:CreativeWork
251 https://doi.org/10.1524/zkri.2007.222.11.656 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004351742
252 rdf:type schema:CreativeWork
253 https://doi.org/10.2494/photopolymer.27.261 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030225119
254 rdf:type schema:CreativeWork
255 https://www.grid.ac/institutes/grid.258333.c schema:alternateName Kagoshima University
256 schema:name Graduate School of Science and Engineering, Kagoshima University, 1-21-40 Korimoto, 890-0065, Kagoshima, Japan
257 rdf:type schema:Organization
258 https://www.grid.ac/institutes/grid.419025.b schema:alternateName Kyoto Institute of Technology
259 schema:name Materials Science and Technology, Kyoto Institute of Technology, Matsugasaki Hashigami-cho, Sakyo-ku, 606-8585, Kyoto, Japan
260 rdf:type schema:Organization
261 https://www.grid.ac/institutes/grid.471315.5 schema:alternateName Sekisui Chemical (Japan)
262 schema:name Sekisui Chemical Co., Ltd., 2-1 Hyakuyama, Shimamoto-cho, Mishima-gun, 618-0021, Osaka, Japan
263 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...