New strategy for designing orangish-red-emitting phosphor via oxygen-vacancy-induced electronic localization View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2019-12

AUTHORS

Yi Wei, Gongcheng Xing, Kang Liu, Guogang Li, Peipei Dang, Sisi Liang, Min Liu, Ziyong Cheng, Dayong Jin, Jun Lin

ABSTRACT

Phosphor-converted white-light-emitting diodes (pc-WLED) have been extensively employed as solid-state lighting sources, which have a very important role in people's daily lives. However, due to the scarcity of the red component, it is difficult to realize warm white light efficiently. Hence, red-emitting phosphors are urgently required for improving the illumination quality. In this work, we develop a novel orangish-red La4GeO8:Bi3+ phosphor, the emission peak of which is located at 600 nm under near-ultraviolet (n-UV) light excitation. The full width at half maximum (fwhm) is 103 nm, the internal quantum efficiency (IQE) exceeds 88%, and the external quantum efficiency (EQE) is 69%. According to Rietveld refinement analysis and density functional theory (DFT) calculations, Bi3+ ions randomly occupy all La sites in orthorhombic La4GeO8. Importantly, the oxygen-vacancy-induced electronic localization around the Bi3+ ions is the main reason for the highly efficient orangish-red luminescence. These results provide a new perspective and insight from the local electron structure for designing inorganic phosphor materials that realize the unique luminescence performance of Bi3+ ions. More... »

PAGES

15

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/s41377-019-0126-1

DOI

http://dx.doi.org/10.1038/s41377-019-0126-1

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https://app.dimensions.ai/details/publication/pub.1111761428

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/30728955


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40 schema:description Phosphor-converted white-light-emitting diodes (pc-WLED) have been extensively employed as solid-state lighting sources, which have a very important role in people's daily lives. However, due to the scarcity of the red component, it is difficult to realize warm white light efficiently. Hence, red-emitting phosphors are urgently required for improving the illumination quality. In this work, we develop a novel orangish-red La<sub>4</sub>GeO<sub>8</sub>:Bi<sup>3+</sup> phosphor, the emission peak of which is located at 600 nm under near-ultraviolet (n-UV) light excitation. The full width at half maximum (fwhm) is 103 nm, the internal quantum efficiency (IQE) exceeds 88%, and the external quantum efficiency (EQE) is 69%. According to Rietveld refinement analysis and density functional theory (DFT) calculations, Bi<sup>3+</sup> ions randomly occupy all La sites in orthorhombic La<sub>4</sub>GeO<sub>8</sub>. Importantly, the oxygen-vacancy-induced electronic localization around the Bi<sup>3+</sup> ions is the main reason for the highly efficient orangish-red luminescence. These results provide a new perspective and insight from the local electron structure for designing inorganic phosphor materials that realize the unique luminescence performance of Bi<sup>3+</sup> ions.
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