Synchronous and separate homo-crystallization of an enantiomeric oligomeric poly(l-3-hydroxybutanoic acid)/poly(d-3-hydroxybutanoic acid) blend View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2016-02

AUTHORS

Hideto Tsuji, Soma Noda, Satoru Shimizu

ABSTRACT

Poly(l-3-hydroxybutanoic acid) [P(l-3HB)] and poly(d-3-hydroxybutanoic acid) [P(d-3HB)] in their equimolar blend crystallized synchronously and separately into each homo-crystallites but not stereocomplex crystallites. In the case of the blend, the orientation and periodical rotation of lamellae in the spherulites disappeared at a relatively low crystallization temperature (Tc); the nucleation for the spherulite growth was prolonged, and the size of homo-crystallites and the radial growth rate of spherulites were decreased, owing to the synchronous and separate homo-crystallization and the coexistence of P(l-3HB) and P(d-3HB) homo-crystallites in spherulites. More... »

PAGES

215

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/pj.2015.96

DOI

http://dx.doi.org/10.1038/pj.2015.96

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1027885615


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0303", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Macromolecular and Materials Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Toyohashi University of Technology", 
          "id": "https://www.grid.ac/institutes/grid.412804.b", 
          "name": [
            "Department of Environmental and Life Sciences, Graduate School of Engineering, Toyohashi University of Technology, Toyohashi, Aichi, Japan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Tsuji", 
        "givenName": "Hideto", 
        "id": "sg:person.01313652351.41", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01313652351.41"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Toyohashi University of Technology", 
          "id": "https://www.grid.ac/institutes/grid.412804.b", 
          "name": [
            "Department of Environmental and Life Sciences, Graduate School of Engineering, Toyohashi University of Technology, Toyohashi, Aichi, Japan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Noda", 
        "givenName": "Soma", 
        "id": "sg:person.010411400233.42", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010411400233.42"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Toyohashi University of Technology", 
          "id": "https://www.grid.ac/institutes/grid.412804.b", 
          "name": [
            "Department of Environmental and Life Sciences, Graduate School of Engineering, Toyohashi University of Technology, Toyohashi, Aichi, Japan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shimizu", 
        "givenName": "Satoru", 
        "id": "sg:person.014271562245.55", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014271562245.55"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.3390/ma2031104", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003721672"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.polymer.2005.02.132", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1008486950"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.progpolymsci.2009.01.003", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012716430"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf01026954", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1016811866", 
          "https://doi.org/10.1007/bf01026954"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.polymer.2011.12.023", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017120818"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.polymer.2012.09.039", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022195118"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1295/polymj.6.248", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1025459111", 
          "https://doi.org/10.1295/polymj.6.248"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0014-3057(89)90151-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026086380"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0014-3057(89)90151-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026086380"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/mabi.200500062", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030481897"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/mabi.200500062", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030481897"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0032-3861(73)90087-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034963064"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0032-3861(73)90087-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034963064"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0079-6700(92)90002-g", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035599515"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0079-6700(92)90002-g", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035599515"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.molstruc.2004.11.033", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038486287"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.polymer.2015.05.056", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039049482"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/pol.1984.180220404", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042150994"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.polymer.2015.05.004", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1049546952"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/bm0155975", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055219579"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/bm0155975", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055219579"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma00165a035", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056181074"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma60011a012", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056199428"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.6028/jres.079a.026", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1073600022"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2016-02", 
    "datePublishedReg": "2016-02-01", 
    "description": "Poly(l-3-hydroxybutanoic acid) [P(l-3HB)] and poly(d-3-hydroxybutanoic acid) [P(d-3HB)] in their equimolar blend crystallized synchronously and separately into each homo-crystallites but not stereocomplex crystallites. In the case of the blend, the orientation and periodical rotation of lamellae in the spherulites disappeared at a relatively low crystallization temperature (Tc); the nucleation for the spherulite growth was prolonged, and the size of homo-crystallites and the radial growth rate of spherulites were decreased, owing to the synchronous and separate homo-crystallization and the coexistence of P(l-3HB) and P(d-3HB) homo-crystallites in spherulites.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1038/pj.2015.96", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isFundedItemOf": [
      {
        "id": "sg:grant.6082746", 
        "type": "MonetaryGrant"
      }, 
      {
        "id": "sg:grant.6092538", 
        "type": "MonetaryGrant"
      }
    ], 
    "isPartOf": [
      {
        "id": "sg:journal.1043822", 
        "issn": [
          "0032-3896", 
          "1349-0540"
        ], 
        "name": "Polymer Journal", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "2", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "48"
      }
    ], 
    "name": "Synchronous and separate homo-crystallization of an enantiomeric oligomeric poly(l-3-hydroxybutanoic acid)/poly(d-3-hydroxybutanoic acid) blend", 
    "pagination": "215", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "84d68a265bc814f8fcc92b9744a8b92e3231935da04a18216e039f20a0e00aba"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1038/pj.2015.96"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1027885615"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1038/pj.2015.96", 
      "https://app.dimensions.ai/details/publication/pub.1027885615"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T22:19", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8690_00000424.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://www.nature.com/articles/pj201596"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1038/pj.2015.96'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1038/pj.2015.96'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1038/pj.2015.96'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1038/pj.2015.96'


 

This table displays all metadata directly associated to this object as RDF triples.

138 TRIPLES      21 PREDICATES      46 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1038/pj.2015.96 schema:about anzsrc-for:03
2 anzsrc-for:0303
3 schema:author N3addd312c6664860a5647b40dc9fde1d
4 schema:citation sg:pub.10.1007/bf01026954
5 sg:pub.10.1295/polymj.6.248
6 https://doi.org/10.1002/mabi.200500062
7 https://doi.org/10.1002/pol.1984.180220404
8 https://doi.org/10.1016/0014-3057(89)90151-1
9 https://doi.org/10.1016/0032-3861(73)90087-6
10 https://doi.org/10.1016/0079-6700(92)90002-g
11 https://doi.org/10.1016/j.molstruc.2004.11.033
12 https://doi.org/10.1016/j.polymer.2005.02.132
13 https://doi.org/10.1016/j.polymer.2011.12.023
14 https://doi.org/10.1016/j.polymer.2012.09.039
15 https://doi.org/10.1016/j.polymer.2015.05.004
16 https://doi.org/10.1016/j.polymer.2015.05.056
17 https://doi.org/10.1016/j.progpolymsci.2009.01.003
18 https://doi.org/10.1021/bm0155975
19 https://doi.org/10.1021/ma00165a035
20 https://doi.org/10.1021/ma60011a012
21 https://doi.org/10.3390/ma2031104
22 https://doi.org/10.6028/jres.079a.026
23 schema:datePublished 2016-02
24 schema:datePublishedReg 2016-02-01
25 schema:description Poly(l-3-hydroxybutanoic acid) [P(l-3HB)] and poly(d-3-hydroxybutanoic acid) [P(d-3HB)] in their equimolar blend crystallized synchronously and separately into each homo-crystallites but not stereocomplex crystallites. In the case of the blend, the orientation and periodical rotation of lamellae in the spherulites disappeared at a relatively low crystallization temperature (Tc); the nucleation for the spherulite growth was prolonged, and the size of homo-crystallites and the radial growth rate of spherulites were decreased, owing to the synchronous and separate homo-crystallization and the coexistence of P(l-3HB) and P(d-3HB) homo-crystallites in spherulites.
26 schema:genre research_article
27 schema:inLanguage en
28 schema:isAccessibleForFree false
29 schema:isPartOf N72e110f01f0844b4a125891a4664ee8c
30 Nee12517ac37e4f9f80cdccd88cdd96ae
31 sg:journal.1043822
32 schema:name Synchronous and separate homo-crystallization of an enantiomeric oligomeric poly(l-3-hydroxybutanoic acid)/poly(d-3-hydroxybutanoic acid) blend
33 schema:pagination 215
34 schema:productId N2a6a9e57ac5b46619f6de4f7af3c8ba8
35 Nb9c7e4feabb640d896300cbc962f31c8
36 Nd7adb527b9794385ba158ad1d3d37ecc
37 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027885615
38 https://doi.org/10.1038/pj.2015.96
39 schema:sdDatePublished 2019-04-10T22:19
40 schema:sdLicense https://scigraph.springernature.com/explorer/license/
41 schema:sdPublisher Nccb0d340c8b6462aa75c1d54abd6d571
42 schema:url https://www.nature.com/articles/pj201596
43 sgo:license sg:explorer/license/
44 sgo:sdDataset articles
45 rdf:type schema:ScholarlyArticle
46 N2a6a9e57ac5b46619f6de4f7af3c8ba8 schema:name readcube_id
47 schema:value 84d68a265bc814f8fcc92b9744a8b92e3231935da04a18216e039f20a0e00aba
48 rdf:type schema:PropertyValue
49 N3addd312c6664860a5647b40dc9fde1d rdf:first sg:person.01313652351.41
50 rdf:rest N4317b5ebcbda4a21a8ef9985ccdbdecc
51 N4317b5ebcbda4a21a8ef9985ccdbdecc rdf:first sg:person.010411400233.42
52 rdf:rest N605d5ea361ca47928498ec35b3e769da
53 N605d5ea361ca47928498ec35b3e769da rdf:first sg:person.014271562245.55
54 rdf:rest rdf:nil
55 N72e110f01f0844b4a125891a4664ee8c schema:issueNumber 2
56 rdf:type schema:PublicationIssue
57 Nb9c7e4feabb640d896300cbc962f31c8 schema:name dimensions_id
58 schema:value pub.1027885615
59 rdf:type schema:PropertyValue
60 Nccb0d340c8b6462aa75c1d54abd6d571 schema:name Springer Nature - SN SciGraph project
61 rdf:type schema:Organization
62 Nd7adb527b9794385ba158ad1d3d37ecc schema:name doi
63 schema:value 10.1038/pj.2015.96
64 rdf:type schema:PropertyValue
65 Nee12517ac37e4f9f80cdccd88cdd96ae schema:volumeNumber 48
66 rdf:type schema:PublicationVolume
67 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
68 schema:name Chemical Sciences
69 rdf:type schema:DefinedTerm
70 anzsrc-for:0303 schema:inDefinedTermSet anzsrc-for:
71 schema:name Macromolecular and Materials Chemistry
72 rdf:type schema:DefinedTerm
73 sg:grant.6082746 http://pending.schema.org/fundedItem sg:pub.10.1038/pj.2015.96
74 rdf:type schema:MonetaryGrant
75 sg:grant.6092538 http://pending.schema.org/fundedItem sg:pub.10.1038/pj.2015.96
76 rdf:type schema:MonetaryGrant
77 sg:journal.1043822 schema:issn 0032-3896
78 1349-0540
79 schema:name Polymer Journal
80 rdf:type schema:Periodical
81 sg:person.010411400233.42 schema:affiliation https://www.grid.ac/institutes/grid.412804.b
82 schema:familyName Noda
83 schema:givenName Soma
84 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010411400233.42
85 rdf:type schema:Person
86 sg:person.01313652351.41 schema:affiliation https://www.grid.ac/institutes/grid.412804.b
87 schema:familyName Tsuji
88 schema:givenName Hideto
89 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01313652351.41
90 rdf:type schema:Person
91 sg:person.014271562245.55 schema:affiliation https://www.grid.ac/institutes/grid.412804.b
92 schema:familyName Shimizu
93 schema:givenName Satoru
94 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014271562245.55
95 rdf:type schema:Person
96 sg:pub.10.1007/bf01026954 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016811866
97 https://doi.org/10.1007/bf01026954
98 rdf:type schema:CreativeWork
99 sg:pub.10.1295/polymj.6.248 schema:sameAs https://app.dimensions.ai/details/publication/pub.1025459111
100 https://doi.org/10.1295/polymj.6.248
101 rdf:type schema:CreativeWork
102 https://doi.org/10.1002/mabi.200500062 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030481897
103 rdf:type schema:CreativeWork
104 https://doi.org/10.1002/pol.1984.180220404 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042150994
105 rdf:type schema:CreativeWork
106 https://doi.org/10.1016/0014-3057(89)90151-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026086380
107 rdf:type schema:CreativeWork
108 https://doi.org/10.1016/0032-3861(73)90087-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034963064
109 rdf:type schema:CreativeWork
110 https://doi.org/10.1016/0079-6700(92)90002-g schema:sameAs https://app.dimensions.ai/details/publication/pub.1035599515
111 rdf:type schema:CreativeWork
112 https://doi.org/10.1016/j.molstruc.2004.11.033 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038486287
113 rdf:type schema:CreativeWork
114 https://doi.org/10.1016/j.polymer.2005.02.132 schema:sameAs https://app.dimensions.ai/details/publication/pub.1008486950
115 rdf:type schema:CreativeWork
116 https://doi.org/10.1016/j.polymer.2011.12.023 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017120818
117 rdf:type schema:CreativeWork
118 https://doi.org/10.1016/j.polymer.2012.09.039 schema:sameAs https://app.dimensions.ai/details/publication/pub.1022195118
119 rdf:type schema:CreativeWork
120 https://doi.org/10.1016/j.polymer.2015.05.004 schema:sameAs https://app.dimensions.ai/details/publication/pub.1049546952
121 rdf:type schema:CreativeWork
122 https://doi.org/10.1016/j.polymer.2015.05.056 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039049482
123 rdf:type schema:CreativeWork
124 https://doi.org/10.1016/j.progpolymsci.2009.01.003 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012716430
125 rdf:type schema:CreativeWork
126 https://doi.org/10.1021/bm0155975 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055219579
127 rdf:type schema:CreativeWork
128 https://doi.org/10.1021/ma00165a035 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056181074
129 rdf:type schema:CreativeWork
130 https://doi.org/10.1021/ma60011a012 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056199428
131 rdf:type schema:CreativeWork
132 https://doi.org/10.3390/ma2031104 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003721672
133 rdf:type schema:CreativeWork
134 https://doi.org/10.6028/jres.079a.026 schema:sameAs https://app.dimensions.ai/details/publication/pub.1073600022
135 rdf:type schema:CreativeWork
136 https://www.grid.ac/institutes/grid.412804.b schema:alternateName Toyohashi University of Technology
137 schema:name Department of Environmental and Life Sciences, Graduate School of Engineering, Toyohashi University of Technology, Toyohashi, Aichi, Japan
138 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...