Design of molecule-responsive organic–inorganic hybrid nanoparticles bearing cyclodextrin as ligands View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2015-02

AUTHORS

Akifumi Kawamura, Tomoya Katoh, Tadashi Uragami, Takashi Miyata

ABSTRACT

Novel organic–inorganic hybrid nanoparticles with a bisphenol A (BPA)-responsive hydrogel layer on the surface of SiO2 nanoparticles were prepared via surface-initiated atom transfer radical polymerization of acrylamide (AAm), acryloyl-modified β-cyclodextrin (CD) and N, N′-methylenebisacrylamide. The resulting CD-PAAm/SiO2 nanoparticles underwent a change in size in response to BPA. The BPA-responsive shrinkage of the CD-PAAm/SiO2 nanoparticles was caused by an increase in the crosslinking density of the CD-PAAm hydrogel layer, which resulted from the formation of CD-BPA-CD complexes acting as dynamic crosslinks. The smart functions of BPA-responsive organic–inorganic hybrid nanoparticles can provide useful tools for constructing molecular sensors and adsorption materials. More... »

PAGES

206

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/pj.2014.122

DOI

http://dx.doi.org/10.1038/pj.2014.122

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https://app.dimensions.ai/details/publication/pub.1053418106


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