Bulk heterojunction solar cells with internal quantum efficiency approaching 100% View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-05

AUTHORS

Sung Heum Park, Anshuman Roy, Serge Beaupré, Shinuk Cho, Nelson Coates, Ji Sun Moon, Daniel Moses, Mario Leclerc, Kwanghee Lee, Alan J. Heeger

ABSTRACT

We report the fabrication and measurement of solar cells with 6% power conversion efficiency using the alternating co-polymer, poly[N-9''-hepta-decanyl-2,7-carbazole-alt-5,5-(4',7'-di-2-thienyl-2',1',3'-benzothiadiazole) (PCDTBT) in bulk heterojunction composites with the fullerene derivative [6,6]-phenyl C70-butyric acid methyl ester (PC70BM). The PCDTBT/PC70BM solar cells exhibit the best performance of any bulk heterojunction system studied to date, with JSC = 10.6 mA cm-2, VOC = 0.88 V, FF = 0.66 and e = 6.1% under air mass 1.5 global (AM 1.5 G) irradiation of 100 mW cm-2. The internal quantum efficiency is close to 100%, implying that essentially every absorbed photon results in a separated pair of charge carriers and that all photogenerated carriers are collected at the electrodes. More... »

PAGES

297-302

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/nphoton.2009.69

DOI

http://dx.doi.org/10.1038/nphoton.2009.69

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1010099089


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0912", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Materials Engineering", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Engineering", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "familyName": "Park", 
        "givenName": "Sung Heum", 
        "id": "sg:person.014424073053.67", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014424073053.67"
        ], 
        "type": "Person"
      }, 
      {
        "familyName": "Roy", 
        "givenName": "Anshuman", 
        "id": "sg:person.013324524651.40", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013324524651.40"
        ], 
        "type": "Person"
      }, 
      {
        "familyName": "Beaupr\u00e9", 
        "givenName": "Serge", 
        "id": "sg:person.011641264075.95", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011641264075.95"
        ], 
        "type": "Person"
      }, 
      {
        "familyName": "Cho", 
        "givenName": "Shinuk", 
        "id": "sg:person.012375402375.02", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012375402375.02"
        ], 
        "type": "Person"
      }, 
      {
        "familyName": "Coates", 
        "givenName": "Nelson", 
        "id": "sg:person.01227211413.02", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01227211413.02"
        ], 
        "type": "Person"
      }, 
      {
        "familyName": "Moon", 
        "givenName": "Ji Sun", 
        "id": "sg:person.01246325247.84", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01246325247.84"
        ], 
        "type": "Person"
      }, 
      {
        "familyName": "Moses", 
        "givenName": "Daniel", 
        "id": "sg:person.016711420665.20", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016711420665.20"
        ], 
        "type": "Person"
      }, 
      {
        "familyName": "Leclerc", 
        "givenName": "Mario", 
        "id": "sg:person.01225642072.59", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01225642072.59"
        ], 
        "type": "Person"
      }, 
      {
        "familyName": "Lee", 
        "givenName": "Kwanghee", 
        "id": "sg:person.01257333071.25", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01257333071.25"
        ], 
        "type": "Person"
      }, 
      {
        "familyName": "Heeger", 
        "givenName": "Alan J.", 
        "id": "sg:person.07372145325.11", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07372145325.11"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1021/ja710079w", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000729394"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja710079w", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000729394"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1557/jmr.2004.0252", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006488920"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1557/jmr.2004.0252", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006488920"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1117/12.148451", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006550008"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1117/12.148451", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006550008"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adfm.200701459", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007950968"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adfm.200701459", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007950968"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adfm.200701459", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007950968"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/1616-3028(200102)11:1<15::aid-adfm15>3.0.co;2-a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1008016412"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adma.200602496", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009633230"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja0771989", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009754655"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja0771989", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009754655"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr050149z", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011150456"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr050149z", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011150456"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b306630d", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011595366"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/376498a0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011979108", 
          "https://doi.org/10.1038/376498a0"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b510618b", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012452265"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b510618b", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012452265"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adma.200602653", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012600874"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/1616-3028(200110)11:5<374::aid-adfm374>3.0.co;2-w", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020376593"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s1369-7021(07)70276-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023645238"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nmat1500", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1024504960", 
          "https://doi.org/10.1038/nmat1500"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nmat1500", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1024504960", 
          "https://doi.org/10.1038/nmat1500"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.2836266", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026765437"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adma.200601933", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031698609"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nmat1574", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032069770", 
          "https://doi.org/10.1038/nmat1574"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nmat1574", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032069770", 
          "https://doi.org/10.1038/nmat1574"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adma.200600160", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033066559"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adma.200800982", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034020275"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adfm.200500339", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034894833"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adfm.200500339", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034894833"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adma.200501825", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035897399"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adma.200501825", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035897399"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/nl802821h", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041291955"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/nl802821h", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041291955"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0009-2614(01)00431-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041369195"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adfm.200500211", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042915433"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adfm.200500211", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042915433"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adma.200501717", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045925128"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adma.200501717", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045925128"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adfm.200600489", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048183080"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/anie.200351647", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050218782"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nmat1928", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1051135055", 
          "https://doi.org/10.1038/nmat1928"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00023a041", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055699905"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.1521244", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057715876"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.2718488", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057859980"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.2730746", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057860998"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.2777724", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057866248"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.2816913", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057874665"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.471154", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1058049856"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1088/0026-1394/37/5/52", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1058978344"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.56.4573", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060586240"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.56.4573", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060586240"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.1141711", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1062455975"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.270.5243.1789", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1062551794"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.258.5087.1474", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1111238468"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2009-05", 
    "datePublishedReg": "2009-05-01", 
    "description": "We report the fabrication and measurement of solar cells with 6% power conversion efficiency using the alternating co-polymer, poly[N-9''-hepta-decanyl-2,7-carbazole-alt-5,5-(4',7'-di-2-thienyl-2',1',3'-benzothiadiazole) (PCDTBT) in bulk heterojunction composites with the fullerene derivative [6,6]-phenyl C70-butyric acid methyl ester (PC70BM). The PCDTBT/PC70BM solar cells exhibit the best performance of any bulk heterojunction system studied to date, with JSC = 10.6 mA cm-2, VOC = 0.88 V, FF = 0.66 and e = 6.1% under air mass 1.5 global (AM 1.5 G) irradiation of 100 mW cm-2. The internal quantum efficiency is close to 100%, implying that essentially every absorbed photon results in a separated pair of charge carriers and that all photogenerated carriers are collected at the electrodes.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1038/nphoton.2009.69", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1037430", 
        "issn": [
          "1749-4885", 
          "1749-4893"
        ], 
        "name": "Nature Photonics", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "5", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "3"
      }
    ], 
    "name": "Bulk heterojunction solar cells with internal quantum efficiency approaching 100%", 
    "pagination": "297-302", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "301cdbb5cdb3d844c17aae5c23d4caacee751308636b078f2100d6394482973c"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1038/nphoton.2009.69"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1010099089"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1038/nphoton.2009.69", 
      "https://app.dimensions.ai/details/publication/pub.1010099089"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T09:12", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000338_0000000338/records_47989_00000000.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://www.nature.com/nphoton/journal/v3/n5/full/nphoton.2009.69.html"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1038/nphoton.2009.69'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1038/nphoton.2009.69'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1038/nphoton.2009.69'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1038/nphoton.2009.69'


 

This table displays all metadata directly associated to this object as RDF triples.

238 TRIPLES      21 PREDICATES      68 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1038/nphoton.2009.69 schema:about anzsrc-for:09
2 anzsrc-for:0912
3 schema:author Nec8d638677184fd99e9d57f1352e1388
4 schema:citation sg:pub.10.1038/376498a0
5 sg:pub.10.1038/nmat1500
6 sg:pub.10.1038/nmat1574
7 sg:pub.10.1038/nmat1928
8 https://doi.org/10.1002/1616-3028(200102)11:1<15::aid-adfm15>3.0.co;2-a
9 https://doi.org/10.1002/1616-3028(200110)11:5<374::aid-adfm374>3.0.co;2-w
10 https://doi.org/10.1002/adfm.200500211
11 https://doi.org/10.1002/adfm.200500339
12 https://doi.org/10.1002/adfm.200600489
13 https://doi.org/10.1002/adfm.200701459
14 https://doi.org/10.1002/adma.200501717
15 https://doi.org/10.1002/adma.200501825
16 https://doi.org/10.1002/adma.200600160
17 https://doi.org/10.1002/adma.200601933
18 https://doi.org/10.1002/adma.200602496
19 https://doi.org/10.1002/adma.200602653
20 https://doi.org/10.1002/adma.200800982
21 https://doi.org/10.1002/anie.200351647
22 https://doi.org/10.1016/s0009-2614(01)00431-6
23 https://doi.org/10.1016/s1369-7021(07)70276-6
24 https://doi.org/10.1021/cr050149z
25 https://doi.org/10.1021/ja00023a041
26 https://doi.org/10.1021/ja0771989
27 https://doi.org/10.1021/ja710079w
28 https://doi.org/10.1021/nl802821h
29 https://doi.org/10.1039/b306630d
30 https://doi.org/10.1039/b510618b
31 https://doi.org/10.1063/1.1521244
32 https://doi.org/10.1063/1.2718488
33 https://doi.org/10.1063/1.2730746
34 https://doi.org/10.1063/1.2777724
35 https://doi.org/10.1063/1.2816913
36 https://doi.org/10.1063/1.2836266
37 https://doi.org/10.1063/1.471154
38 https://doi.org/10.1088/0026-1394/37/5/52
39 https://doi.org/10.1103/physrevb.56.4573
40 https://doi.org/10.1117/12.148451
41 https://doi.org/10.1126/science.1141711
42 https://doi.org/10.1126/science.258.5087.1474
43 https://doi.org/10.1126/science.270.5243.1789
44 https://doi.org/10.1557/jmr.2004.0252
45 schema:datePublished 2009-05
46 schema:datePublishedReg 2009-05-01
47 schema:description We report the fabrication and measurement of solar cells with 6% power conversion efficiency using the alternating co-polymer, poly[N-9''-hepta-decanyl-2,7-carbazole-alt-5,5-(4',7'-di-2-thienyl-2',1',3'-benzothiadiazole) (PCDTBT) in bulk heterojunction composites with the fullerene derivative [6,6]-phenyl C70-butyric acid methyl ester (PC70BM). The PCDTBT/PC70BM solar cells exhibit the best performance of any bulk heterojunction system studied to date, with JSC = 10.6 mA cm-2, VOC = 0.88 V, FF = 0.66 and e = 6.1% under air mass 1.5 global (AM 1.5 G) irradiation of 100 mW cm-2. The internal quantum efficiency is close to 100%, implying that essentially every absorbed photon results in a separated pair of charge carriers and that all photogenerated carriers are collected at the electrodes.
48 schema:genre research_article
49 schema:inLanguage en
50 schema:isAccessibleForFree false
51 schema:isPartOf N80d7894ed6884c94b89b1415130c6ad3
52 Ndc725bad3e0a4aeab01fe53a4bdcfd10
53 sg:journal.1037430
54 schema:name Bulk heterojunction solar cells with internal quantum efficiency approaching 100%
55 schema:pagination 297-302
56 schema:productId N384e1ebe467242ee8470961dc75a642b
57 Nca5df3d9e09746308246e39ba78a12f8
58 Nec2fbfd82942455b94124dd042963c7c
59 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010099089
60 https://doi.org/10.1038/nphoton.2009.69
61 schema:sdDatePublished 2019-04-11T09:12
62 schema:sdLicense https://scigraph.springernature.com/explorer/license/
63 schema:sdPublisher Ndb9c3f5abb444183a3946115166f4a26
64 schema:url http://www.nature.com/nphoton/journal/v3/n5/full/nphoton.2009.69.html
65 sgo:license sg:explorer/license/
66 sgo:sdDataset articles
67 rdf:type schema:ScholarlyArticle
68 N3566b8c6668d462ebabe6cee79885a46 rdf:first sg:person.016711420665.20
69 rdf:rest N53b343119de54acba24a5bb78dd89813
70 N384e1ebe467242ee8470961dc75a642b schema:name readcube_id
71 schema:value 301cdbb5cdb3d844c17aae5c23d4caacee751308636b078f2100d6394482973c
72 rdf:type schema:PropertyValue
73 N46273f2200b44be0b0de1e0afc5250d9 rdf:first sg:person.011641264075.95
74 rdf:rest Ne63f692e05eb46c299e36529021370c5
75 N53b343119de54acba24a5bb78dd89813 rdf:first sg:person.01225642072.59
76 rdf:rest Ne385b1eb84eb40d1aae911a517685ca5
77 N80d7894ed6884c94b89b1415130c6ad3 schema:issueNumber 5
78 rdf:type schema:PublicationIssue
79 Nb6819be869864e729e82b5b84151095b rdf:first sg:person.01246325247.84
80 rdf:rest N3566b8c6668d462ebabe6cee79885a46
81 Nca5df3d9e09746308246e39ba78a12f8 schema:name doi
82 schema:value 10.1038/nphoton.2009.69
83 rdf:type schema:PropertyValue
84 Nd64855493b274f928688642383cfa11f rdf:first sg:person.07372145325.11
85 rdf:rest rdf:nil
86 Ndb9c3f5abb444183a3946115166f4a26 schema:name Springer Nature - SN SciGraph project
87 rdf:type schema:Organization
88 Ndc725bad3e0a4aeab01fe53a4bdcfd10 schema:volumeNumber 3
89 rdf:type schema:PublicationVolume
90 Ne385b1eb84eb40d1aae911a517685ca5 rdf:first sg:person.01257333071.25
91 rdf:rest Nd64855493b274f928688642383cfa11f
92 Ne63f692e05eb46c299e36529021370c5 rdf:first sg:person.012375402375.02
93 rdf:rest Nf17018bb0a1743efbabcd0bbc9a15676
94 Nec2fbfd82942455b94124dd042963c7c schema:name dimensions_id
95 schema:value pub.1010099089
96 rdf:type schema:PropertyValue
97 Nec8d638677184fd99e9d57f1352e1388 rdf:first sg:person.014424073053.67
98 rdf:rest Nef723f0c679d4e2695d6be6c2192a40c
99 Nef723f0c679d4e2695d6be6c2192a40c rdf:first sg:person.013324524651.40
100 rdf:rest N46273f2200b44be0b0de1e0afc5250d9
101 Nf17018bb0a1743efbabcd0bbc9a15676 rdf:first sg:person.01227211413.02
102 rdf:rest Nb6819be869864e729e82b5b84151095b
103 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
104 schema:name Engineering
105 rdf:type schema:DefinedTerm
106 anzsrc-for:0912 schema:inDefinedTermSet anzsrc-for:
107 schema:name Materials Engineering
108 rdf:type schema:DefinedTerm
109 sg:journal.1037430 schema:issn 1749-4885
110 1749-4893
111 schema:name Nature Photonics
112 rdf:type schema:Periodical
113 sg:person.011641264075.95 schema:familyName Beaupré
114 schema:givenName Serge
115 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011641264075.95
116 rdf:type schema:Person
117 sg:person.01225642072.59 schema:familyName Leclerc
118 schema:givenName Mario
119 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01225642072.59
120 rdf:type schema:Person
121 sg:person.01227211413.02 schema:familyName Coates
122 schema:givenName Nelson
123 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01227211413.02
124 rdf:type schema:Person
125 sg:person.012375402375.02 schema:familyName Cho
126 schema:givenName Shinuk
127 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012375402375.02
128 rdf:type schema:Person
129 sg:person.01246325247.84 schema:familyName Moon
130 schema:givenName Ji Sun
131 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01246325247.84
132 rdf:type schema:Person
133 sg:person.01257333071.25 schema:familyName Lee
134 schema:givenName Kwanghee
135 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01257333071.25
136 rdf:type schema:Person
137 sg:person.013324524651.40 schema:familyName Roy
138 schema:givenName Anshuman
139 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013324524651.40
140 rdf:type schema:Person
141 sg:person.014424073053.67 schema:familyName Park
142 schema:givenName Sung Heum
143 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014424073053.67
144 rdf:type schema:Person
145 sg:person.016711420665.20 schema:familyName Moses
146 schema:givenName Daniel
147 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016711420665.20
148 rdf:type schema:Person
149 sg:person.07372145325.11 schema:familyName Heeger
150 schema:givenName Alan J.
151 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07372145325.11
152 rdf:type schema:Person
153 sg:pub.10.1038/376498a0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011979108
154 https://doi.org/10.1038/376498a0
155 rdf:type schema:CreativeWork
156 sg:pub.10.1038/nmat1500 schema:sameAs https://app.dimensions.ai/details/publication/pub.1024504960
157 https://doi.org/10.1038/nmat1500
158 rdf:type schema:CreativeWork
159 sg:pub.10.1038/nmat1574 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032069770
160 https://doi.org/10.1038/nmat1574
161 rdf:type schema:CreativeWork
162 sg:pub.10.1038/nmat1928 schema:sameAs https://app.dimensions.ai/details/publication/pub.1051135055
163 https://doi.org/10.1038/nmat1928
164 rdf:type schema:CreativeWork
165 https://doi.org/10.1002/1616-3028(200102)11:1<15::aid-adfm15>3.0.co;2-a schema:sameAs https://app.dimensions.ai/details/publication/pub.1008016412
166 rdf:type schema:CreativeWork
167 https://doi.org/10.1002/1616-3028(200110)11:5<374::aid-adfm374>3.0.co;2-w schema:sameAs https://app.dimensions.ai/details/publication/pub.1020376593
168 rdf:type schema:CreativeWork
169 https://doi.org/10.1002/adfm.200500211 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042915433
170 rdf:type schema:CreativeWork
171 https://doi.org/10.1002/adfm.200500339 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034894833
172 rdf:type schema:CreativeWork
173 https://doi.org/10.1002/adfm.200600489 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048183080
174 rdf:type schema:CreativeWork
175 https://doi.org/10.1002/adfm.200701459 schema:sameAs https://app.dimensions.ai/details/publication/pub.1007950968
176 rdf:type schema:CreativeWork
177 https://doi.org/10.1002/adma.200501717 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045925128
178 rdf:type schema:CreativeWork
179 https://doi.org/10.1002/adma.200501825 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035897399
180 rdf:type schema:CreativeWork
181 https://doi.org/10.1002/adma.200600160 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033066559
182 rdf:type schema:CreativeWork
183 https://doi.org/10.1002/adma.200601933 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031698609
184 rdf:type schema:CreativeWork
185 https://doi.org/10.1002/adma.200602496 schema:sameAs https://app.dimensions.ai/details/publication/pub.1009633230
186 rdf:type schema:CreativeWork
187 https://doi.org/10.1002/adma.200602653 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012600874
188 rdf:type schema:CreativeWork
189 https://doi.org/10.1002/adma.200800982 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034020275
190 rdf:type schema:CreativeWork
191 https://doi.org/10.1002/anie.200351647 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050218782
192 rdf:type schema:CreativeWork
193 https://doi.org/10.1016/s0009-2614(01)00431-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041369195
194 rdf:type schema:CreativeWork
195 https://doi.org/10.1016/s1369-7021(07)70276-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023645238
196 rdf:type schema:CreativeWork
197 https://doi.org/10.1021/cr050149z schema:sameAs https://app.dimensions.ai/details/publication/pub.1011150456
198 rdf:type schema:CreativeWork
199 https://doi.org/10.1021/ja00023a041 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055699905
200 rdf:type schema:CreativeWork
201 https://doi.org/10.1021/ja0771989 schema:sameAs https://app.dimensions.ai/details/publication/pub.1009754655
202 rdf:type schema:CreativeWork
203 https://doi.org/10.1021/ja710079w schema:sameAs https://app.dimensions.ai/details/publication/pub.1000729394
204 rdf:type schema:CreativeWork
205 https://doi.org/10.1021/nl802821h schema:sameAs https://app.dimensions.ai/details/publication/pub.1041291955
206 rdf:type schema:CreativeWork
207 https://doi.org/10.1039/b306630d schema:sameAs https://app.dimensions.ai/details/publication/pub.1011595366
208 rdf:type schema:CreativeWork
209 https://doi.org/10.1039/b510618b schema:sameAs https://app.dimensions.ai/details/publication/pub.1012452265
210 rdf:type schema:CreativeWork
211 https://doi.org/10.1063/1.1521244 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057715876
212 rdf:type schema:CreativeWork
213 https://doi.org/10.1063/1.2718488 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057859980
214 rdf:type schema:CreativeWork
215 https://doi.org/10.1063/1.2730746 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057860998
216 rdf:type schema:CreativeWork
217 https://doi.org/10.1063/1.2777724 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057866248
218 rdf:type schema:CreativeWork
219 https://doi.org/10.1063/1.2816913 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057874665
220 rdf:type schema:CreativeWork
221 https://doi.org/10.1063/1.2836266 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026765437
222 rdf:type schema:CreativeWork
223 https://doi.org/10.1063/1.471154 schema:sameAs https://app.dimensions.ai/details/publication/pub.1058049856
224 rdf:type schema:CreativeWork
225 https://doi.org/10.1088/0026-1394/37/5/52 schema:sameAs https://app.dimensions.ai/details/publication/pub.1058978344
226 rdf:type schema:CreativeWork
227 https://doi.org/10.1103/physrevb.56.4573 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060586240
228 rdf:type schema:CreativeWork
229 https://doi.org/10.1117/12.148451 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006550008
230 rdf:type schema:CreativeWork
231 https://doi.org/10.1126/science.1141711 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062455975
232 rdf:type schema:CreativeWork
233 https://doi.org/10.1126/science.258.5087.1474 schema:sameAs https://app.dimensions.ai/details/publication/pub.1111238468
234 rdf:type schema:CreativeWork
235 https://doi.org/10.1126/science.270.5243.1789 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062551794
236 rdf:type schema:CreativeWork
237 https://doi.org/10.1557/jmr.2004.0252 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006488920
238 rdf:type schema:CreativeWork
 




Preview window. Press ESC to close (or click here)


...