Engineering the surface structure of MoS2 to preferentially expose active edge sites for electrocatalysis View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-11

AUTHORS

Jakob Kibsgaard, Zhebo Chen, Benjamin N. Reinecke, Thomas F. Jaramillo

ABSTRACT

Controlling surface structure at the atomic scale is paramount to developing effective catalysts. For example, the edge sites of MoS(2) are highly catalytically active and are thus preferred at the catalyst surface over MoS(2) basal planes, which are inert. However, thermodynamics favours the presence of the basal plane, limiting the number of active sites at the surface. Herein, we engineer the surface structure of MoS(2) to preferentially expose edge sites to effect improved catalysis by successfully synthesizing contiguous large-area thin films of a highly ordered double-gyroid MoS(2) bicontinuous network with nanoscaled pores. The high surface curvature of this catalyst mesostructure exposes a large fraction of edge sites, which, along with its high surface area, leads to excellent activity for electrocatalytic hydrogen evolution. This work elucidates how morphological control of materials at the nanoscale can significantly impact the surface structure at the atomic scale, enabling new opportunities for enhancing surface properties for catalysis and other important technological applications. More... »

PAGES

963

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/nmat3439

DOI

http://dx.doi.org/10.1038/nmat3439

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1011433921

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/23042413


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This table displays all metadata directly associated to this object as RDF triples.

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