Atomic origins of the high catalytic activity of nanoporous gold View Full Text


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Article Info

DATE

2012-08-12

AUTHORS

Takeshi Fujita, Pengfei Guan, Keith McKenna, Xingyou Lang, Akihiko Hirata, Ling Zhang, Tomoharu Tokunaga, Shigeo Arai, Yuta Yamamoto, Nobuo Tanaka, Yoshifumi Ishikawa, Naoki Asao, Yoshinori Yamamoto, Jonah Erlebacher, Mingwei Chen

ABSTRACT

Distinct from inert bulk gold, nanoparticulate gold has been found to possess remarkable catalytic activity towards oxidation reactions. The catalytic performance of nanoparticulate gold strongly depends on size and support, and catalytic activity usually cannot be observed at characteristic sizes larger than 5 nm. Interestingly, significant catalytic activity can be retained in dealloyed nanoporous gold (NPG) even when its feature lengths are larger than 30 nm. Here we report atomic insights of the NPG catalysis, characterized by spherical-aberration-corrected transmission electron microscopy (TEM) and environmental TEM. A high density of atomic steps and kinks is observed on the curved surfaces of NPG, comparable to 3–5 nm nanoparticles, which are stabilized by hyperboloid-like gold ligaments. In situ TEM observations provide compelling evidence that the surface defects are active sites for the catalytic oxidation of CO and residual Ag stabilizes the atomic steps by suppressing {111} faceting kinetics. More... »

PAGES

775-780

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/nmat3391

DOI

http://dx.doi.org/10.1038/nmat3391

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1044918281

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/22886067


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