A 3.90 V iron-based fluorosulphate material for lithium-ion batteries crystallizing in the triplite structure View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-10

AUTHORS

P. Barpanda, M. Ati, B. C. Melot, G. Rousse, J-N. Chotard, M-L. Doublet, M. T. Sougrati, S. A. Corr, J-C. Jumas, J-M. Tarascon

ABSTRACT

Li-ion batteries have empowered consumer electronics and are now seen as the best choice to propel forward the development of eco-friendly (hybrid) electric vehicles. To enhance the energy density, an intensive search has been made for new polyanionic compounds that have a higher potential for the Fe²⁺/Fe³⁺ redox couple. Herein we push this potential to 3.90 V in a new polyanionic material that crystallizes in the triplite structure by substituting as little as 5 atomic per cent of Mn for Fe in Li(Fe(1-δ)Mn(δ))SO₄F. Not only is this the highest voltage reported so far for the Fe²⁺/Fe³⁺ redox couple, exceeding that of LiFePO₄ by 450 mV, but this new triplite phase is capable of reversibly releasing and reinserting 0.7-0.8 Li ions with a volume change of 0.6% (compared with 7 and 10% for LiFePO₄ and LiFeSO₄F respectively), to give a capacity of ~125 mA h g⁻¹. More... »

PAGES

772

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/nmat3093

DOI

http://dx.doi.org/10.1038/nmat3093

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1051411835

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/21857675


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