Free-standing nanoparticle superlattice sheets controlled by DNA View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-06

AUTHORS

Wenlong Cheng, Michael J. Campolongo, Judy J. Cha, Shawn J. Tan, Christopher C. Umbach, David A. Muller, Dan Luo

ABSTRACT

Free-standing nanoparticle superlattices (suspended highly ordered nanoparticle arrays) are ideal for designing metamaterials and nanodevices free of substrate-induced electromagnetic interference. Here, we report on the first DNA-based route towards monolayered free-standing nanoparticle superlattices. In an unconventional way, DNA was used as a 'dry ligand' in a microhole-confined, drying-mediated self-assembly process. Without the requirement of specific Watson-Crick base-pairing, we obtained discrete, free-standing superlattice sheets in which both structure (inter-particle spacings) and functional properties (plasmonic and mechanical) can be rationally controlled by adjusting DNA length. In particular, the edge-to-edge inter-particle spacing for monolayered superlattice sheets can be tuned up to 20 nm, which is a much wider range than has been achieved with alkyl molecular ligands. Our method opens a simple yet efficient avenue towards the assembly of artificial nanoparticle solids in their ultimate thickness limit--a promising step that may enable the integration of free-standing superlattices into solid-state nanodevices. More... »

PAGES

519

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/nmat2440

DOI

http://dx.doi.org/10.1038/nmat2440

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1038029234

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/19404241


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