Two Ih-symmetry-breaking C60 isomers stabilized by chlorination View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2008-10

AUTHORS

Yuan-Zhi Tan, Zhao-Jiang Liao, Zhuo-Zhen Qian, Rui-Ting Chen, Xin Wu, Hua Liang, Xiao Han, Feng Zhu, Sheng-Jun Zhou, Zhiping Zheng, Xin Lu, Su-Yuan Xie, Rong-Bin Huang, Lan-Sun Zheng

ABSTRACT

One abiding surprise in fullerene science is that I(h)-symmetric buckminsterfullerene C(60) (ref. 1) (I(h)-C(60) or (#1,812)C(60), the nomenclature specified by symmetry or by Fowler's spiral algorithm) remains the sole C(60) species experimentally available. Setting it apart from the other 1,811 topological isomers (isobuckminsterfullerenes) is its exclusive conformity with the isolated-pentagon rule, which states that stable fullerenes have isolated pentagons. Although gas-phase existence of isobuckminsterfullerenes has long been suspected, synthetic efforts have yet to yield successful results. Here, we report the realization of two isobuckminsterfullerenes by means of chlorination of the respective C(2v)- and C(s)-symmetric C(60) cages. These chlorinated species, (#1,809)C(60)Cl(8)(1) and (#1,804)C(60)Cl(12)(2), were isolated in experimentally useful yields. Structural characterization by crystallography unambiguously established the unique pentagon-pentagon ring fusions. These distinct structural features are directly responsible for the regioselectivity observed in subsequent substitution of chlorines, and also render these unprecedented derivatives of C(60) isomers important for resolving the long-standing puzzle of fullerene formation by the Stone-Wales transformation scheme. More... »

PAGES

790

Journal

TITLE

Nature Materials

ISSUE

10

VOLUME

7

Author Affiliations

From Grant

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/nmat2275

DOI

http://dx.doi.org/10.1038/nmat2275

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1051255553

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/18776890


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