Self-assembly of metal–polymer analogues of amphiphilic triblock copolymers View Full Text


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Article Info

DATE

2007-08

AUTHORS

Zhihong Nie, Daniele Fava, Eugenia Kumacheva, Shan Zou, Gilbert C Walker, Michael Rubinstein

ABSTRACT

Organized arrays of anisotropic nanoparticles show electronic and optical properties that originate from the coupling of shape-dependent properties of the individual nanorods. The organization of nanorods in a controllable and predictable way provides a route to the fabrication of new materials and functional devices. So far, significant progress has been achieved in the self-assembly of nanorod arrays, yet the realization of a range of different structures requires changing the surface chemistry of the nanoparticles. We organized metal nanorods in structures with varying geometries by using a striking analogy between amphiphilic ABA triblock copolymers and the hydrophilic nanorods tethered with hydrophobic polymer chains at both ends. The self-assembly was tuneable and reversible and it was achieved solely by changing the solvent quality for the constituent blocks. This approach provides a new route to the organization of anisotropic nanoparticles by using the strategies that are established for the self-assembly of block copolymers. More... »

PAGES

609-614

References to SciGraph publications

  • 2006-07. Curved polymer and polyelectrolyte brushes beyond the Daoud-Cotton model in THE EUROPEAN PHYSICAL JOURNAL E
  • 2003-10. Multifunctional nanorods for gene delivery in NATURE MATERIALS
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1038/nmat1954

    DOI

    http://dx.doi.org/10.1038/nmat1954

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    PUBMED

    https://www.ncbi.nlm.nih.gov/pubmed/17618291


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