Hierarchical nanoparticle assemblies formed by decorating breath figures View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2004-05

AUTHORS

Alexander Böker, Yao Lin, Kristen Chiapperini, Reina Horowitz, Mike Thompson, Vincent Carreon, Ting Xu, Clarissa Abetz, Habib Skaff, A. D. Dinsmore, Todd Emrick, Thomas P. Russell

ABSTRACT

The combination of two self-assembly processes on different length scales leads to the formation of hierarchically structured nanoparticle arrays. Here, the formation of spherical cavities, or 'breath figures'-made by the condensation of micrometre-sized water droplets on the surface of a polymer solution-that self-assemble into a well-ordered hexagonal array, is combined with the self-assembly of CdSe nanoparticles at the polymer solution-water droplet interface. Complete evaporation of the solvent and water confines the particle assembly to an array of spherical cavities and allows for ex situ investigation. Fluorescence confocal, transmission electron and scanning electron microscope images show the preferential segregation of the CdSe nanoparticles to the polymer solution-water interface where they form a 5-7-nm-thick layer, thus functionalizing the walls of the holes. This process opens a new route to fabricating highly functionalized ordered microarrays of nanoparticles, potentially useful in sensory, separation membrane or catalytic applications. More... »

PAGES

302-306

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/nmat1110

DOI

http://dx.doi.org/10.1038/nmat1110

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1043691938

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/15098023


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HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1038/nmat1110'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1038/nmat1110'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1038/nmat1110'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1038/nmat1110'


 

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