Ontology type: schema:ScholarlyArticle
2017-01
AUTHORSAlexis Grimaud, Arnaud Demortière, Matthieu Saubanère, Walid Dachraoui, Martial Duchamp, Marie-Liesse Doublet, Jean-Marie Tarascon
ABSTRACTThe oxygen evolution reaction (OER) is of prime importance in multiple energy storage devices; however, deeper mechanistic understanding is required to design enhanced electrocatalysts for the reaction. Current understanding of the OER mechanism based on oxygen adsorption on a metallic surface site fails to fully explain the activity of iridium and ruthenium oxide surfaces, and the drastic surface reconstruction observed for the most active OER catalysts. Here we demonstrate, using La2LiIrO6 as a model catalyst, that the exceptionally high activity found for Ir-based catalysts arises from the formation of active surface oxygen atoms that act as electrophilic centres for water to react. Moreover, with the help of transmission electron microscopy, we observe drastic surface reconstruction and iridium migration from the bulk to the surface. Therefore, we establish a correlation between surface activity and surface stability for OER catalysts that is rooted in the formation of surface reactive oxygen. More... »
PAGESnenergy2016189
http://scigraph.springernature.com/pub.10.1038/nenergy.2016.189
DOIhttp://dx.doi.org/10.1038/nenergy.2016.189
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1041401652
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Physical Chemistry (incl. Structural)",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "Research Network on Electrochemical Energy Storage",
"id": "https://www.grid.ac/institutes/grid.494528.6",
"name": [
"Chimie du Solide et de l\u2019Energie, UMR 8260, Coll\u00e8ge de France, 75231 Paris Cedex 05, France",
"R\u00e9seau sur le Stockage Electrochimique de l\u2019Energie (RS2E), FR CNRS 3459, 80039 Amiens Cedex, France"
],
"type": "Organization"
},
"familyName": "Grimaud",
"givenName": "Alexis",
"id": "sg:person.01312507235.53",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01312507235.53"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Laboratoire de R\u00e9activit\u00e9 et Chimie des Solides",
"id": "https://www.grid.ac/institutes/grid.463728.c",
"name": [
"R\u00e9seau sur le Stockage Electrochimique de l\u2019Energie (RS2E), FR CNRS 3459, 80039 Amiens Cedex, France",
"Laboratoire de R\u00e9activit\u00e9 et Chimie des Solides, UMR CNRS 7314, 33 Rue Saint Leu, 80039 Amiens Cedex, France"
],
"type": "Organization"
},
"familyName": "Demorti\u00e8re",
"givenName": "Arnaud",
"id": "sg:person.013011611633.06",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013011611633.06"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Institut Charles Gerhardt",
"id": "https://www.grid.ac/institutes/grid.462034.7",
"name": [
"Chimie du Solide et de l\u2019Energie, UMR 8260, Coll\u00e8ge de France, 75231 Paris Cedex 05, France",
"R\u00e9seau sur le Stockage Electrochimique de l\u2019Energie (RS2E), FR CNRS 3459, 80039 Amiens Cedex, France",
"Institut Charles Gerhardt, CNRS UMR 5253, Universit\u00e9 Montpellier, Place E. Bataillon, 34095 Montpellier, France"
],
"type": "Organization"
},
"familyName": "Sauban\u00e8re",
"givenName": "Matthieu",
"id": "sg:person.01140055126.45",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01140055126.45"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Laboratoire de R\u00e9activit\u00e9 et Chimie des Solides",
"id": "https://www.grid.ac/institutes/grid.463728.c",
"name": [
"R\u00e9seau sur le Stockage Electrochimique de l\u2019Energie (RS2E), FR CNRS 3459, 80039 Amiens Cedex, France",
"Laboratoire de R\u00e9activit\u00e9 et Chimie des Solides, UMR CNRS 7314, 33 Rue Saint Leu, 80039 Amiens Cedex, France"
],
"type": "Organization"
},
"familyName": "Dachraoui",
"givenName": "Walid",
"id": "sg:person.0723101726.51",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0723101726.51"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Forschungszentrum J\u00fclich",
"id": "https://www.grid.ac/institutes/grid.8385.6",
"name": [
"Ernst Ruska-Centre for Microscopy and Spectroscopy with Electrons (ER-C) and Peter Gr\u00fcnberg Institute (PGI), Forschungszentrum J\u00fclich, 52428 J\u00fclich, Germany"
],
"type": "Organization"
},
"familyName": "Duchamp",
"givenName": "Martial",
"id": "sg:person.01335545014.58",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01335545014.58"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Institut Charles Gerhardt",
"id": "https://www.grid.ac/institutes/grid.462034.7",
"name": [
"R\u00e9seau sur le Stockage Electrochimique de l\u2019Energie (RS2E), FR CNRS 3459, 80039 Amiens Cedex, France",
"Institut Charles Gerhardt, CNRS UMR 5253, Universit\u00e9 Montpellier, Place E. Bataillon, 34095 Montpellier, France"
],
"type": "Organization"
},
"familyName": "Doublet",
"givenName": "Marie-Liesse",
"id": "sg:person.014247162643.07",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014247162643.07"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Sorbonne University",
"id": "https://www.grid.ac/institutes/grid.462844.8",
"name": [
"Chimie du Solide et de l\u2019Energie, UMR 8260, Coll\u00e8ge de France, 75231 Paris Cedex 05, France",
"R\u00e9seau sur le Stockage Electrochimique de l\u2019Energie (RS2E), FR CNRS 3459, 80039 Amiens Cedex, France",
"ALISTORE-European Research Institute, FR CNRS 3104, 80039 Amiens, France",
"Sorbonne Universit\u00e9s\u2014UPMC Univ Paris 06, 75005 Paris, France"
],
"type": "Organization"
},
"familyName": "Tarascon",
"givenName": "Jean-Marie",
"id": "sg:person.01364322774.51",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01364322774.51"
],
"type": "Person"
}
],
"citation": [
{
"id": "https://doi.org/10.1016/s0022-0728(80)80084-2",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1000755180"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1126/science.aac8260",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1001033756"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/nmat4551",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1001045037",
"https://doi.org/10.1038/nmat4551"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/s0022-0728(79)80299-5",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1002124064"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1126/science.1212858",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1002273528"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/ncomms3439",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1004505020",
"https://doi.org/10.1038/ncomms3439"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/nmat3699",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1004852838",
"https://doi.org/10.1038/nmat3699"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1039/c3sc50205h",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1010504875"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/cctc.201000397",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1015510977"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/cctc.201000397",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1015510977"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/ncomms5191",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1016119570",
"https://doi.org/10.1038/ncomms5191"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1039/c4sc00975d",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1016771634"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1149/1.2100742",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1020370460"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1149/1.2115565",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1021980084"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/jp202489s",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1029111413"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/jp202489s",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1029111413"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/jz2016507",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1030883592"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1039/c0cp02875d",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1033118310"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/srep12167",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1033860478",
"https://doi.org/10.1038/srep12167"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/cctc.201000126",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1034718850"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/cctc.201000126",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1034718850"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/jcc.23424",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1038212482"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/anie.201406455",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1038556101"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1039/c5ee03048j",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1038628627"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0025-5408(80)90051-3",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1038629294"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0025-5408(80)90051-3",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1038629294"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1039/c2sc21601a",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1039565955"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1149/1.3456630",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1039573145"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/ncomms9249",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1041458038",
"https://doi.org/10.1038/ncomms9249"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/jacs.5b07788",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1041704186"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.cattod.2015.10.006",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1042987159"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1149/1.2129762",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1043339160"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.cattod.2015.08.014",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1044239260"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1039/c4ee03869j",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1046768884"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0022-0728(87)85237-3",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1047458532"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/j.elecom.2007.05.008",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1047726166"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0254-0584(86)90045-3",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1047869582"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0254-0584(86)90045-3",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1047869582"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1080/08957959608240465",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1051458427"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/cctc.201402194",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1052060573"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/cm502201z",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1053893608"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/cm403785q",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1053994002"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/acs.jpcc.5b01832",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055108392"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/acscatal.5b02432",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055133891"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ic701972n",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055582391"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ic701972n",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055582391"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/j100135a014",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055654428"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ja106102b",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055848126"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ja106102b",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055848126"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ja108588y",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055848676"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/ja108588y",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055848676"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/jp3126768",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056093327"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/jp502970r",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056100611"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/jz301414z",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056134724"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/om400658a",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056278778"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevb.45.13244",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1060560884"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevb.45.13244",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1060560884"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevb.47.558",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1060566310"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevb.47.558",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1060566310"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevb.54.11169",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1060581262"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevb.54.11169",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1060581262"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevb.56.1354",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1060585611"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevb.56.1354",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1060585611"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevb.57.1505",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1060587642"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1103/physrevb.57.1505",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1060587642"
],
"type": "CreativeWork"
}
],
"datePublished": "2017-01",
"datePublishedReg": "2017-01-01",
"description": "The oxygen evolution reaction (OER) is of prime importance in multiple energy storage devices; however, deeper mechanistic understanding is required to design enhanced electrocatalysts for the reaction. Current understanding of the OER mechanism based on oxygen adsorption on a metallic surface site fails to fully explain the activity of iridium and ruthenium oxide surfaces, and the drastic surface reconstruction observed for the most active OER catalysts. Here we demonstrate, using La2LiIrO6 as a model catalyst, that the exceptionally high activity found for Ir-based catalysts arises from the formation of active surface oxygen atoms that act as electrophilic centres for water to react. Moreover, with the help of transmission electron microscopy, we observe drastic surface reconstruction and iridium migration from the bulk to the surface. Therefore, we establish a correlation between surface activity and surface stability for OER catalysts that is rooted in the formation of surface reactive oxygen.",
"genre": "research_article",
"id": "sg:pub.10.1038/nenergy.2016.189",
"inLanguage": [
"en"
],
"isAccessibleForFree": false,
"isFundedItemOf": [
{
"id": "sg:grant.3797650",
"type": "MonetaryGrant"
},
{
"id": "sg:grant.4273984",
"type": "MonetaryGrant"
}
],
"isPartOf": [
{
"id": "sg:journal.1136447",
"issn": [
"2058-7546"
],
"name": "Nature Energy",
"type": "Periodical"
},
{
"issueNumber": "1",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "2"
}
],
"name": "Activation of surface oxygen sites on an iridium-based model catalyst for the oxygen evolution reaction",
"pagination": "nenergy2016189",
"productId": [
{
"name": "readcube_id",
"type": "PropertyValue",
"value": [
"c539afdb0b155866c8fb2242115f4bbce02c0d52e49c2529ae84392832603f8c"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1038/nenergy.2016.189"
]
},
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1041401652"
]
}
],
"sameAs": [
"https://doi.org/10.1038/nenergy.2016.189",
"https://app.dimensions.ai/details/publication/pub.1041401652"
],
"sdDataset": "articles",
"sdDatePublished": "2019-04-10T15:56",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8664_00000537.jsonl",
"type": "ScholarlyArticle",
"url": "http://www.nature.com/articles/nenergy2016189"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1038/nenergy.2016.189'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1038/nenergy.2016.189'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1038/nenergy.2016.189'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1038/nenergy.2016.189'
This table displays all metadata directly associated to this object as RDF triples.
287 TRIPLES
21 PREDICATES
79 URIs
19 LITERALS
7 BLANK NODES