Evidence of covalent synergy in silicon–sulfur–graphene yielding highly efficient and long-life lithium-ion batteries View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2015-12

AUTHORS

Fathy M. Hassan, Rasim Batmaz, Jingde Li, Xiaolei Wang, Xingcheng Xiao, Aiping Yu, Zhongwei Chen

ABSTRACT

Silicon has the potential to revolutionize the energy storage capacities of lithium-ion batteries to meet the ever increasing power demands of next generation technologies. To avoid the operational stability problems of silicon-based anodes, we propose synergistic physicochemical alteration of electrode structures during their design. This capitalizes on covalent interaction of Si nanoparticles with sulfur-doped graphene and with cyclized polyacrylonitrile to provide a robust nanoarchitecture. This hierarchical structure stabilized the solid electrolyte interphase leading to superior reversible capacity of over 1,000 mAh g(-1) for 2,275 cycles at 2 A g(-1). Furthermore, the nanoarchitectured design lowered the contact of the electrolyte to the electrode leading to not only high coulombic efficiency of 99.9% but also maintaining high stability even with high electrode loading associated with 3.4 mAh cm(-2). The excellent performance combined with the simplistic, scalable and non-hazardous approach render the process as a very promising candidate for Li-ion battery technology. More... »

PAGES

8597

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/ncomms9597

DOI

http://dx.doi.org/10.1038/ncomms9597

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1002522247

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/26497228


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "University of Waterloo", 
          "id": "https://www.grid.ac/institutes/grid.46078.3d", 
          "name": [
            "Department of Chemical Engineering, University of Waterloo, Waterloo, Ontario, Canada N2L3G1"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Hassan", 
        "givenName": "Fathy M.", 
        "id": "sg:person.0776643741.90", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0776643741.90"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Waterloo", 
          "id": "https://www.grid.ac/institutes/grid.46078.3d", 
          "name": [
            "Department of Chemical Engineering, University of Waterloo, Waterloo, Ontario, Canada N2L3G1"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Batmaz", 
        "givenName": "Rasim", 
        "id": "sg:person.013500625471.38", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013500625471.38"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Waterloo", 
          "id": "https://www.grid.ac/institutes/grid.46078.3d", 
          "name": [
            "Department of Chemical Engineering, University of Waterloo, Waterloo, Ontario, Canada N2L3G1"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Li", 
        "givenName": "Jingde", 
        "id": "sg:person.016465447565.85", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016465447565.85"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Waterloo", 
          "id": "https://www.grid.ac/institutes/grid.46078.3d", 
          "name": [
            "Department of Chemical Engineering, University of Waterloo, Waterloo, Ontario, Canada N2L3G1"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Wang", 
        "givenName": "Xiaolei", 
        "id": "sg:person.01372502401.05", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01372502401.05"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Chemical and Materials Systems, General Motors Global Research and Development Center, Warren, Michigan 48090, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Xiao", 
        "givenName": "Xingcheng", 
        "id": "sg:person.01236465500.13", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01236465500.13"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Waterloo", 
          "id": "https://www.grid.ac/institutes/grid.46078.3d", 
          "name": [
            "Department of Chemical Engineering, University of Waterloo, Waterloo, Ontario, Canada N2L3G1"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Yu", 
        "givenName": "Aiping", 
        "id": "sg:person.01137424352.94", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01137424352.94"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Waterloo", 
          "id": "https://www.grid.ac/institutes/grid.46078.3d", 
          "name": [
            "Department of Chemical Engineering, University of Waterloo, Waterloo, Ontario, Canada N2L3G1"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Chen", 
        "givenName": "Zhongwei", 
        "id": "sg:person.01274317233.41", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01274317233.41"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/j.jpowsour.2009.01.007", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000095809"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.3382344", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002352738"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.nantod.2012.08.004", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002365928"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nnano.2014.6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003314836", 
          "https://doi.org/10.1038/nnano.2014.6"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0378-7753(99)00124-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003386938"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adfm.201400161", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004410577"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/451652a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007137639", 
          "https://doi.org/10.1038/451652a"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b919877f", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1008486514"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b919877f", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1008486514"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0009-2614(98)01105-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009613847"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.eurpolymj.2011.10.006", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011222875"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/anie.201201429", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011853071"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.susc.2006.01.041", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012006613"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.susc.2006.08.020", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012539102"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nmat2749", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013832024", 
          "https://doi.org/10.1038/nmat2749"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adfm.201200186", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1015397982"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/nn203393d", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1015920599"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/ncomms2941", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1024403187", 
          "https://doi.org/10.1038/ncomms2941"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/app.40343", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1025123487"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c0gc00384k", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026407167"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1088/0953-8984/3/35/005", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026419786"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1149/1.1388178", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1029100650"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0378-7753(96)02547-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031122833"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0039-6028(02)02208-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031784704"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nnano.2007.411", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032531480", 
          "https://doi.org/10.1038/nnano.2007.411"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c1cc12272j", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033815817"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/aenm.201300882", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034429842"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cs200652y", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034762797"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/ncomms5105", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1037869964", 
          "https://doi.org/10.1038/ncomms5105"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s11661-010-0438-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039545149", 
          "https://doi.org/10.1007/s11661-010-0438-5"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s11661-010-0438-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039545149", 
          "https://doi.org/10.1007/s11661-010-0438-5"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/sia.1283", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040416665"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02861463", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040883689", 
          "https://doi.org/10.1007/bf02861463"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02861463", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040883689", 
          "https://doi.org/10.1007/bf02861463"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/pola.1986.080241134", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040934252"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jpowsour.2010.07.020", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041327000"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/chem.201203242", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042178469"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/app.26862", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043559909"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nnano.2014.92", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044115930", 
          "https://doi.org/10.1038/nnano.2014.92"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c2gc16415a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045897088"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/anie.196510141", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047759121"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c0ee00281j", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1049883984"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nnano.2012.35", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050288514", 
          "https://doi.org/10.1038/nnano.2012.35"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0378-7753(00)00431-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050291316"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nmat2725", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053357993", 
          "https://doi.org/10.1038/nmat2725"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nmat2725", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053357993", 
          "https://doi.org/10.1038/nmat2725"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1073/pnas.1201088109", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053363670"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adma.201404426", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053446679"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/am5032067", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055146007"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cs5003806", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055422705"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/j100626a023", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055674461"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja108085d", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055848577"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja108085d", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055848577"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp004016n", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056044936"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp004016n", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056044936"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jz301821n", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056134830"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/nl401880v", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056220175"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/nl403943g", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056220477"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/nn503294z", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056226196"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.4731342", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1058054020"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.44.7888", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060560048"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.44.7888", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060560048"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1142/s1793292011002536", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1063021038"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2015-12", 
    "datePublishedReg": "2015-12-01", 
    "description": "Silicon has the potential to revolutionize the energy storage capacities of lithium-ion batteries to meet the ever increasing power demands of next generation technologies. To avoid the operational stability problems of silicon-based anodes, we propose synergistic physicochemical alteration of electrode structures during their design. This capitalizes on covalent interaction of Si nanoparticles with sulfur-doped graphene and with cyclized polyacrylonitrile to provide a robust nanoarchitecture. This hierarchical structure stabilized the solid electrolyte interphase leading to superior reversible capacity of over 1,000\u2009mAh\u2009g(-1) for 2,275 cycles at 2\u2009A\u2009g(-1). Furthermore, the nanoarchitectured design lowered the contact of the electrolyte to the electrode leading to not only high coulombic efficiency of 99.9% but also maintaining high stability even with high electrode loading associated with 3.4\u2009mAh\u2009cm(-2). The excellent performance combined with the simplistic, scalable and non-hazardous approach render the process as a very promising candidate for Li-ion battery technology. ", 
    "genre": "research_article", 
    "id": "sg:pub.10.1038/ncomms9597", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": true, 
    "isPartOf": [
      {
        "id": "sg:journal.1043282", 
        "issn": [
          "2041-1723"
        ], 
        "name": "Nature Communications", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "6"
      }
    ], 
    "name": "Evidence of covalent synergy in silicon\u2013sulfur\u2013graphene yielding highly efficient and long-life lithium-ion batteries", 
    "pagination": "8597", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "0c023063c9b011ef6c27896940ab5a39d256efde80edd15e5d00949f5db5e6e0"
        ]
      }, 
      {
        "name": "pubmed_id", 
        "type": "PropertyValue", 
        "value": [
          "26497228"
        ]
      }, 
      {
        "name": "nlm_unique_id", 
        "type": "PropertyValue", 
        "value": [
          "101528555"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1038/ncomms9597"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1002522247"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1038/ncomms9597", 
      "https://app.dimensions.ai/details/publication/pub.1002522247"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T13:00", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8659_00000435.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://www.nature.com/articles/ncomms9597"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1038/ncomms9597'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1038/ncomms9597'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1038/ncomms9597'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1038/ncomms9597'


 

This table displays all metadata directly associated to this object as RDF triples.

291 TRIPLES      21 PREDICATES      85 URIs      21 LITERALS      9 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1038/ncomms9597 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N11f55d07107e4bca8abe001f11936dc0
4 schema:citation sg:pub.10.1007/bf02861463
5 sg:pub.10.1007/s11661-010-0438-5
6 sg:pub.10.1038/451652a
7 sg:pub.10.1038/ncomms2941
8 sg:pub.10.1038/ncomms5105
9 sg:pub.10.1038/nmat2725
10 sg:pub.10.1038/nmat2749
11 sg:pub.10.1038/nnano.2007.411
12 sg:pub.10.1038/nnano.2012.35
13 sg:pub.10.1038/nnano.2014.6
14 sg:pub.10.1038/nnano.2014.92
15 https://doi.org/10.1002/adfm.201200186
16 https://doi.org/10.1002/adfm.201400161
17 https://doi.org/10.1002/adma.201404426
18 https://doi.org/10.1002/aenm.201300882
19 https://doi.org/10.1002/anie.196510141
20 https://doi.org/10.1002/anie.201201429
21 https://doi.org/10.1002/app.26862
22 https://doi.org/10.1002/app.40343
23 https://doi.org/10.1002/chem.201203242
24 https://doi.org/10.1002/pola.1986.080241134
25 https://doi.org/10.1002/sia.1283
26 https://doi.org/10.1016/j.eurpolymj.2011.10.006
27 https://doi.org/10.1016/j.jpowsour.2009.01.007
28 https://doi.org/10.1016/j.jpowsour.2010.07.020
29 https://doi.org/10.1016/j.nantod.2012.08.004
30 https://doi.org/10.1016/j.susc.2006.01.041
31 https://doi.org/10.1016/j.susc.2006.08.020
32 https://doi.org/10.1016/s0009-2614(98)01105-1
33 https://doi.org/10.1016/s0039-6028(02)02208-2
34 https://doi.org/10.1016/s0378-7753(00)00431-6
35 https://doi.org/10.1016/s0378-7753(96)02547-5
36 https://doi.org/10.1016/s0378-7753(99)00124-x
37 https://doi.org/10.1021/am5032067
38 https://doi.org/10.1021/cs200652y
39 https://doi.org/10.1021/cs5003806
40 https://doi.org/10.1021/j100626a023
41 https://doi.org/10.1021/ja108085d
42 https://doi.org/10.1021/jp004016n
43 https://doi.org/10.1021/jz301821n
44 https://doi.org/10.1021/nl401880v
45 https://doi.org/10.1021/nl403943g
46 https://doi.org/10.1021/nn203393d
47 https://doi.org/10.1021/nn503294z
48 https://doi.org/10.1039/b919877f
49 https://doi.org/10.1039/c0ee00281j
50 https://doi.org/10.1039/c0gc00384k
51 https://doi.org/10.1039/c1cc12272j
52 https://doi.org/10.1039/c2gc16415a
53 https://doi.org/10.1063/1.3382344
54 https://doi.org/10.1063/1.4731342
55 https://doi.org/10.1073/pnas.1201088109
56 https://doi.org/10.1088/0953-8984/3/35/005
57 https://doi.org/10.1103/physrevb.44.7888
58 https://doi.org/10.1142/s1793292011002536
59 https://doi.org/10.1149/1.1388178
60 schema:datePublished 2015-12
61 schema:datePublishedReg 2015-12-01
62 schema:description Silicon has the potential to revolutionize the energy storage capacities of lithium-ion batteries to meet the ever increasing power demands of next generation technologies. To avoid the operational stability problems of silicon-based anodes, we propose synergistic physicochemical alteration of electrode structures during their design. This capitalizes on covalent interaction of Si nanoparticles with sulfur-doped graphene and with cyclized polyacrylonitrile to provide a robust nanoarchitecture. This hierarchical structure stabilized the solid electrolyte interphase leading to superior reversible capacity of over 1,000 mAh g(-1) for 2,275 cycles at 2 A g(-1). Furthermore, the nanoarchitectured design lowered the contact of the electrolyte to the electrode leading to not only high coulombic efficiency of 99.9% but also maintaining high stability even with high electrode loading associated with 3.4 mAh cm(-2). The excellent performance combined with the simplistic, scalable and non-hazardous approach render the process as a very promising candidate for Li-ion battery technology.
63 schema:genre research_article
64 schema:inLanguage en
65 schema:isAccessibleForFree true
66 schema:isPartOf N400101c28a5b4d268b2dc0ade13eac59
67 Ne9123d9b479d491a9391bf02c3b90a23
68 sg:journal.1043282
69 schema:name Evidence of covalent synergy in silicon–sulfur–graphene yielding highly efficient and long-life lithium-ion batteries
70 schema:pagination 8597
71 schema:productId N49d876b0467b4d6e8960ae569dd1c788
72 N56948640f3c34fd78e7f9277ac9564f1
73 N6f2f4816e36441e4a3dc8ab7f37b0fc0
74 N82c40780bd884c95996dda320ac59b08
75 N99be835d1c2c4fa88f11245759ffeca3
76 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002522247
77 https://doi.org/10.1038/ncomms9597
78 schema:sdDatePublished 2019-04-10T13:00
79 schema:sdLicense https://scigraph.springernature.com/explorer/license/
80 schema:sdPublisher N57b026e81cd148cba40ee68a9ecd94fd
81 schema:url https://www.nature.com/articles/ncomms9597
82 sgo:license sg:explorer/license/
83 sgo:sdDataset articles
84 rdf:type schema:ScholarlyArticle
85 N11f55d07107e4bca8abe001f11936dc0 rdf:first sg:person.0776643741.90
86 rdf:rest N79ae82cf5d6f43109d17395a094ccf12
87 N35044699a29c4370896a5e4f7a0f01f2 rdf:first sg:person.01372502401.05
88 rdf:rest Nafbcc89507e04eec961489db164eb0ae
89 N400101c28a5b4d268b2dc0ade13eac59 schema:volumeNumber 6
90 rdf:type schema:PublicationVolume
91 N49d876b0467b4d6e8960ae569dd1c788 schema:name doi
92 schema:value 10.1038/ncomms9597
93 rdf:type schema:PropertyValue
94 N56948640f3c34fd78e7f9277ac9564f1 schema:name dimensions_id
95 schema:value pub.1002522247
96 rdf:type schema:PropertyValue
97 N57b026e81cd148cba40ee68a9ecd94fd schema:name Springer Nature - SN SciGraph project
98 rdf:type schema:Organization
99 N5b0a13e6e7684a2ea86a1e992f86c383 rdf:first sg:person.01137424352.94
100 rdf:rest Ncf267e3bc8a24ff0a2cc948ad6b398db
101 N6f2f4816e36441e4a3dc8ab7f37b0fc0 schema:name pubmed_id
102 schema:value 26497228
103 rdf:type schema:PropertyValue
104 N79ae82cf5d6f43109d17395a094ccf12 rdf:first sg:person.013500625471.38
105 rdf:rest Ne3a655161b80482293c3bfd4828aa0a7
106 N82c40780bd884c95996dda320ac59b08 schema:name readcube_id
107 schema:value 0c023063c9b011ef6c27896940ab5a39d256efde80edd15e5d00949f5db5e6e0
108 rdf:type schema:PropertyValue
109 N99be835d1c2c4fa88f11245759ffeca3 schema:name nlm_unique_id
110 schema:value 101528555
111 rdf:type schema:PropertyValue
112 Nafbcc89507e04eec961489db164eb0ae rdf:first sg:person.01236465500.13
113 rdf:rest N5b0a13e6e7684a2ea86a1e992f86c383
114 Ncf267e3bc8a24ff0a2cc948ad6b398db rdf:first sg:person.01274317233.41
115 rdf:rest rdf:nil
116 Nd611fdde74ec4bffb490d4f2baefc813 schema:name Chemical and Materials Systems, General Motors Global Research and Development Center, Warren, Michigan 48090, USA
117 rdf:type schema:Organization
118 Ne3a655161b80482293c3bfd4828aa0a7 rdf:first sg:person.016465447565.85
119 rdf:rest N35044699a29c4370896a5e4f7a0f01f2
120 Ne9123d9b479d491a9391bf02c3b90a23 schema:issueNumber 1
121 rdf:type schema:PublicationIssue
122 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
123 schema:name Chemical Sciences
124 rdf:type schema:DefinedTerm
125 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
126 schema:name Physical Chemistry (incl. Structural)
127 rdf:type schema:DefinedTerm
128 sg:journal.1043282 schema:issn 2041-1723
129 schema:name Nature Communications
130 rdf:type schema:Periodical
131 sg:person.01137424352.94 schema:affiliation https://www.grid.ac/institutes/grid.46078.3d
132 schema:familyName Yu
133 schema:givenName Aiping
134 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01137424352.94
135 rdf:type schema:Person
136 sg:person.01236465500.13 schema:affiliation Nd611fdde74ec4bffb490d4f2baefc813
137 schema:familyName Xiao
138 schema:givenName Xingcheng
139 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01236465500.13
140 rdf:type schema:Person
141 sg:person.01274317233.41 schema:affiliation https://www.grid.ac/institutes/grid.46078.3d
142 schema:familyName Chen
143 schema:givenName Zhongwei
144 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01274317233.41
145 rdf:type schema:Person
146 sg:person.013500625471.38 schema:affiliation https://www.grid.ac/institutes/grid.46078.3d
147 schema:familyName Batmaz
148 schema:givenName Rasim
149 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013500625471.38
150 rdf:type schema:Person
151 sg:person.01372502401.05 schema:affiliation https://www.grid.ac/institutes/grid.46078.3d
152 schema:familyName Wang
153 schema:givenName Xiaolei
154 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01372502401.05
155 rdf:type schema:Person
156 sg:person.016465447565.85 schema:affiliation https://www.grid.ac/institutes/grid.46078.3d
157 schema:familyName Li
158 schema:givenName Jingde
159 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016465447565.85
160 rdf:type schema:Person
161 sg:person.0776643741.90 schema:affiliation https://www.grid.ac/institutes/grid.46078.3d
162 schema:familyName Hassan
163 schema:givenName Fathy M.
164 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0776643741.90
165 rdf:type schema:Person
166 sg:pub.10.1007/bf02861463 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040883689
167 https://doi.org/10.1007/bf02861463
168 rdf:type schema:CreativeWork
169 sg:pub.10.1007/s11661-010-0438-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039545149
170 https://doi.org/10.1007/s11661-010-0438-5
171 rdf:type schema:CreativeWork
172 sg:pub.10.1038/451652a schema:sameAs https://app.dimensions.ai/details/publication/pub.1007137639
173 https://doi.org/10.1038/451652a
174 rdf:type schema:CreativeWork
175 sg:pub.10.1038/ncomms2941 schema:sameAs https://app.dimensions.ai/details/publication/pub.1024403187
176 https://doi.org/10.1038/ncomms2941
177 rdf:type schema:CreativeWork
178 sg:pub.10.1038/ncomms5105 schema:sameAs https://app.dimensions.ai/details/publication/pub.1037869964
179 https://doi.org/10.1038/ncomms5105
180 rdf:type schema:CreativeWork
181 sg:pub.10.1038/nmat2725 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053357993
182 https://doi.org/10.1038/nmat2725
183 rdf:type schema:CreativeWork
184 sg:pub.10.1038/nmat2749 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013832024
185 https://doi.org/10.1038/nmat2749
186 rdf:type schema:CreativeWork
187 sg:pub.10.1038/nnano.2007.411 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032531480
188 https://doi.org/10.1038/nnano.2007.411
189 rdf:type schema:CreativeWork
190 sg:pub.10.1038/nnano.2012.35 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050288514
191 https://doi.org/10.1038/nnano.2012.35
192 rdf:type schema:CreativeWork
193 sg:pub.10.1038/nnano.2014.6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003314836
194 https://doi.org/10.1038/nnano.2014.6
195 rdf:type schema:CreativeWork
196 sg:pub.10.1038/nnano.2014.92 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044115930
197 https://doi.org/10.1038/nnano.2014.92
198 rdf:type schema:CreativeWork
199 https://doi.org/10.1002/adfm.201200186 schema:sameAs https://app.dimensions.ai/details/publication/pub.1015397982
200 rdf:type schema:CreativeWork
201 https://doi.org/10.1002/adfm.201400161 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004410577
202 rdf:type schema:CreativeWork
203 https://doi.org/10.1002/adma.201404426 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053446679
204 rdf:type schema:CreativeWork
205 https://doi.org/10.1002/aenm.201300882 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034429842
206 rdf:type schema:CreativeWork
207 https://doi.org/10.1002/anie.196510141 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047759121
208 rdf:type schema:CreativeWork
209 https://doi.org/10.1002/anie.201201429 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011853071
210 rdf:type schema:CreativeWork
211 https://doi.org/10.1002/app.26862 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043559909
212 rdf:type schema:CreativeWork
213 https://doi.org/10.1002/app.40343 schema:sameAs https://app.dimensions.ai/details/publication/pub.1025123487
214 rdf:type schema:CreativeWork
215 https://doi.org/10.1002/chem.201203242 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042178469
216 rdf:type schema:CreativeWork
217 https://doi.org/10.1002/pola.1986.080241134 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040934252
218 rdf:type schema:CreativeWork
219 https://doi.org/10.1002/sia.1283 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040416665
220 rdf:type schema:CreativeWork
221 https://doi.org/10.1016/j.eurpolymj.2011.10.006 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011222875
222 rdf:type schema:CreativeWork
223 https://doi.org/10.1016/j.jpowsour.2009.01.007 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000095809
224 rdf:type schema:CreativeWork
225 https://doi.org/10.1016/j.jpowsour.2010.07.020 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041327000
226 rdf:type schema:CreativeWork
227 https://doi.org/10.1016/j.nantod.2012.08.004 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002365928
228 rdf:type schema:CreativeWork
229 https://doi.org/10.1016/j.susc.2006.01.041 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012006613
230 rdf:type schema:CreativeWork
231 https://doi.org/10.1016/j.susc.2006.08.020 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012539102
232 rdf:type schema:CreativeWork
233 https://doi.org/10.1016/s0009-2614(98)01105-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1009613847
234 rdf:type schema:CreativeWork
235 https://doi.org/10.1016/s0039-6028(02)02208-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031784704
236 rdf:type schema:CreativeWork
237 https://doi.org/10.1016/s0378-7753(00)00431-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050291316
238 rdf:type schema:CreativeWork
239 https://doi.org/10.1016/s0378-7753(96)02547-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031122833
240 rdf:type schema:CreativeWork
241 https://doi.org/10.1016/s0378-7753(99)00124-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1003386938
242 rdf:type schema:CreativeWork
243 https://doi.org/10.1021/am5032067 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055146007
244 rdf:type schema:CreativeWork
245 https://doi.org/10.1021/cs200652y schema:sameAs https://app.dimensions.ai/details/publication/pub.1034762797
246 rdf:type schema:CreativeWork
247 https://doi.org/10.1021/cs5003806 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055422705
248 rdf:type schema:CreativeWork
249 https://doi.org/10.1021/j100626a023 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055674461
250 rdf:type schema:CreativeWork
251 https://doi.org/10.1021/ja108085d schema:sameAs https://app.dimensions.ai/details/publication/pub.1055848577
252 rdf:type schema:CreativeWork
253 https://doi.org/10.1021/jp004016n schema:sameAs https://app.dimensions.ai/details/publication/pub.1056044936
254 rdf:type schema:CreativeWork
255 https://doi.org/10.1021/jz301821n schema:sameAs https://app.dimensions.ai/details/publication/pub.1056134830
256 rdf:type schema:CreativeWork
257 https://doi.org/10.1021/nl401880v schema:sameAs https://app.dimensions.ai/details/publication/pub.1056220175
258 rdf:type schema:CreativeWork
259 https://doi.org/10.1021/nl403943g schema:sameAs https://app.dimensions.ai/details/publication/pub.1056220477
260 rdf:type schema:CreativeWork
261 https://doi.org/10.1021/nn203393d schema:sameAs https://app.dimensions.ai/details/publication/pub.1015920599
262 rdf:type schema:CreativeWork
263 https://doi.org/10.1021/nn503294z schema:sameAs https://app.dimensions.ai/details/publication/pub.1056226196
264 rdf:type schema:CreativeWork
265 https://doi.org/10.1039/b919877f schema:sameAs https://app.dimensions.ai/details/publication/pub.1008486514
266 rdf:type schema:CreativeWork
267 https://doi.org/10.1039/c0ee00281j schema:sameAs https://app.dimensions.ai/details/publication/pub.1049883984
268 rdf:type schema:CreativeWork
269 https://doi.org/10.1039/c0gc00384k schema:sameAs https://app.dimensions.ai/details/publication/pub.1026407167
270 rdf:type schema:CreativeWork
271 https://doi.org/10.1039/c1cc12272j schema:sameAs https://app.dimensions.ai/details/publication/pub.1033815817
272 rdf:type schema:CreativeWork
273 https://doi.org/10.1039/c2gc16415a schema:sameAs https://app.dimensions.ai/details/publication/pub.1045897088
274 rdf:type schema:CreativeWork
275 https://doi.org/10.1063/1.3382344 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002352738
276 rdf:type schema:CreativeWork
277 https://doi.org/10.1063/1.4731342 schema:sameAs https://app.dimensions.ai/details/publication/pub.1058054020
278 rdf:type schema:CreativeWork
279 https://doi.org/10.1073/pnas.1201088109 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053363670
280 rdf:type schema:CreativeWork
281 https://doi.org/10.1088/0953-8984/3/35/005 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026419786
282 rdf:type schema:CreativeWork
283 https://doi.org/10.1103/physrevb.44.7888 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060560048
284 rdf:type schema:CreativeWork
285 https://doi.org/10.1142/s1793292011002536 schema:sameAs https://app.dimensions.ai/details/publication/pub.1063021038
286 rdf:type schema:CreativeWork
287 https://doi.org/10.1149/1.1388178 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029100650
288 rdf:type schema:CreativeWork
289 https://www.grid.ac/institutes/grid.46078.3d schema:alternateName University of Waterloo
290 schema:name Department of Chemical Engineering, University of Waterloo, Waterloo, Ontario, Canada N2L3G1
291 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...