Site-selective hexa-hetero-functionalization of α-cyclodextrin an archetypical C6-symmetric concave cycle View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2014-12

AUTHORS

Bo Wang, Elena Zaborova, Samuel Guieu, Marta Petrillo, Maxime Guitet, Yves Blériot, Mickaël Ménand, Yongmin Zhang, Matthieu Sollogoub

ABSTRACT

Access to Cn (n>4) symmetric cyclic concave molecules with a different function on each of their n subunits is an unmet challenge. The reason lies in the lack of a post-functionalization method whose site selectivity is sufficiently understood, predictable and modulable to access most functionalization patterns. Here we disclose a new site-directing rule for a debenzylation reaction on cyclodextrins that solves this problem and allows the unprecedented access to penta- and ultimately hexa-differentiations of such C6 concave cycles. This achievement opens the access to objects with very high-density information. More... »

PAGES

5354

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/ncomms6354

DOI

http://dx.doi.org/10.1038/ncomms6354

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1035272250

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/25382259


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