Tuning the magneto-structural properties of non-porous coordination polymers by HCl chemisorption View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2012-01

AUTHORS

Eugenio Coronado, Mónica Giménez-Marqués, Guillermo Mínguez Espallargas, Lee Brammer

ABSTRACT

Responsive materials for which physical or chemical properties can be tuned by applying an external stimulus are attracting considerable interest in view of their potential applications as chemical switches or molecular sensors. A potential source of such materials is metal-organic frameworks. These porous coordination polymers permit the physisorption of guest molecules that can provoke subtle changes in their porous structure, thus affecting their physical properties. Here we show that the chemisorption of gaseous HCl molecules by a non-porous one-dimensional coordination polymer instigates drastic modifications in the magnetic properties of the material. These changes result from profound structural changes, involving cleavage and formation of covalent bonds, but with no disruption of crystallinity. More... »

PAGES

828

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/ncomms1827

DOI

http://dx.doi.org/10.1038/ncomms1827

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1026809251

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/22569372


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0303", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Macromolecular and Materials Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "University of Valencia", 
          "id": "https://www.grid.ac/institutes/grid.5338.d", 
          "name": [
            "Instituto de Ciencia Molecular (ICMol), Universidad de Valencia, c/ Catedr\u00e1tico Jos\u00e9 Beltr\u00e1n, 2, 46980 Paterna, Spain."
          ], 
          "type": "Organization"
        }, 
        "familyName": "Coronado", 
        "givenName": "Eugenio", 
        "id": "sg:person.01245166576.37", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01245166576.37"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Valencia", 
          "id": "https://www.grid.ac/institutes/grid.5338.d", 
          "name": [
            "Instituto de Ciencia Molecular (ICMol), Universidad de Valencia, c/ Catedr\u00e1tico Jos\u00e9 Beltr\u00e1n, 2, 46980 Paterna, Spain."
          ], 
          "type": "Organization"
        }, 
        "familyName": "Gim\u00e9nez-Marqu\u00e9s", 
        "givenName": "M\u00f3nica", 
        "id": "sg:person.0677563015.17", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0677563015.17"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Valencia", 
          "id": "https://www.grid.ac/institutes/grid.5338.d", 
          "name": [
            "Instituto de Ciencia Molecular (ICMol), Universidad de Valencia, c/ Catedr\u00e1tico Jos\u00e9 Beltr\u00e1n, 2, 46980 Paterna, Spain."
          ], 
          "type": "Organization"
        }, 
        "familyName": "Espallargas", 
        "givenName": "Guillermo M\u00ednguez", 
        "id": "sg:person.015664777525.52", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015664777525.52"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Sheffield", 
          "id": "https://www.grid.ac/institutes/grid.11835.3e", 
          "name": [
            "Department of Chemistry, University of Sheffield, Sheffield S3 7HF, UK."
          ], 
          "type": "Organization"
        }, 
        "familyName": "Brammer", 
        "givenName": "Lee", 
        "id": "sg:person.0613575461.14", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0613575461.14"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1039/c0cs00167h", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001327983"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/35023107", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001978706", 
          "https://doi.org/10.1038/35023107"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/35023107", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001978706", 
          "https://doi.org/10.1038/35023107"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c1cs15042a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003706424"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c1cs15046d", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003753594"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0021889891006441", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004857738"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b618320b", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011478070"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/anie.200904379", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011695644"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0021889806042117", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013367423"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nature06900", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013448970", 
          "https://doi.org/10.1038/nature06900"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/anie.201007872", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018678977"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.poly.2005.03.033", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019151562"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/a800855h", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020263512"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.65.144412", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020301594"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.65.144412", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020301594"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1073/pnas.0602439103", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022558871"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/anie.201003265", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023682759"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/anie.201003265", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023682759"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0909049511013641", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026391140"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0108767307043930", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027786902"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/anie.200300610", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027885687"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0021889869006558", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030634393"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nmat834", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032167638", 
          "https://doi.org/10.1038/nmat834"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nmat834", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032167638", 
          "https://doi.org/10.1038/nmat834"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nchem.585", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032220247", 
          "https://doi.org/10.1038/nchem.585"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nchem.585", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032220247", 
          "https://doi.org/10.1038/nchem.585"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b804680h", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033375973"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b804680h", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033375973"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/anie.200603593", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035552617"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nmat1260", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1037054661", 
          "https://doi.org/10.1038/nmat1260"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.1067208", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039206546"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/anie.199420241", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039451421"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nchem.444", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040589250", 
          "https://doi.org/10.1038/nchem.444"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nchem.444", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040589250", 
          "https://doi.org/10.1038/nchem.444"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0021889881009618", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043517724"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c0sc00127a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1046405328"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c0sc00127a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1046405328"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/anie.200806039", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047347108"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/anie.200806039", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047347108"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/j19680000061", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047769901"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1246/bcsj.46.3438", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048023825"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b501491c", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1051401979"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b500614g", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1051767590"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cg015522k", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055392552"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cg015522k", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055392552"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic00175a001", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055545949"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic50011a023", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055567139"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic50136a057", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055574613"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja043166z", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055835832"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja043166z", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055835832"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja061514m", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055841895"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja061514m", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055841895"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja0625733", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055842207"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja0625733", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055842207"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja075265t", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055845789"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja075265t", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055845789"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja102412g", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055847259"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja102412g", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055847259"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja111674c", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055849305"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja111674c", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055849305"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.3167217", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057917117"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.24.5349", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060529734"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevb.24.5349", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060529734"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.1075948", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1062446917"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.272.5262.704", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1062552908"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2012-01", 
    "datePublishedReg": "2012-01-01", 
    "description": "Responsive materials for which physical or chemical properties can be tuned by applying an external stimulus are attracting considerable interest in view of their potential applications as chemical switches or molecular sensors. A potential source of such materials is metal-organic frameworks. These porous coordination polymers permit the physisorption of guest molecules that can provoke subtle changes in their porous structure, thus affecting their physical properties. Here we show that the chemisorption of gaseous HCl molecules by a non-porous one-dimensional coordination polymer instigates drastic modifications in the magnetic properties of the material. These changes result from profound structural changes, involving cleavage and formation of covalent bonds, but with no disruption of crystallinity.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1038/ncomms1827", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": true, 
    "isFundedItemOf": [
      {
        "id": "sg:grant.3790229", 
        "type": "MonetaryGrant"
      }, 
      {
        "id": "sg:grant.3786115", 
        "type": "MonetaryGrant"
      }, 
      {
        "id": "sg:grant.3778646", 
        "type": "MonetaryGrant"
      }
    ], 
    "isPartOf": [
      {
        "id": "sg:journal.1043282", 
        "issn": [
          "2041-1723"
        ], 
        "name": "Nature Communications", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "3"
      }
    ], 
    "name": "Tuning the magneto-structural properties of non-porous coordination polymers by HCl chemisorption", 
    "pagination": "828", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "7fb6ee7ab9225290cbd31809a81f0b1f985f3f9a151c0ab0612fdf3948efe579"
        ]
      }, 
      {
        "name": "pubmed_id", 
        "type": "PropertyValue", 
        "value": [
          "22569372"
        ]
      }, 
      {
        "name": "nlm_unique_id", 
        "type": "PropertyValue", 
        "value": [
          "101528555"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1038/ncomms1827"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1026809251"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1038/ncomms1827", 
      "https://app.dimensions.ai/details/publication/pub.1026809251"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T00:56", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8697_00000435.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://www.nature.com/articles/ncomms1827"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1038/ncomms1827'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1038/ncomms1827'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1038/ncomms1827'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1038/ncomms1827'


 

This table displays all metadata directly associated to this object as RDF triples.

248 TRIPLES      21 PREDICATES      77 URIs      21 LITERALS      9 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1038/ncomms1827 schema:about anzsrc-for:03
2 anzsrc-for:0303
3 schema:author Ndcec0824e6794f81ad17ef81bbcd55e8
4 schema:citation sg:pub.10.1038/35023107
5 sg:pub.10.1038/nature06900
6 sg:pub.10.1038/nchem.444
7 sg:pub.10.1038/nchem.585
8 sg:pub.10.1038/nmat1260
9 sg:pub.10.1038/nmat834
10 https://doi.org/10.1002/anie.199420241
11 https://doi.org/10.1002/anie.200300610
12 https://doi.org/10.1002/anie.200603593
13 https://doi.org/10.1002/anie.200806039
14 https://doi.org/10.1002/anie.200904379
15 https://doi.org/10.1002/anie.201003265
16 https://doi.org/10.1002/anie.201007872
17 https://doi.org/10.1016/j.poly.2005.03.033
18 https://doi.org/10.1021/cg015522k
19 https://doi.org/10.1021/ic00175a001
20 https://doi.org/10.1021/ic50011a023
21 https://doi.org/10.1021/ic50136a057
22 https://doi.org/10.1021/ja043166z
23 https://doi.org/10.1021/ja061514m
24 https://doi.org/10.1021/ja0625733
25 https://doi.org/10.1021/ja075265t
26 https://doi.org/10.1021/ja102412g
27 https://doi.org/10.1021/ja111674c
28 https://doi.org/10.1039/a800855h
29 https://doi.org/10.1039/b500614g
30 https://doi.org/10.1039/b501491c
31 https://doi.org/10.1039/b618320b
32 https://doi.org/10.1039/b804680h
33 https://doi.org/10.1039/c0cs00167h
34 https://doi.org/10.1039/c0sc00127a
35 https://doi.org/10.1039/c1cs15042a
36 https://doi.org/10.1039/c1cs15046d
37 https://doi.org/10.1039/j19680000061
38 https://doi.org/10.1063/1.3167217
39 https://doi.org/10.1073/pnas.0602439103
40 https://doi.org/10.1103/physrevb.24.5349
41 https://doi.org/10.1103/physrevb.65.144412
42 https://doi.org/10.1107/s0021889806042117
43 https://doi.org/10.1107/s0021889869006558
44 https://doi.org/10.1107/s0021889881009618
45 https://doi.org/10.1107/s0021889891006441
46 https://doi.org/10.1107/s0108767307043930
47 https://doi.org/10.1107/s0909049511013641
48 https://doi.org/10.1126/science.1067208
49 https://doi.org/10.1126/science.1075948
50 https://doi.org/10.1126/science.272.5262.704
51 https://doi.org/10.1246/bcsj.46.3438
52 schema:datePublished 2012-01
53 schema:datePublishedReg 2012-01-01
54 schema:description Responsive materials for which physical or chemical properties can be tuned by applying an external stimulus are attracting considerable interest in view of their potential applications as chemical switches or molecular sensors. A potential source of such materials is metal-organic frameworks. These porous coordination polymers permit the physisorption of guest molecules that can provoke subtle changes in their porous structure, thus affecting their physical properties. Here we show that the chemisorption of gaseous HCl molecules by a non-porous one-dimensional coordination polymer instigates drastic modifications in the magnetic properties of the material. These changes result from profound structural changes, involving cleavage and formation of covalent bonds, but with no disruption of crystallinity.
55 schema:genre research_article
56 schema:inLanguage en
57 schema:isAccessibleForFree true
58 schema:isPartOf N02e52a167ec3428183608107c90fb8c6
59 Na8d98fdccf4946a7bb2a02a7ed9f270f
60 sg:journal.1043282
61 schema:name Tuning the magneto-structural properties of non-porous coordination polymers by HCl chemisorption
62 schema:pagination 828
63 schema:productId N0de8600b1c6d4dac8cab58035d16655e
64 N21bb6a9f6b2e48ba9b742dd333ec4d12
65 N5d3a65b2aed1432d965609fe47712679
66 N71bfb180c2fd470ebfb01f140a7c48fb
67 Nca19a4480efc459d9dab7ac17c5d35ee
68 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026809251
69 https://doi.org/10.1038/ncomms1827
70 schema:sdDatePublished 2019-04-11T00:56
71 schema:sdLicense https://scigraph.springernature.com/explorer/license/
72 schema:sdPublisher N4fc8ba25088e46d0a91415aba04db8f0
73 schema:url https://www.nature.com/articles/ncomms1827
74 sgo:license sg:explorer/license/
75 sgo:sdDataset articles
76 rdf:type schema:ScholarlyArticle
77 N02e52a167ec3428183608107c90fb8c6 schema:volumeNumber 3
78 rdf:type schema:PublicationVolume
79 N03c78b09cee946c782fdf83997a0c003 rdf:first sg:person.015664777525.52
80 rdf:rest Nbc94af92d317432eb0aeb18bd8238186
81 N0de8600b1c6d4dac8cab58035d16655e schema:name dimensions_id
82 schema:value pub.1026809251
83 rdf:type schema:PropertyValue
84 N21bb6a9f6b2e48ba9b742dd333ec4d12 schema:name nlm_unique_id
85 schema:value 101528555
86 rdf:type schema:PropertyValue
87 N4fc8ba25088e46d0a91415aba04db8f0 schema:name Springer Nature - SN SciGraph project
88 rdf:type schema:Organization
89 N5d3a65b2aed1432d965609fe47712679 schema:name pubmed_id
90 schema:value 22569372
91 rdf:type schema:PropertyValue
92 N71bfb180c2fd470ebfb01f140a7c48fb schema:name doi
93 schema:value 10.1038/ncomms1827
94 rdf:type schema:PropertyValue
95 Na8d98fdccf4946a7bb2a02a7ed9f270f schema:issueNumber 1
96 rdf:type schema:PublicationIssue
97 Nbc94af92d317432eb0aeb18bd8238186 rdf:first sg:person.0613575461.14
98 rdf:rest rdf:nil
99 Nbeabe02c162e4cc3a08cbc7d8c751374 rdf:first sg:person.0677563015.17
100 rdf:rest N03c78b09cee946c782fdf83997a0c003
101 Nca19a4480efc459d9dab7ac17c5d35ee schema:name readcube_id
102 schema:value 7fb6ee7ab9225290cbd31809a81f0b1f985f3f9a151c0ab0612fdf3948efe579
103 rdf:type schema:PropertyValue
104 Ndcec0824e6794f81ad17ef81bbcd55e8 rdf:first sg:person.01245166576.37
105 rdf:rest Nbeabe02c162e4cc3a08cbc7d8c751374
106 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
107 schema:name Chemical Sciences
108 rdf:type schema:DefinedTerm
109 anzsrc-for:0303 schema:inDefinedTermSet anzsrc-for:
110 schema:name Macromolecular and Materials Chemistry
111 rdf:type schema:DefinedTerm
112 sg:grant.3778646 http://pending.schema.org/fundedItem sg:pub.10.1038/ncomms1827
113 rdf:type schema:MonetaryGrant
114 sg:grant.3786115 http://pending.schema.org/fundedItem sg:pub.10.1038/ncomms1827
115 rdf:type schema:MonetaryGrant
116 sg:grant.3790229 http://pending.schema.org/fundedItem sg:pub.10.1038/ncomms1827
117 rdf:type schema:MonetaryGrant
118 sg:journal.1043282 schema:issn 2041-1723
119 schema:name Nature Communications
120 rdf:type schema:Periodical
121 sg:person.01245166576.37 schema:affiliation https://www.grid.ac/institutes/grid.5338.d
122 schema:familyName Coronado
123 schema:givenName Eugenio
124 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01245166576.37
125 rdf:type schema:Person
126 sg:person.015664777525.52 schema:affiliation https://www.grid.ac/institutes/grid.5338.d
127 schema:familyName Espallargas
128 schema:givenName Guillermo Mínguez
129 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015664777525.52
130 rdf:type schema:Person
131 sg:person.0613575461.14 schema:affiliation https://www.grid.ac/institutes/grid.11835.3e
132 schema:familyName Brammer
133 schema:givenName Lee
134 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0613575461.14
135 rdf:type schema:Person
136 sg:person.0677563015.17 schema:affiliation https://www.grid.ac/institutes/grid.5338.d
137 schema:familyName Giménez-Marqués
138 schema:givenName Mónica
139 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0677563015.17
140 rdf:type schema:Person
141 sg:pub.10.1038/35023107 schema:sameAs https://app.dimensions.ai/details/publication/pub.1001978706
142 https://doi.org/10.1038/35023107
143 rdf:type schema:CreativeWork
144 sg:pub.10.1038/nature06900 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013448970
145 https://doi.org/10.1038/nature06900
146 rdf:type schema:CreativeWork
147 sg:pub.10.1038/nchem.444 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040589250
148 https://doi.org/10.1038/nchem.444
149 rdf:type schema:CreativeWork
150 sg:pub.10.1038/nchem.585 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032220247
151 https://doi.org/10.1038/nchem.585
152 rdf:type schema:CreativeWork
153 sg:pub.10.1038/nmat1260 schema:sameAs https://app.dimensions.ai/details/publication/pub.1037054661
154 https://doi.org/10.1038/nmat1260
155 rdf:type schema:CreativeWork
156 sg:pub.10.1038/nmat834 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032167638
157 https://doi.org/10.1038/nmat834
158 rdf:type schema:CreativeWork
159 https://doi.org/10.1002/anie.199420241 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039451421
160 rdf:type schema:CreativeWork
161 https://doi.org/10.1002/anie.200300610 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027885687
162 rdf:type schema:CreativeWork
163 https://doi.org/10.1002/anie.200603593 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035552617
164 rdf:type schema:CreativeWork
165 https://doi.org/10.1002/anie.200806039 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047347108
166 rdf:type schema:CreativeWork
167 https://doi.org/10.1002/anie.200904379 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011695644
168 rdf:type schema:CreativeWork
169 https://doi.org/10.1002/anie.201003265 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023682759
170 rdf:type schema:CreativeWork
171 https://doi.org/10.1002/anie.201007872 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018678977
172 rdf:type schema:CreativeWork
173 https://doi.org/10.1016/j.poly.2005.03.033 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019151562
174 rdf:type schema:CreativeWork
175 https://doi.org/10.1021/cg015522k schema:sameAs https://app.dimensions.ai/details/publication/pub.1055392552
176 rdf:type schema:CreativeWork
177 https://doi.org/10.1021/ic00175a001 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055545949
178 rdf:type schema:CreativeWork
179 https://doi.org/10.1021/ic50011a023 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055567139
180 rdf:type schema:CreativeWork
181 https://doi.org/10.1021/ic50136a057 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055574613
182 rdf:type schema:CreativeWork
183 https://doi.org/10.1021/ja043166z schema:sameAs https://app.dimensions.ai/details/publication/pub.1055835832
184 rdf:type schema:CreativeWork
185 https://doi.org/10.1021/ja061514m schema:sameAs https://app.dimensions.ai/details/publication/pub.1055841895
186 rdf:type schema:CreativeWork
187 https://doi.org/10.1021/ja0625733 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055842207
188 rdf:type schema:CreativeWork
189 https://doi.org/10.1021/ja075265t schema:sameAs https://app.dimensions.ai/details/publication/pub.1055845789
190 rdf:type schema:CreativeWork
191 https://doi.org/10.1021/ja102412g schema:sameAs https://app.dimensions.ai/details/publication/pub.1055847259
192 rdf:type schema:CreativeWork
193 https://doi.org/10.1021/ja111674c schema:sameAs https://app.dimensions.ai/details/publication/pub.1055849305
194 rdf:type schema:CreativeWork
195 https://doi.org/10.1039/a800855h schema:sameAs https://app.dimensions.ai/details/publication/pub.1020263512
196 rdf:type schema:CreativeWork
197 https://doi.org/10.1039/b500614g schema:sameAs https://app.dimensions.ai/details/publication/pub.1051767590
198 rdf:type schema:CreativeWork
199 https://doi.org/10.1039/b501491c schema:sameAs https://app.dimensions.ai/details/publication/pub.1051401979
200 rdf:type schema:CreativeWork
201 https://doi.org/10.1039/b618320b schema:sameAs https://app.dimensions.ai/details/publication/pub.1011478070
202 rdf:type schema:CreativeWork
203 https://doi.org/10.1039/b804680h schema:sameAs https://app.dimensions.ai/details/publication/pub.1033375973
204 rdf:type schema:CreativeWork
205 https://doi.org/10.1039/c0cs00167h schema:sameAs https://app.dimensions.ai/details/publication/pub.1001327983
206 rdf:type schema:CreativeWork
207 https://doi.org/10.1039/c0sc00127a schema:sameAs https://app.dimensions.ai/details/publication/pub.1046405328
208 rdf:type schema:CreativeWork
209 https://doi.org/10.1039/c1cs15042a schema:sameAs https://app.dimensions.ai/details/publication/pub.1003706424
210 rdf:type schema:CreativeWork
211 https://doi.org/10.1039/c1cs15046d schema:sameAs https://app.dimensions.ai/details/publication/pub.1003753594
212 rdf:type schema:CreativeWork
213 https://doi.org/10.1039/j19680000061 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047769901
214 rdf:type schema:CreativeWork
215 https://doi.org/10.1063/1.3167217 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057917117
216 rdf:type schema:CreativeWork
217 https://doi.org/10.1073/pnas.0602439103 schema:sameAs https://app.dimensions.ai/details/publication/pub.1022558871
218 rdf:type schema:CreativeWork
219 https://doi.org/10.1103/physrevb.24.5349 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060529734
220 rdf:type schema:CreativeWork
221 https://doi.org/10.1103/physrevb.65.144412 schema:sameAs https://app.dimensions.ai/details/publication/pub.1020301594
222 rdf:type schema:CreativeWork
223 https://doi.org/10.1107/s0021889806042117 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013367423
224 rdf:type schema:CreativeWork
225 https://doi.org/10.1107/s0021889869006558 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030634393
226 rdf:type schema:CreativeWork
227 https://doi.org/10.1107/s0021889881009618 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043517724
228 rdf:type schema:CreativeWork
229 https://doi.org/10.1107/s0021889891006441 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004857738
230 rdf:type schema:CreativeWork
231 https://doi.org/10.1107/s0108767307043930 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027786902
232 rdf:type schema:CreativeWork
233 https://doi.org/10.1107/s0909049511013641 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026391140
234 rdf:type schema:CreativeWork
235 https://doi.org/10.1126/science.1067208 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039206546
236 rdf:type schema:CreativeWork
237 https://doi.org/10.1126/science.1075948 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062446917
238 rdf:type schema:CreativeWork
239 https://doi.org/10.1126/science.272.5262.704 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062552908
240 rdf:type schema:CreativeWork
241 https://doi.org/10.1246/bcsj.46.3438 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048023825
242 rdf:type schema:CreativeWork
243 https://www.grid.ac/institutes/grid.11835.3e schema:alternateName University of Sheffield
244 schema:name Department of Chemistry, University of Sheffield, Sheffield S3 7HF, UK.
245 rdf:type schema:Organization
246 https://www.grid.ac/institutes/grid.5338.d schema:alternateName University of Valencia
247 schema:name Instituto de Ciencia Molecular (ICMol), Universidad de Valencia, c/ Catedrático José Beltrán, 2, 46980 Paterna, Spain.
248 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...