Giant barocaloric effect in the ferroic organic-inorganic hybrid [TPrA][Mn(dca)<sub>3</sub>] perovskite under easily accessible pressures View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2017-06-01

AUTHORS

Juan M. Bermúdez-García, Manuel Sánchez-Andújar, Socorro Castro-García, Jorge López-Beceiro, Ramón Artiaga, María A. Señarís-Rodríguez

ABSTRACT

The fast growing family of organic-inorganic hybrid compounds has recently been attracting increased attention owing to the remarkable functional properties (magnetic, multiferroic, optoelectronic, photovoltaic) displayed by some of its members. Here we show that these compounds can also have great potential in the until now unexplored field of solid-state cooling by presenting giant barocaloric effects near room temperature already under easily accessible pressures in the hybrid perovskite [TPrA][Mn(dca)3] (TPrA: tetrapropylammonium, dca: dicyanamide). Moreover, we propose that this will not be an isolated example for such an extraordinary behaviour as many other organic-inorganic hybrids (metal-organic frameworks and coordination polymers) exhibit the basic ingredients to display large caloric effects which can be very sensitive to pressure and other external stimuli. These findings open up new horizons and great opportunities for both organic-inorganic hybrids and for solid-state cooling technologies. More... »

PAGES

15715

References to SciGraph publications

Journal

TITLE

Nature Communications

ISSUE

N/A

VOLUME

8

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/ncomms15715

DOI

http://dx.doi.org/10.1038/ncomms15715

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1085738534

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/28569842


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