A metallic molybdenum dioxide with high stability for surface enhanced Raman spectroscopy View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2017-04-24

AUTHORS

Qiqi Zhang, Xinshi Li, Qiang Ma, Qing Zhang, Hua Bai, Wencai Yi, Jingyao Liu, Jing Han, Guangcheng Xi

ABSTRACT

Compared with noble metals, semiconductors with surface plasmon resonance effect are another type of SERS substrate materials. The main obstacles so far are that the semiconducting materials are often unstable and easy to be further oxidized or decomposed by laser irradiating or contacting with corrosive substances. Here, we report that metallic MoO2 can be used as a SERS substrate to detect trace amounts of highly risk chemicals including bisphenol A (BPA), dichloropheno (DCP), pentachlorophenol (PCP) and so on. The minimum detectable concentration was 10-7 M and the maximum enhancement factor is up to 3.75 × 106. To the best of our knowledge, it may be the best among the metal oxides and even reaches or approaches to Au/Ag. The MoO2 shows an unexpected high oxidation resistance, which can even withstand 300 °C in air without further oxidation. The MoO2 material also can resist long etching of strong acid and alkali. More... »

PAGES

14903

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/ncomms14903

DOI

http://dx.doi.org/10.1038/ncomms14903

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1085050662

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/28436440


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N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1038/ncomms14903'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1038/ncomms14903'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1038/ncomms14903'


 

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