Hydroxyl radical-induced formation of highly oxidized organic compounds View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2016-12-02

AUTHORS

Torsten Berndt, Stefanie Richters, Tuija Jokinen, Noora Hyttinen, Theo Kurtén, Rasmus V. Otkjær, Henrik G. Kjaergaard, Frank Stratmann, Hartmut Herrmann, Mikko Sipilä, Markku Kulmala, Mikael Ehn

ABSTRACT

Explaining the formation of secondary organic aerosol is an intriguing question in atmospheric sciences because of its importance for Earth's radiation budget and the associated effects on health and ecosystems. A breakthrough was recently achieved in the understanding of secondary organic aerosol formation from ozone reactions of biogenic emissions by the rapid formation of highly oxidized multifunctional organic compounds via autoxidation. However, the important daytime hydroxyl radical reactions have been considered to be less important in this process. Here we report measurements on the reaction of hydroxyl radicals with α- and β-pinene applying improved mass spectrometric methods. Our laboratory results prove that the formation of highly oxidized products from hydroxyl radical reactions proceeds with considerably higher yields than previously reported. Field measurements support these findings. Our results allow for a better description of the diurnal behaviour of the highly oxidized product formation and subsequent secondary organic aerosol formation in the atmosphere. More... »

PAGES

13677

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/ncomms13677

DOI

http://dx.doi.org/10.1038/ncomms13677

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1044776216

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/27910849


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N-Triples is a line-based linked data format ideal for batch operations.

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Turtle is a human-readable linked data format.

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RDF/XML is a standard XML format for linked data.

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