Tuning charge and correlation effects for a single molecule on a graphene device View Full Text


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Article Info

DATE

2016-11-25

AUTHORS

Sebastian Wickenburg, Jiong Lu, Johannes Lischner, Hsin-Zon Tsai, Arash A. Omrani, Alexander Riss, Christoph Karrasch, Aaron Bradley, Han Sae Jung, Ramin Khajeh, Dillon Wong, Kenji Watanabe, Takashi Taniguchi, Alex Zettl, A.H. Castro Neto, Steven G. Louie, Michael F. Crommie

ABSTRACT

The ability to understand and control the electronic properties of individual molecules in a device environment is crucial for developing future technologies at the nanometre scale and below. Achieving this, however, requires the creation of three-terminal devices that allow single molecules to be both gated and imaged at the atomic scale. We have accomplished this by integrating a graphene field effect transistor with a scanning tunnelling microscope, thus allowing gate-controlled charging and spectroscopic interrogation of individual tetrafluoro-tetracyanoquinodimethane molecules. We observe a non-rigid shift in the molecule’s lowest unoccupied molecular orbital energy (relative to the Dirac point) as a function of gate voltage due to graphene polarization effects. Our results show that electron–electron interactions play an important role in how molecular energy levels align to the graphene Dirac point, and may significantly influence charge transport through individual molecules incorporated in graphene-based nanodevices. More... »

PAGES

13553

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/ncomms13553

DOI

http://dx.doi.org/10.1038/ncomms13553

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1019968392

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/27886170


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