Ballbot-type motion of N-heterocyclic carbenes on gold surfaces View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-02

AUTHORS

Gaoqiang Wang, Andreas Rühling, Saeed Amirjalayer, Marek Knor, Johannes Bruno Ernst, Christian Richter, Hong-Jun Gao, Alexander Timmer, Hong-Ying Gao, Nikos L. Doltsinis, Frank Glorius, Harald Fuchs

ABSTRACT

Recently, N-heterocyclic carbenes (NHCs) were introduced as alternative anchors for surface modifications and so offered many attractive features, which might render them superior to thiol-based systems. However, little effort has been made to investigate the self-organization process of NHCs on surfaces, an important aspect for the formation of self-assembled monolayers (SAMs), which requires molecular mobility. Based on investigations with scanning tunnelling microscopy and first-principles calculations, we provide an understanding of the microscopic mechanism behind the high mobility observed for NHCs. These NHCs extract a gold atom from the surface, which leads to the formation of an NHC-gold adatom complex that displays a high surface mobility by a ballbot-type motion. Together with their high desorption barrier this enables the formation of ordered and strongly bound SAMs. In addition, this mechanism allows a complementary surface-assisted synthesis of dimeric and hitherto unknown trimeric NHC gold complexes on the surface. More... »

PAGES

152-156

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/nchem.2622

DOI

http://dx.doi.org/10.1038/nchem.2622

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1020834439

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/28282049


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