Imaging single-molecule reaction intermediates stabilized by surface dissipation and entropy View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2016-05-02

AUTHORS

Alexander Riss, Alejandro Pérez Paz, Sebastian Wickenburg, Hsin-Zon Tsai, Dimas G. De Oteyza, Aaron J. Bradley, Miguel M. Ugeda, Patrick Gorman, Han Sae Jung, Michael F. Crommie, Angel Rubio, Felix R. Fischer

ABSTRACT

Chemical transformations at the interface between solid/liquid or solid/gaseous phases of matter lie at the heart of key industrial-scale manufacturing processes. A comprehensive study of the molecular energetics and conformational dynamics that underlie these transformations is often limited to ensemble-averaging analytical techniques. Here we report the detailed investigation of a surface-catalysed cross-coupling and sequential cyclization cascade of 1,2-bis(2-ethynyl phenyl)ethyne on Ag(100). Using non-contact atomic force microscopy, we imaged the single-bond-resolved chemical structure of transient metastable intermediates. Theoretical simulations indicate that the kinetic stabilization of experimentally observable intermediates is determined not only by the potential-energy landscape, but also by selective energy dissipation to the substrate and entropic changes associated with key transformations along the reaction pathway. The microscopic insights gained here pave the way for the rational design and control of complex organic reactions at the surface of heterogeneous catalysts. More... »

PAGES

678-683

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/nchem.2506

DOI

http://dx.doi.org/10.1038/nchem.2506

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1029397198

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/27325094


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Present address: Department of Physics E20, Technical University Munich, James-Franck-Stra\u00dfe 1, 85748 Garching, Germany", 
          "id": "http://www.grid.ac/institutes/grid.6936.a", 
          "name": [
            "Department of Physics, University of California, 94720, Berkeley, California, USA", 
            "Institute of Applied Physics, Vienna University of Technology, 1040, Wien, Austria", 
            "Present address: Department of Physics E20, Technical University Munich, James-Franck-Stra\u00dfe 1, 85748 Garching, Germany"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Riss", 
        "givenName": "Alexander", 
        "id": "sg:person.0620676335.76", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0620676335.76"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Nano-Bio Spectroscopy Group and ETSF, Universidad del Pa\u00eds Vasco, 20018, San Sebasti\u00e1n, Spain", 
          "id": "http://www.grid.ac/institutes/grid.11480.3c", 
          "name": [
            "Nano-Bio Spectroscopy Group and ETSF, Universidad del Pa\u00eds Vasco, 20018, San Sebasti\u00e1n, Spain"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Paz", 
        "givenName": "Alejandro P\u00e9rez", 
        "id": "sg:person.01243706106.96", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01243706106.96"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Materials Sciences Division, Lawrence Berkeley National Laboratory, 94720, Berkeley, California, USA", 
          "id": "http://www.grid.ac/institutes/grid.184769.5", 
          "name": [
            "Department of Physics, University of California, 94720, Berkeley, California, USA", 
            "Materials Sciences Division, Lawrence Berkeley National Laboratory, 94720, Berkeley, California, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Wickenburg", 
        "givenName": "Sebastian", 
        "id": "sg:person.0641012330.19", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0641012330.19"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Physics, University of California, 94720, Berkeley, California, USA", 
          "id": "http://www.grid.ac/institutes/grid.47840.3f", 
          "name": [
            "Department of Physics, University of California, 94720, Berkeley, California, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Tsai", 
        "givenName": "Hsin-Zon", 
        "id": "sg:person.01137602530.65", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01137602530.65"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Centro de F\u00edsica de Materiales CSIC/UPV-EHU-Materials Physics Center, 20018, San Sebasti\u00e1n, Spain", 
          "id": "http://www.grid.ac/institutes/grid.482265.f", 
          "name": [
            "Donostia International Physics Center, 20018, San Sebasti\u00e1n, Spain", 
            "Ikerbasque, Basque Foundation for Science, 48013, Bilbao, Spain", 
            "Centro de F\u00edsica de Materiales CSIC/UPV-EHU-Materials Physics Center, 20018, San Sebasti\u00e1n, Spain"
          ], 
          "type": "Organization"
        }, 
        "familyName": "De Oteyza", 
        "givenName": "Dimas G.", 
        "id": "sg:person.01013021533.53", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01013021533.53"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Physics, University of California, 94720, Berkeley, California, USA", 
          "id": "http://www.grid.ac/institutes/grid.47840.3f", 
          "name": [
            "Department of Physics, University of California, 94720, Berkeley, California, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Bradley", 
        "givenName": "Aaron J.", 
        "id": "sg:person.01064060210.80", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01064060210.80"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "CIC nanoGUNE, 20018, San Sebasti\u00e1n, Spain", 
          "id": "http://www.grid.ac/institutes/grid.424265.3", 
          "name": [
            "Department of Physics, University of California, 94720, Berkeley, California, USA", 
            "Ikerbasque, Basque Foundation for Science, 48013, Bilbao, Spain", 
            "CIC nanoGUNE, 20018, San Sebasti\u00e1n, Spain"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ugeda", 
        "givenName": "Miguel M.", 
        "id": "sg:person.0775607057.55", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0775607057.55"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Chemistry, University of California, 94720, Berkeley, California, USA", 
          "id": "http://www.grid.ac/institutes/grid.47840.3f", 
          "name": [
            "Department of Chemistry, University of California, 94720, Berkeley, California, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Gorman", 
        "givenName": "Patrick", 
        "id": "sg:person.01316303230.55", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01316303230.55"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Chemistry, University of California, 94720, Berkeley, California, USA", 
          "id": "http://www.grid.ac/institutes/grid.47840.3f", 
          "name": [
            "Department of Physics, University of California, 94720, Berkeley, California, USA", 
            "Department of Chemistry, University of California, 94720, Berkeley, California, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Jung", 
        "givenName": "Han Sae", 
        "id": "sg:person.01053410373.29", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01053410373.29"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Kavli Energy NanoSciences Institute at the University of California Berkeley and the Lawrence Berkeley National Laboratory, 94720, Berkeley, California, USA", 
          "id": "http://www.grid.ac/institutes/grid.494610.e", 
          "name": [
            "Department of Physics, University of California, 94720, Berkeley, California, USA", 
            "Materials Sciences Division, Lawrence Berkeley National Laboratory, 94720, Berkeley, California, USA", 
            "Kavli Energy NanoSciences Institute at the University of California Berkeley and the Lawrence Berkeley National Laboratory, 94720, Berkeley, California, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Crommie", 
        "givenName": "Michael F.", 
        "id": "sg:person.01046572263.84", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01046572263.84"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Center for Free-electron Laser Science (CFEL), Luruper Chaussee 149, 22761, Hamburg, Germany", 
          "id": "http://www.grid.ac/institutes/grid.466493.a", 
          "name": [
            "Nano-Bio Spectroscopy Group and ETSF, Universidad del Pa\u00eds Vasco, 20018, San Sebasti\u00e1n, Spain", 
            "Max Planck Institute for the Structure and Dynamics of Matter, Luruper Chaussee 149, 22761, Hamburg, Germany", 
            "Center for Free-electron Laser Science (CFEL), Luruper Chaussee 149, 22761, Hamburg, Germany"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Rubio", 
        "givenName": "Angel", 
        "id": "sg:person.01222456463.35", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01222456463.35"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Kavli Energy NanoSciences Institute at the University of California Berkeley and the Lawrence Berkeley National Laboratory, 94720, Berkeley, California, USA", 
          "id": "http://www.grid.ac/institutes/grid.494610.e", 
          "name": [
            "Materials Sciences Division, Lawrence Berkeley National Laboratory, 94720, Berkeley, California, USA", 
            "Department of Chemistry, University of California, 94720, Berkeley, California, USA", 
            "Kavli Energy NanoSciences Institute at the University of California Berkeley and the Lawrence Berkeley National Laboratory, 94720, Berkeley, California, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Fischer", 
        "givenName": "Felix R.", 
        "id": "sg:person.01314535210.06", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01314535210.06"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1038/nchem.891", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033476971", 
          "https://doi.org/10.1038/nchem.891"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nchem.765", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006572478", 
          "https://doi.org/10.1038/nchem.765"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/ncomms3023", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003898170", 
          "https://doi.org/10.1038/ncomms3023"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/srep03899", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001419535", 
          "https://doi.org/10.1038/srep03899"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/ncomms4931", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019633291", 
          "https://doi.org/10.1038/ncomms4931"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nnano.2007.106", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042874921", 
          "https://doi.org/10.1038/nnano.2007.106"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/ncomms2291", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023723973", 
          "https://doi.org/10.1038/ncomms2291"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2016-05-02", 
    "datePublishedReg": "2016-05-02", 
    "description": "Chemical transformations at the interface between solid/liquid or solid/gaseous phases of matter lie at the heart of key industrial-scale manufacturing processes. A comprehensive study of the molecular energetics and conformational dynamics that underlie these transformations is often limited to ensemble-averaging analytical techniques. Here we report the detailed investigation of a surface-catalysed cross-coupling and sequential cyclization cascade of 1,2-bis(2-ethynyl phenyl)ethyne on Ag(100). Using non-contact atomic force microscopy, we imaged the single-bond-resolved chemical structure of transient metastable intermediates. Theoretical simulations indicate that the kinetic stabilization of experimentally observable intermediates is determined not only by the potential-energy landscape, but also by selective energy dissipation to the substrate and entropic changes associated with key transformations along the reaction pathway. The microscopic insights gained here pave the way for the rational design and control of complex organic reactions at the surface of heterogeneous catalysts.", 
    "genre": "article", 
    "id": "sg:pub.10.1038/nchem.2506", 
    "isAccessibleForFree": true, 
    "isFundedItemOf": [
      {
        "id": "sg:grant.3783982", 
        "type": "MonetaryGrant"
      }
    ], 
    "isPartOf": [
      {
        "id": "sg:journal.1041224", 
        "issn": [
          "1755-4330", 
          "1755-4349"
        ], 
        "name": "Nature Chemistry", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "7", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "8"
      }
    ], 
    "keywords": [
      "non-contact atomic force microscopy", 
      "complex organic reactions", 
      "atomic force microscopy", 
      "organic reactions", 
      "heterogeneous catalysts", 
      "chemical transformations", 
      "reaction intermediates", 
      "chemical structure", 
      "reaction pathways", 
      "molecular energetics", 
      "key transformations", 
      "cyclization cascade", 
      "rational design", 
      "kinetic stabilization", 
      "observable intermediates", 
      "force microscopy", 
      "metastable intermediates", 
      "microscopic insight", 
      "entropic changes", 
      "conformational dynamics", 
      "analytical techniques", 
      "potential energy landscape", 
      "gaseous phase", 
      "intermediates", 
      "matter lies", 
      "theoretical simulations", 
      "surface dissipation", 
      "catalyst", 
      "ethynyl", 
      "detailed investigation", 
      "energy dissipation", 
      "reaction", 
      "dissipation", 
      "energetics", 
      "microscopy", 
      "substrate", 
      "surface", 
      "transformation", 
      "structure", 
      "comprehensive study", 
      "stabilization", 
      "interface", 
      "phase", 
      "manufacturing process", 
      "dynamics", 
      "simulations", 
      "investigation", 
      "process", 
      "technique", 
      "insights", 
      "lies", 
      "pathway", 
      "cascade", 
      "design", 
      "study", 
      "changes", 
      "way", 
      "control", 
      "landscape", 
      "heart"
    ], 
    "name": "Imaging single-molecule reaction intermediates stabilized by surface dissipation and entropy", 
    "pagination": "678-683", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1029397198"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1038/nchem.2506"
        ]
      }, 
      {
        "name": "pubmed_id", 
        "type": "PropertyValue", 
        "value": [
          "27325094"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1038/nchem.2506", 
      "https://app.dimensions.ai/details/publication/pub.1029397198"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-11-24T20:59", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20221124/entities/gbq_results/article/article_692.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1038/nchem.2506"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1038/nchem.2506'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1038/nchem.2506'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1038/nchem.2506'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1038/nchem.2506'


 

This table displays all metadata directly associated to this object as RDF triples.

263 TRIPLES      21 PREDICATES      92 URIs      77 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1038/nchem.2506 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N4432a11fab3e4ed880af03f0c4812a83
4 schema:citation sg:pub.10.1038/nchem.765
5 sg:pub.10.1038/nchem.891
6 sg:pub.10.1038/ncomms2291
7 sg:pub.10.1038/ncomms3023
8 sg:pub.10.1038/ncomms4931
9 sg:pub.10.1038/nnano.2007.106
10 sg:pub.10.1038/srep03899
11 schema:datePublished 2016-05-02
12 schema:datePublishedReg 2016-05-02
13 schema:description Chemical transformations at the interface between solid/liquid or solid/gaseous phases of matter lie at the heart of key industrial-scale manufacturing processes. A comprehensive study of the molecular energetics and conformational dynamics that underlie these transformations is often limited to ensemble-averaging analytical techniques. Here we report the detailed investigation of a surface-catalysed cross-coupling and sequential cyclization cascade of 1,2-bis(2-ethynyl phenyl)ethyne on Ag(100). Using non-contact atomic force microscopy, we imaged the single-bond-resolved chemical structure of transient metastable intermediates. Theoretical simulations indicate that the kinetic stabilization of experimentally observable intermediates is determined not only by the potential-energy landscape, but also by selective energy dissipation to the substrate and entropic changes associated with key transformations along the reaction pathway. The microscopic insights gained here pave the way for the rational design and control of complex organic reactions at the surface of heterogeneous catalysts.
14 schema:genre article
15 schema:isAccessibleForFree true
16 schema:isPartOf N37c2e40552f243c08ec319e82a9dabb6
17 N79e87aad275d46f8949c3bc391db95b7
18 sg:journal.1041224
19 schema:keywords analytical techniques
20 atomic force microscopy
21 cascade
22 catalyst
23 changes
24 chemical structure
25 chemical transformations
26 complex organic reactions
27 comprehensive study
28 conformational dynamics
29 control
30 cyclization cascade
31 design
32 detailed investigation
33 dissipation
34 dynamics
35 energetics
36 energy dissipation
37 entropic changes
38 ethynyl
39 force microscopy
40 gaseous phase
41 heart
42 heterogeneous catalysts
43 insights
44 interface
45 intermediates
46 investigation
47 key transformations
48 kinetic stabilization
49 landscape
50 lies
51 manufacturing process
52 matter lies
53 metastable intermediates
54 microscopic insight
55 microscopy
56 molecular energetics
57 non-contact atomic force microscopy
58 observable intermediates
59 organic reactions
60 pathway
61 phase
62 potential energy landscape
63 process
64 rational design
65 reaction
66 reaction intermediates
67 reaction pathways
68 simulations
69 stabilization
70 structure
71 study
72 substrate
73 surface
74 surface dissipation
75 technique
76 theoretical simulations
77 transformation
78 way
79 schema:name Imaging single-molecule reaction intermediates stabilized by surface dissipation and entropy
80 schema:pagination 678-683
81 schema:productId N027618aa2dc9475fa60e2ff58768401b
82 N9698c6b493534152a486dc71207d8cb2
83 Ne701f59a414e46a18623594f9de4312a
84 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029397198
85 https://doi.org/10.1038/nchem.2506
86 schema:sdDatePublished 2022-11-24T20:59
87 schema:sdLicense https://scigraph.springernature.com/explorer/license/
88 schema:sdPublisher Nf19417c8829044e5b4a1c6719c3fc139
89 schema:url https://doi.org/10.1038/nchem.2506
90 sgo:license sg:explorer/license/
91 sgo:sdDataset articles
92 rdf:type schema:ScholarlyArticle
93 N027618aa2dc9475fa60e2ff58768401b schema:name pubmed_id
94 schema:value 27325094
95 rdf:type schema:PropertyValue
96 N11676503fa6c496bab4083a812ea5796 rdf:first sg:person.0775607057.55
97 rdf:rest N3989cbf0e728483f9a71444e6a6323c9
98 N2978259737514f9d8028ed541bf3fbb2 rdf:first sg:person.01314535210.06
99 rdf:rest rdf:nil
100 N37c2e40552f243c08ec319e82a9dabb6 schema:issueNumber 7
101 rdf:type schema:PublicationIssue
102 N3989cbf0e728483f9a71444e6a6323c9 rdf:first sg:person.01316303230.55
103 rdf:rest Nbfb2d7de29924c3a8d6a017288558692
104 N4432a11fab3e4ed880af03f0c4812a83 rdf:first sg:person.0620676335.76
105 rdf:rest Ncbcfcab12d2a45d282665fbe228ce961
106 N6e45335b48c342b3a9ad1db0e34e1ee2 rdf:first sg:person.01013021533.53
107 rdf:rest Na1a0e639def64fe79a77a0f96727164e
108 N70a79863f37b4c4fb4a945bd615876c0 rdf:first sg:person.0641012330.19
109 rdf:rest Ncfb9a6cc55f54d5aa8365d4d7d7006c3
110 N79e87aad275d46f8949c3bc391db95b7 schema:volumeNumber 8
111 rdf:type schema:PublicationVolume
112 N8ffa9938b3b94c2f917f5f62e0e5e933 rdf:first sg:person.01046572263.84
113 rdf:rest Nd353cd46214743aea0ff3c9439713ec1
114 N9698c6b493534152a486dc71207d8cb2 schema:name dimensions_id
115 schema:value pub.1029397198
116 rdf:type schema:PropertyValue
117 Na1a0e639def64fe79a77a0f96727164e rdf:first sg:person.01064060210.80
118 rdf:rest N11676503fa6c496bab4083a812ea5796
119 Nbfb2d7de29924c3a8d6a017288558692 rdf:first sg:person.01053410373.29
120 rdf:rest N8ffa9938b3b94c2f917f5f62e0e5e933
121 Ncbcfcab12d2a45d282665fbe228ce961 rdf:first sg:person.01243706106.96
122 rdf:rest N70a79863f37b4c4fb4a945bd615876c0
123 Ncfb9a6cc55f54d5aa8365d4d7d7006c3 rdf:first sg:person.01137602530.65
124 rdf:rest N6e45335b48c342b3a9ad1db0e34e1ee2
125 Nd353cd46214743aea0ff3c9439713ec1 rdf:first sg:person.01222456463.35
126 rdf:rest N2978259737514f9d8028ed541bf3fbb2
127 Ne701f59a414e46a18623594f9de4312a schema:name doi
128 schema:value 10.1038/nchem.2506
129 rdf:type schema:PropertyValue
130 Nf19417c8829044e5b4a1c6719c3fc139 schema:name Springer Nature - SN SciGraph project
131 rdf:type schema:Organization
132 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
133 schema:name Chemical Sciences
134 rdf:type schema:DefinedTerm
135 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
136 schema:name Physical Chemistry (incl. Structural)
137 rdf:type schema:DefinedTerm
138 sg:grant.3783982 http://pending.schema.org/fundedItem sg:pub.10.1038/nchem.2506
139 rdf:type schema:MonetaryGrant
140 sg:journal.1041224 schema:issn 1755-4330
141 1755-4349
142 schema:name Nature Chemistry
143 schema:publisher Springer Nature
144 rdf:type schema:Periodical
145 sg:person.01013021533.53 schema:affiliation grid-institutes:grid.482265.f
146 schema:familyName De Oteyza
147 schema:givenName Dimas G.
148 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01013021533.53
149 rdf:type schema:Person
150 sg:person.01046572263.84 schema:affiliation grid-institutes:grid.494610.e
151 schema:familyName Crommie
152 schema:givenName Michael F.
153 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01046572263.84
154 rdf:type schema:Person
155 sg:person.01053410373.29 schema:affiliation grid-institutes:grid.47840.3f
156 schema:familyName Jung
157 schema:givenName Han Sae
158 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01053410373.29
159 rdf:type schema:Person
160 sg:person.01064060210.80 schema:affiliation grid-institutes:grid.47840.3f
161 schema:familyName Bradley
162 schema:givenName Aaron J.
163 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01064060210.80
164 rdf:type schema:Person
165 sg:person.01137602530.65 schema:affiliation grid-institutes:grid.47840.3f
166 schema:familyName Tsai
167 schema:givenName Hsin-Zon
168 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01137602530.65
169 rdf:type schema:Person
170 sg:person.01222456463.35 schema:affiliation grid-institutes:grid.466493.a
171 schema:familyName Rubio
172 schema:givenName Angel
173 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01222456463.35
174 rdf:type schema:Person
175 sg:person.01243706106.96 schema:affiliation grid-institutes:grid.11480.3c
176 schema:familyName Paz
177 schema:givenName Alejandro Pérez
178 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01243706106.96
179 rdf:type schema:Person
180 sg:person.01314535210.06 schema:affiliation grid-institutes:grid.494610.e
181 schema:familyName Fischer
182 schema:givenName Felix R.
183 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01314535210.06
184 rdf:type schema:Person
185 sg:person.01316303230.55 schema:affiliation grid-institutes:grid.47840.3f
186 schema:familyName Gorman
187 schema:givenName Patrick
188 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01316303230.55
189 rdf:type schema:Person
190 sg:person.0620676335.76 schema:affiliation grid-institutes:grid.6936.a
191 schema:familyName Riss
192 schema:givenName Alexander
193 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0620676335.76
194 rdf:type schema:Person
195 sg:person.0641012330.19 schema:affiliation grid-institutes:grid.184769.5
196 schema:familyName Wickenburg
197 schema:givenName Sebastian
198 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0641012330.19
199 rdf:type schema:Person
200 sg:person.0775607057.55 schema:affiliation grid-institutes:grid.424265.3
201 schema:familyName Ugeda
202 schema:givenName Miguel M.
203 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0775607057.55
204 rdf:type schema:Person
205 sg:pub.10.1038/nchem.765 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006572478
206 https://doi.org/10.1038/nchem.765
207 rdf:type schema:CreativeWork
208 sg:pub.10.1038/nchem.891 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033476971
209 https://doi.org/10.1038/nchem.891
210 rdf:type schema:CreativeWork
211 sg:pub.10.1038/ncomms2291 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023723973
212 https://doi.org/10.1038/ncomms2291
213 rdf:type schema:CreativeWork
214 sg:pub.10.1038/ncomms3023 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003898170
215 https://doi.org/10.1038/ncomms3023
216 rdf:type schema:CreativeWork
217 sg:pub.10.1038/ncomms4931 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019633291
218 https://doi.org/10.1038/ncomms4931
219 rdf:type schema:CreativeWork
220 sg:pub.10.1038/nnano.2007.106 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042874921
221 https://doi.org/10.1038/nnano.2007.106
222 rdf:type schema:CreativeWork
223 sg:pub.10.1038/srep03899 schema:sameAs https://app.dimensions.ai/details/publication/pub.1001419535
224 https://doi.org/10.1038/srep03899
225 rdf:type schema:CreativeWork
226 grid-institutes:grid.11480.3c schema:alternateName Nano-Bio Spectroscopy Group and ETSF, Universidad del País Vasco, 20018, San Sebastián, Spain
227 schema:name Nano-Bio Spectroscopy Group and ETSF, Universidad del País Vasco, 20018, San Sebastián, Spain
228 rdf:type schema:Organization
229 grid-institutes:grid.184769.5 schema:alternateName Materials Sciences Division, Lawrence Berkeley National Laboratory, 94720, Berkeley, California, USA
230 schema:name Department of Physics, University of California, 94720, Berkeley, California, USA
231 Materials Sciences Division, Lawrence Berkeley National Laboratory, 94720, Berkeley, California, USA
232 rdf:type schema:Organization
233 grid-institutes:grid.424265.3 schema:alternateName CIC nanoGUNE, 20018, San Sebastián, Spain
234 schema:name CIC nanoGUNE, 20018, San Sebastián, Spain
235 Department of Physics, University of California, 94720, Berkeley, California, USA
236 Ikerbasque, Basque Foundation for Science, 48013, Bilbao, Spain
237 rdf:type schema:Organization
238 grid-institutes:grid.466493.a schema:alternateName Center for Free-electron Laser Science (CFEL), Luruper Chaussee 149, 22761, Hamburg, Germany
239 schema:name Center for Free-electron Laser Science (CFEL), Luruper Chaussee 149, 22761, Hamburg, Germany
240 Max Planck Institute for the Structure and Dynamics of Matter, Luruper Chaussee 149, 22761, Hamburg, Germany
241 Nano-Bio Spectroscopy Group and ETSF, Universidad del País Vasco, 20018, San Sebastián, Spain
242 rdf:type schema:Organization
243 grid-institutes:grid.47840.3f schema:alternateName Department of Chemistry, University of California, 94720, Berkeley, California, USA
244 Department of Physics, University of California, 94720, Berkeley, California, USA
245 schema:name Department of Chemistry, University of California, 94720, Berkeley, California, USA
246 Department of Physics, University of California, 94720, Berkeley, California, USA
247 rdf:type schema:Organization
248 grid-institutes:grid.482265.f schema:alternateName Centro de Física de Materiales CSIC/UPV-EHU-Materials Physics Center, 20018, San Sebastián, Spain
249 schema:name Centro de Física de Materiales CSIC/UPV-EHU-Materials Physics Center, 20018, San Sebastián, Spain
250 Donostia International Physics Center, 20018, San Sebastián, Spain
251 Ikerbasque, Basque Foundation for Science, 48013, Bilbao, Spain
252 rdf:type schema:Organization
253 grid-institutes:grid.494610.e schema:alternateName Kavli Energy NanoSciences Institute at the University of California Berkeley and the Lawrence Berkeley National Laboratory, 94720, Berkeley, California, USA
254 schema:name Department of Chemistry, University of California, 94720, Berkeley, California, USA
255 Department of Physics, University of California, 94720, Berkeley, California, USA
256 Kavli Energy NanoSciences Institute at the University of California Berkeley and the Lawrence Berkeley National Laboratory, 94720, Berkeley, California, USA
257 Materials Sciences Division, Lawrence Berkeley National Laboratory, 94720, Berkeley, California, USA
258 rdf:type schema:Organization
259 grid-institutes:grid.6936.a schema:alternateName Present address: Department of Physics E20, Technical University Munich, James-Franck-Straße 1, 85748 Garching, Germany
260 schema:name Department of Physics, University of California, 94720, Berkeley, California, USA
261 Institute of Applied Physics, Vienna University of Technology, 1040, Wien, Austria
262 Present address: Department of Physics E20, Technical University Munich, James-Franck-Straße 1, 85748 Garching, Germany
263 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...