Ontology type: schema:ScholarlyArticle
2014-07
AUTHORSGaston R. Schaller, Filip Topić, Kari Rissanen, Yoshio Okamoto, Jun Shen, Rainer Herges
ABSTRACTAs long as 50 years ago theoretical calculations predicted that Möbius annulenes with only one π surface and one edge would exhibit peculiar electronic properties and violate the Hückel rules. Numerous synthetic attempts notwithstanding, the first singly twisted Möbius annulene was not prepared until 2003. Here we present a general, rational strategy to synthesize triply or even more highly twisted cyclic π systems. We apply this strategy to the preparation of a triply twisted [24]dehydroannulene, the structure of which was confirmed by X-ray analysis. Our strategy is based on the topological transformation of 'twist' into 'writhe'. The advantage is twofold: the product exhibits a lower degree of strain and precursors can be designed that inherently include the writhe, which, after cyclization, ends up in the Möbius product. With our strategy, triply twisted systems are easier to prepare than their singly twisted counterparts. More... »
PAGES608-613
http://scigraph.springernature.com/pub.10.1038/nchem.1955
DOIhttp://dx.doi.org/10.1038/nchem.1955
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PUBMEDhttps://www.ncbi.nlm.nih.gov/pubmed/24950331
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"sdDataset": "articles",
"sdDatePublished": "2019-04-10T14:48",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8663_00000426.jsonl",
"type": "ScholarlyArticle",
"url": "http://www.nature.com/articles/nchem.1955"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1038/nchem.1955'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1038/nchem.1955'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1038/nchem.1955'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1038/nchem.1955'
This table displays all metadata directly associated to this object as RDF triples.
278 TRIPLES
21 PREDICATES
79 URIs
25 LITERALS
13 BLANK NODES