A two-dimensional polymer prepared by organic synthesis View Full Text


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Article Info

DATE

2012-04

AUTHORS

Patrick Kissel, Rolf Erni, W. Bernd Schweizer, Marta D. Rossell, Benjamin T. King, Thomas Bauer, Stephan Götzinger, A. Dieter Schlüter, Junji Sakamoto

ABSTRACT

Synthetic polymers are widely used materials, as attested by a production of more than 200 millions of tons per year, and are typically composed of linear repeat units. They may also be branched or irregularly crosslinked. Here, we introduce a two-dimensional polymer with internal periodicity composed of areal repeat units. This is an extension of Staudinger's polymerization concept (to form macromolecules by covalently linking repeat units together), but in two dimensions. A well-known example of such a two-dimensional polymer is graphene, but its thermolytic synthesis precludes molecular design on demand. Here, we have rationally synthesized an ordered, non-equilibrium two-dimensional polymer far beyond molecular dimensions. The procedure includes the crystallization of a specifically designed photoreactive monomer into a layered structure, a photo-polymerization step within the crystal and a solvent-induced delamination step that isolates individual two-dimensional polymers as free-standing, monolayered molecular sheets. More... »

PAGES

287

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/nchem.1265

DOI

http://dx.doi.org/10.1038/nchem.1265

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1026810072

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/22437713


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