Single-atom catalysis of CO oxidation using Pt1/FeOx View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-08

AUTHORS

Botao Qiao, Aiqin Wang, Xiaofeng Yang, Lawrence F. Allard, Zheng Jiang, Yitao Cui, Jingyue Liu, Jun Li, Tao Zhang

ABSTRACT

Platinum-based heterogeneous catalysts are critical to many important commercial chemical processes, but their efficiency is extremely low on a per metal atom basis, because only the surface active-site atoms are used. Catalysts with single-atom dispersions are thus highly desirable to maximize atom efficiency, but making them is challenging. Here we report the synthesis of a single-atom catalyst that consists of only isolated single Pt atoms anchored to the surfaces of iron oxide nanocrystallites. This single-atom catalyst has extremely high atom efficiency and shows excellent stability and high activity for both CO oxidation and preferential oxidation of CO in H2. Density functional theory calculations show that the high catalytic activity correlates with the partially vacant 5d orbitals of the positively charged, high-valent Pt atoms, which help to reduce both the CO adsorption energy and the activation barriers for CO oxidation. More... »

PAGES

634

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/nchem.1095

DOI

http://dx.doi.org/10.1038/nchem.1095

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1035388530

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/21778984


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Adsorption", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Carbon Monoxide", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Catalysis", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Ferric Compounds", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Microscopy, Electron, Scanning Transmission", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Oxidation-Reduction", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Platinum", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Spectroscopy, Fourier Transform Infrared", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Dalian Institute of Chemical Physics", 
          "id": "https://www.grid.ac/institutes/grid.423905.9", 
          "name": [
            "State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Qiao", 
        "givenName": "Botao", 
        "id": "sg:person.01201710146.74", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01201710146.74"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Dalian Institute of Chemical Physics", 
          "id": "https://www.grid.ac/institutes/grid.423905.9", 
          "name": [
            "State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Wang", 
        "givenName": "Aiqin", 
        "id": "sg:person.012530523507.59", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012530523507.59"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Tsinghua University", 
          "id": "https://www.grid.ac/institutes/grid.12527.33", 
          "name": [
            "Department of Chemistry, Tsinghua University, Beijing 100084, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Yang", 
        "givenName": "Xiaofeng", 
        "id": "sg:person.01150012135.99", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01150012135.99"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Oak Ridge National Laboratory", 
          "id": "https://www.grid.ac/institutes/grid.135519.a", 
          "name": [
            "Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Allard", 
        "givenName": "Lawrence F.", 
        "id": "sg:person.01134604051.41", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01134604051.41"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Shanghai Institute of Applied Physics", 
          "id": "https://www.grid.ac/institutes/grid.450275.1", 
          "name": [
            "Shanghai Synchrotron Radiation Facility, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201204, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Jiang", 
        "givenName": "Zheng", 
        "id": "sg:person.01247406306.69", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01247406306.69"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Dalian Institute of Chemical Physics", 
          "id": "https://www.grid.ac/institutes/grid.423905.9", 
          "name": [
            "State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Cui", 
        "givenName": "Yitao", 
        "id": "sg:person.0577415220.93", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0577415220.93"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of California Los Angeles", 
          "id": "https://www.grid.ac/institutes/grid.19006.3e", 
          "name": [
            "State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China", 
            "Center for Nanoscience, Department of Physics & Astronomy, and Department of Chemistry & Biochemistry, University of Missouri-St Louis, Missouri 63121, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Liu", 
        "givenName": "Jingyue", 
        "id": "sg:person.01143154225.34", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01143154225.34"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Tsinghua University", 
          "id": "https://www.grid.ac/institutes/grid.12527.33", 
          "name": [
            "Department of Chemistry, Tsinghua University, Beijing 100084, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Li", 
        "givenName": "Jun", 
        "id": "sg:person.01312616330.54", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01312616330.54"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Dalian Institute of Chemical Physics", 
          "id": "https://www.grid.ac/institutes/grid.423905.9", 
          "name": [
            "State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zhang", 
        "givenName": "Tao", 
        "id": "sg:person.013053504600.19", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013053504600.19"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1039/b808341j", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000869843"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b307181b", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001880180"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b414159h", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003152384"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nmat1077", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003430406", 
          "https://doi.org/10.1038/nmat1077"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nmat1077", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003430406", 
          "https://doi.org/10.1038/nmat1077"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0039-6028(99)00200-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005568285"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.81.1038", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005948378"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.81.1038", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005948378"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp0485035", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007413997"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp0485035", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007413997"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0360-0564(02)47008-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1008930637"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/cphc.200400212", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009050406"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.susc.2007.05.028", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013445424"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00769171", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1014153558", 
          "https://doi.org/10.1007/bf00769171"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0909049598017919", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1014676752"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jcat.2008.11.012", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018379112"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0039-6028(97)00144-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021163871"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0039-6028(85)90163-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021435054"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0039-6028(85)90163-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021435054"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nnano.2010.92", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021463263", 
          "https://doi.org/10.1038/nnano.2010.92"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nnano.2010.92", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021463263", 
          "https://doi.org/10.1038/nnano.2010.92"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jcat.2009.11.017", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1024549617"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.1159639", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1025641156"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1098/rsta.2009.0112", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026686893"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/anie.200461699", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027680162"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nature07877", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031191073", 
          "https://doi.org/10.1038/nature07877"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nature07877", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031191073", 
          "https://doi.org/10.1038/nature07877"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0920-5861(96)00208-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031773825"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.1185200", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032844061"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.1185200", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032844061"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nmat2384", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035832865", 
          "https://doi.org/10.1038/nmat2384"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1088/0953-8984/21/13/134010", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038551506"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1088/0953-8984/21/13/134010", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038551506"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.ijhydene.2007.03.031", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040386949"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nature06470", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043162329", 
          "https://doi.org/10.1038/nature06470"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/nn9008142", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043302007"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0021-9517(89)90034-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044585718"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/anie.200461698", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045300766"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1023/a:1020181423055", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1046461927", 
          "https://doi.org/10.1023/a:1020181423055"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.1102420", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1046801465"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jcat.2005.10.014", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047659738"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nature07194", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1049533335", 
          "https://doi.org/10.1038/nature07194"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0039-6028(93)90552-u", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050375032"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0039-6028(93)90552-u", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050375032"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0304-3991(89)90173-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1052214976"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0304-3991(89)90173-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1052214976"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00042a025", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055701566"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja039037k", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055834898"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja039037k", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055834898"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja049436v", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055838078"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja049436v", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055838078"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp909876t", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056118595"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp909876t", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056118595"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1093/jmicro/dfp016", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1059811150"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1093/jmicro/dfp016", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1059811150"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.80.3650", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060817324"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.80.3650", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060817324"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.1085721", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1062448236"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.1100965", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1062450847"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.1104168", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1062451108"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.1135752", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1062454972"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.1176745", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1062460370"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.1176745", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1062460370"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.1180297", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1062461160"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.1188267", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1062461668"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.1188267", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1062461668"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.274.5286.413", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1062554489"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2011-08", 
    "datePublishedReg": "2011-08-01", 
    "description": "Platinum-based heterogeneous catalysts are critical to many important commercial chemical processes, but their efficiency is extremely low on a per metal atom basis, because only the surface active-site atoms are used. Catalysts with single-atom dispersions are thus highly desirable to maximize atom efficiency, but making them is challenging. Here we report the synthesis of a single-atom catalyst that consists of only isolated single Pt atoms anchored to the surfaces of iron oxide nanocrystallites. This single-atom catalyst has extremely high atom efficiency and shows excellent stability and high activity for both CO oxidation and preferential oxidation of CO in H2. Density functional theory calculations show that the high catalytic activity correlates with the partially vacant 5d orbitals of the positively charged, high-valent Pt atoms, which help to reduce both the CO adsorption energy and the activation barriers for CO oxidation.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1038/nchem.1095", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isFundedItemOf": [
      {
        "id": "sg:grant.4977158", 
        "type": "MonetaryGrant"
      }, 
      {
        "id": "sg:grant.4949093", 
        "type": "MonetaryGrant"
      }
    ], 
    "isPartOf": [
      {
        "id": "sg:journal.1041224", 
        "issn": [
          "1755-4330", 
          "1755-4349"
        ], 
        "name": "Nature Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "8", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "3"
      }
    ], 
    "name": "Single-atom catalysis of CO oxidation using Pt1/FeOx", 
    "pagination": "634", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "a89362860ec6a7ae69a32e23f46e24a24e50989ef572bc1e5d0b982a3317a4a0"
        ]
      }, 
      {
        "name": "pubmed_id", 
        "type": "PropertyValue", 
        "value": [
          "21778984"
        ]
      }, 
      {
        "name": "nlm_unique_id", 
        "type": "PropertyValue", 
        "value": [
          "101499734"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1038/nchem.1095"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1035388530"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1038/nchem.1095", 
      "https://app.dimensions.ai/details/publication/pub.1035388530"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T14:49", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8663_00000435.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://www.nature.com/articles/nchem.1095"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1038/nchem.1095'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1038/nchem.1095'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1038/nchem.1095'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1038/nchem.1095'


 

This table displays all metadata directly associated to this object as RDF triples.

333 TRIPLES      21 PREDICATES      87 URIs      29 LITERALS      17 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1038/nchem.1095 schema:about N07cdc4238cf24a099f52f5fbb403ed6f
2 N2aaae4b461a5473e8e5166f11b31130c
3 N3b156417c5fd4359ae91fec7135d7175
4 N506d7f7a1e594a92946361f85a36ee8c
5 N5ef427d58ca041a9b5062382b315dccf
6 N7adb9d18386f4c7886c294e286c01723
7 N8237bb1df24649fa9d4318e5f37203cc
8 Nf687dce7af9a494fbeede6564237d7eb
9 anzsrc-for:03
10 anzsrc-for:0306
11 schema:author Nfba27dc1a8c34de78fac5f4a5148b787
12 schema:citation sg:pub.10.1007/bf00769171
13 sg:pub.10.1023/a:1020181423055
14 sg:pub.10.1038/nature06470
15 sg:pub.10.1038/nature07194
16 sg:pub.10.1038/nature07877
17 sg:pub.10.1038/nmat1077
18 sg:pub.10.1038/nmat2384
19 sg:pub.10.1038/nnano.2010.92
20 https://doi.org/10.1002/anie.200461698
21 https://doi.org/10.1002/anie.200461699
22 https://doi.org/10.1002/cphc.200400212
23 https://doi.org/10.1016/0021-9517(89)90034-1
24 https://doi.org/10.1016/0039-6028(85)90163-3
25 https://doi.org/10.1016/0039-6028(93)90552-u
26 https://doi.org/10.1016/0304-3991(89)90173-3
27 https://doi.org/10.1016/j.ijhydene.2007.03.031
28 https://doi.org/10.1016/j.jcat.2005.10.014
29 https://doi.org/10.1016/j.jcat.2008.11.012
30 https://doi.org/10.1016/j.jcat.2009.11.017
31 https://doi.org/10.1016/j.susc.2007.05.028
32 https://doi.org/10.1016/s0039-6028(97)00144-1
33 https://doi.org/10.1016/s0039-6028(99)00200-9
34 https://doi.org/10.1016/s0360-0564(02)47008-3
35 https://doi.org/10.1016/s0920-5861(96)00208-8
36 https://doi.org/10.1021/ja00042a025
37 https://doi.org/10.1021/ja039037k
38 https://doi.org/10.1021/ja049436v
39 https://doi.org/10.1021/jp0485035
40 https://doi.org/10.1021/jp909876t
41 https://doi.org/10.1021/nn9008142
42 https://doi.org/10.1039/b307181b
43 https://doi.org/10.1039/b414159h
44 https://doi.org/10.1039/b808341j
45 https://doi.org/10.1088/0953-8984/21/13/134010
46 https://doi.org/10.1093/jmicro/dfp016
47 https://doi.org/10.1098/rsta.2009.0112
48 https://doi.org/10.1103/physrevlett.80.3650
49 https://doi.org/10.1103/physrevlett.81.1038
50 https://doi.org/10.1107/s0909049598017919
51 https://doi.org/10.1126/science.1085721
52 https://doi.org/10.1126/science.1100965
53 https://doi.org/10.1126/science.1102420
54 https://doi.org/10.1126/science.1104168
55 https://doi.org/10.1126/science.1135752
56 https://doi.org/10.1126/science.1159639
57 https://doi.org/10.1126/science.1176745
58 https://doi.org/10.1126/science.1180297
59 https://doi.org/10.1126/science.1185200
60 https://doi.org/10.1126/science.1188267
61 https://doi.org/10.1126/science.274.5286.413
62 schema:datePublished 2011-08
63 schema:datePublishedReg 2011-08-01
64 schema:description Platinum-based heterogeneous catalysts are critical to many important commercial chemical processes, but their efficiency is extremely low on a per metal atom basis, because only the surface active-site atoms are used. Catalysts with single-atom dispersions are thus highly desirable to maximize atom efficiency, but making them is challenging. Here we report the synthesis of a single-atom catalyst that consists of only isolated single Pt atoms anchored to the surfaces of iron oxide nanocrystallites. This single-atom catalyst has extremely high atom efficiency and shows excellent stability and high activity for both CO oxidation and preferential oxidation of CO in H2. Density functional theory calculations show that the high catalytic activity correlates with the partially vacant 5d orbitals of the positively charged, high-valent Pt atoms, which help to reduce both the CO adsorption energy and the activation barriers for CO oxidation.
65 schema:genre research_article
66 schema:inLanguage en
67 schema:isAccessibleForFree false
68 schema:isPartOf N4a79e00aab1148c68104ec886b0ff991
69 Nc4b9ffcf2f1f4cc4b06f6cf5f035dd94
70 sg:journal.1041224
71 schema:name Single-atom catalysis of CO oxidation using Pt1/FeOx
72 schema:pagination 634
73 schema:productId N413adb1351464ba1996793ae7f286b91
74 N4aec6e28811741498a916cef4cfff975
75 N8fa5c88c89774c2e85b41aae307fbc35
76 Nc175a54a5dde4c2a8a45a041139a9517
77 Nc9541cbc9bf447bb8ce85588b1453021
78 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035388530
79 https://doi.org/10.1038/nchem.1095
80 schema:sdDatePublished 2019-04-10T14:49
81 schema:sdLicense https://scigraph.springernature.com/explorer/license/
82 schema:sdPublisher Nf22e0237df9f44c49dce98825a184752
83 schema:url https://www.nature.com/articles/nchem.1095
84 sgo:license sg:explorer/license/
85 sgo:sdDataset articles
86 rdf:type schema:ScholarlyArticle
87 N05a8a74882694b78832bf2c376899bcc rdf:first sg:person.01247406306.69
88 rdf:rest Nc9823b09071f4548b0ca5932c4a782d4
89 N07cdc4238cf24a099f52f5fbb403ed6f schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
90 schema:name Ferric Compounds
91 rdf:type schema:DefinedTerm
92 N2aaae4b461a5473e8e5166f11b31130c schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
93 schema:name Platinum
94 rdf:type schema:DefinedTerm
95 N3b156417c5fd4359ae91fec7135d7175 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
96 schema:name Adsorption
97 rdf:type schema:DefinedTerm
98 N413adb1351464ba1996793ae7f286b91 schema:name nlm_unique_id
99 schema:value 101499734
100 rdf:type schema:PropertyValue
101 N4a79e00aab1148c68104ec886b0ff991 schema:issueNumber 8
102 rdf:type schema:PublicationIssue
103 N4aec6e28811741498a916cef4cfff975 schema:name pubmed_id
104 schema:value 21778984
105 rdf:type schema:PropertyValue
106 N506d7f7a1e594a92946361f85a36ee8c schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
107 schema:name Catalysis
108 rdf:type schema:DefinedTerm
109 N52e30831ade84257a853b7a173f12c77 rdf:first sg:person.01312616330.54
110 rdf:rest N90215e45b1614242adceb0ca4805dc81
111 N5ef427d58ca041a9b5062382b315dccf schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
112 schema:name Microscopy, Electron, Scanning Transmission
113 rdf:type schema:DefinedTerm
114 N7adb9d18386f4c7886c294e286c01723 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
115 schema:name Spectroscopy, Fourier Transform Infrared
116 rdf:type schema:DefinedTerm
117 N8237bb1df24649fa9d4318e5f37203cc schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
118 schema:name Oxidation-Reduction
119 rdf:type schema:DefinedTerm
120 N8fa5c88c89774c2e85b41aae307fbc35 schema:name doi
121 schema:value 10.1038/nchem.1095
122 rdf:type schema:PropertyValue
123 N90215e45b1614242adceb0ca4805dc81 rdf:first sg:person.013053504600.19
124 rdf:rest rdf:nil
125 Nb8ebad6debc242b6a425a0f68495c0fc rdf:first sg:person.012530523507.59
126 rdf:rest Nf4cd1629859c4fce948752dc9109cdde
127 Nc175a54a5dde4c2a8a45a041139a9517 schema:name dimensions_id
128 schema:value pub.1035388530
129 rdf:type schema:PropertyValue
130 Nc4b9ffcf2f1f4cc4b06f6cf5f035dd94 schema:volumeNumber 3
131 rdf:type schema:PublicationVolume
132 Nc9541cbc9bf447bb8ce85588b1453021 schema:name readcube_id
133 schema:value a89362860ec6a7ae69a32e23f46e24a24e50989ef572bc1e5d0b982a3317a4a0
134 rdf:type schema:PropertyValue
135 Nc9823b09071f4548b0ca5932c4a782d4 rdf:first sg:person.0577415220.93
136 rdf:rest Nf7e0cb4808fb421a935f0b3bd892e9d4
137 Nd0196fcfa8c74fcc91a7404913b89ca2 rdf:first sg:person.01134604051.41
138 rdf:rest N05a8a74882694b78832bf2c376899bcc
139 Nf22e0237df9f44c49dce98825a184752 schema:name Springer Nature - SN SciGraph project
140 rdf:type schema:Organization
141 Nf4cd1629859c4fce948752dc9109cdde rdf:first sg:person.01150012135.99
142 rdf:rest Nd0196fcfa8c74fcc91a7404913b89ca2
143 Nf687dce7af9a494fbeede6564237d7eb schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
144 schema:name Carbon Monoxide
145 rdf:type schema:DefinedTerm
146 Nf7e0cb4808fb421a935f0b3bd892e9d4 rdf:first sg:person.01143154225.34
147 rdf:rest N52e30831ade84257a853b7a173f12c77
148 Nfba27dc1a8c34de78fac5f4a5148b787 rdf:first sg:person.01201710146.74
149 rdf:rest Nb8ebad6debc242b6a425a0f68495c0fc
150 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
151 schema:name Chemical Sciences
152 rdf:type schema:DefinedTerm
153 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
154 schema:name Physical Chemistry (incl. Structural)
155 rdf:type schema:DefinedTerm
156 sg:grant.4949093 http://pending.schema.org/fundedItem sg:pub.10.1038/nchem.1095
157 rdf:type schema:MonetaryGrant
158 sg:grant.4977158 http://pending.schema.org/fundedItem sg:pub.10.1038/nchem.1095
159 rdf:type schema:MonetaryGrant
160 sg:journal.1041224 schema:issn 1755-4330
161 1755-4349
162 schema:name Nature Chemistry
163 rdf:type schema:Periodical
164 sg:person.01134604051.41 schema:affiliation https://www.grid.ac/institutes/grid.135519.a
165 schema:familyName Allard
166 schema:givenName Lawrence F.
167 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01134604051.41
168 rdf:type schema:Person
169 sg:person.01143154225.34 schema:affiliation https://www.grid.ac/institutes/grid.19006.3e
170 schema:familyName Liu
171 schema:givenName Jingyue
172 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01143154225.34
173 rdf:type schema:Person
174 sg:person.01150012135.99 schema:affiliation https://www.grid.ac/institutes/grid.12527.33
175 schema:familyName Yang
176 schema:givenName Xiaofeng
177 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01150012135.99
178 rdf:type schema:Person
179 sg:person.01201710146.74 schema:affiliation https://www.grid.ac/institutes/grid.423905.9
180 schema:familyName Qiao
181 schema:givenName Botao
182 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01201710146.74
183 rdf:type schema:Person
184 sg:person.01247406306.69 schema:affiliation https://www.grid.ac/institutes/grid.450275.1
185 schema:familyName Jiang
186 schema:givenName Zheng
187 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01247406306.69
188 rdf:type schema:Person
189 sg:person.012530523507.59 schema:affiliation https://www.grid.ac/institutes/grid.423905.9
190 schema:familyName Wang
191 schema:givenName Aiqin
192 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012530523507.59
193 rdf:type schema:Person
194 sg:person.013053504600.19 schema:affiliation https://www.grid.ac/institutes/grid.423905.9
195 schema:familyName Zhang
196 schema:givenName Tao
197 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013053504600.19
198 rdf:type schema:Person
199 sg:person.01312616330.54 schema:affiliation https://www.grid.ac/institutes/grid.12527.33
200 schema:familyName Li
201 schema:givenName Jun
202 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01312616330.54
203 rdf:type schema:Person
204 sg:person.0577415220.93 schema:affiliation https://www.grid.ac/institutes/grid.423905.9
205 schema:familyName Cui
206 schema:givenName Yitao
207 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0577415220.93
208 rdf:type schema:Person
209 sg:pub.10.1007/bf00769171 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014153558
210 https://doi.org/10.1007/bf00769171
211 rdf:type schema:CreativeWork
212 sg:pub.10.1023/a:1020181423055 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046461927
213 https://doi.org/10.1023/a:1020181423055
214 rdf:type schema:CreativeWork
215 sg:pub.10.1038/nature06470 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043162329
216 https://doi.org/10.1038/nature06470
217 rdf:type schema:CreativeWork
218 sg:pub.10.1038/nature07194 schema:sameAs https://app.dimensions.ai/details/publication/pub.1049533335
219 https://doi.org/10.1038/nature07194
220 rdf:type schema:CreativeWork
221 sg:pub.10.1038/nature07877 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031191073
222 https://doi.org/10.1038/nature07877
223 rdf:type schema:CreativeWork
224 sg:pub.10.1038/nmat1077 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003430406
225 https://doi.org/10.1038/nmat1077
226 rdf:type schema:CreativeWork
227 sg:pub.10.1038/nmat2384 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035832865
228 https://doi.org/10.1038/nmat2384
229 rdf:type schema:CreativeWork
230 sg:pub.10.1038/nnano.2010.92 schema:sameAs https://app.dimensions.ai/details/publication/pub.1021463263
231 https://doi.org/10.1038/nnano.2010.92
232 rdf:type schema:CreativeWork
233 https://doi.org/10.1002/anie.200461698 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045300766
234 rdf:type schema:CreativeWork
235 https://doi.org/10.1002/anie.200461699 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027680162
236 rdf:type schema:CreativeWork
237 https://doi.org/10.1002/cphc.200400212 schema:sameAs https://app.dimensions.ai/details/publication/pub.1009050406
238 rdf:type schema:CreativeWork
239 https://doi.org/10.1016/0021-9517(89)90034-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044585718
240 rdf:type schema:CreativeWork
241 https://doi.org/10.1016/0039-6028(85)90163-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1021435054
242 rdf:type schema:CreativeWork
243 https://doi.org/10.1016/0039-6028(93)90552-u schema:sameAs https://app.dimensions.ai/details/publication/pub.1050375032
244 rdf:type schema:CreativeWork
245 https://doi.org/10.1016/0304-3991(89)90173-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1052214976
246 rdf:type schema:CreativeWork
247 https://doi.org/10.1016/j.ijhydene.2007.03.031 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040386949
248 rdf:type schema:CreativeWork
249 https://doi.org/10.1016/j.jcat.2005.10.014 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047659738
250 rdf:type schema:CreativeWork
251 https://doi.org/10.1016/j.jcat.2008.11.012 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018379112
252 rdf:type schema:CreativeWork
253 https://doi.org/10.1016/j.jcat.2009.11.017 schema:sameAs https://app.dimensions.ai/details/publication/pub.1024549617
254 rdf:type schema:CreativeWork
255 https://doi.org/10.1016/j.susc.2007.05.028 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013445424
256 rdf:type schema:CreativeWork
257 https://doi.org/10.1016/s0039-6028(97)00144-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1021163871
258 rdf:type schema:CreativeWork
259 https://doi.org/10.1016/s0039-6028(99)00200-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005568285
260 rdf:type schema:CreativeWork
261 https://doi.org/10.1016/s0360-0564(02)47008-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1008930637
262 rdf:type schema:CreativeWork
263 https://doi.org/10.1016/s0920-5861(96)00208-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031773825
264 rdf:type schema:CreativeWork
265 https://doi.org/10.1021/ja00042a025 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055701566
266 rdf:type schema:CreativeWork
267 https://doi.org/10.1021/ja039037k schema:sameAs https://app.dimensions.ai/details/publication/pub.1055834898
268 rdf:type schema:CreativeWork
269 https://doi.org/10.1021/ja049436v schema:sameAs https://app.dimensions.ai/details/publication/pub.1055838078
270 rdf:type schema:CreativeWork
271 https://doi.org/10.1021/jp0485035 schema:sameAs https://app.dimensions.ai/details/publication/pub.1007413997
272 rdf:type schema:CreativeWork
273 https://doi.org/10.1021/jp909876t schema:sameAs https://app.dimensions.ai/details/publication/pub.1056118595
274 rdf:type schema:CreativeWork
275 https://doi.org/10.1021/nn9008142 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043302007
276 rdf:type schema:CreativeWork
277 https://doi.org/10.1039/b307181b schema:sameAs https://app.dimensions.ai/details/publication/pub.1001880180
278 rdf:type schema:CreativeWork
279 https://doi.org/10.1039/b414159h schema:sameAs https://app.dimensions.ai/details/publication/pub.1003152384
280 rdf:type schema:CreativeWork
281 https://doi.org/10.1039/b808341j schema:sameAs https://app.dimensions.ai/details/publication/pub.1000869843
282 rdf:type schema:CreativeWork
283 https://doi.org/10.1088/0953-8984/21/13/134010 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038551506
284 rdf:type schema:CreativeWork
285 https://doi.org/10.1093/jmicro/dfp016 schema:sameAs https://app.dimensions.ai/details/publication/pub.1059811150
286 rdf:type schema:CreativeWork
287 https://doi.org/10.1098/rsta.2009.0112 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026686893
288 rdf:type schema:CreativeWork
289 https://doi.org/10.1103/physrevlett.80.3650 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060817324
290 rdf:type schema:CreativeWork
291 https://doi.org/10.1103/physrevlett.81.1038 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005948378
292 rdf:type schema:CreativeWork
293 https://doi.org/10.1107/s0909049598017919 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014676752
294 rdf:type schema:CreativeWork
295 https://doi.org/10.1126/science.1085721 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062448236
296 rdf:type schema:CreativeWork
297 https://doi.org/10.1126/science.1100965 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062450847
298 rdf:type schema:CreativeWork
299 https://doi.org/10.1126/science.1102420 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046801465
300 rdf:type schema:CreativeWork
301 https://doi.org/10.1126/science.1104168 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062451108
302 rdf:type schema:CreativeWork
303 https://doi.org/10.1126/science.1135752 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062454972
304 rdf:type schema:CreativeWork
305 https://doi.org/10.1126/science.1159639 schema:sameAs https://app.dimensions.ai/details/publication/pub.1025641156
306 rdf:type schema:CreativeWork
307 https://doi.org/10.1126/science.1176745 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062460370
308 rdf:type schema:CreativeWork
309 https://doi.org/10.1126/science.1180297 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062461160
310 rdf:type schema:CreativeWork
311 https://doi.org/10.1126/science.1185200 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032844061
312 rdf:type schema:CreativeWork
313 https://doi.org/10.1126/science.1188267 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062461668
314 rdf:type schema:CreativeWork
315 https://doi.org/10.1126/science.274.5286.413 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062554489
316 rdf:type schema:CreativeWork
317 https://www.grid.ac/institutes/grid.12527.33 schema:alternateName Tsinghua University
318 schema:name Department of Chemistry, Tsinghua University, Beijing 100084, China
319 rdf:type schema:Organization
320 https://www.grid.ac/institutes/grid.135519.a schema:alternateName Oak Ridge National Laboratory
321 schema:name Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA
322 rdf:type schema:Organization
323 https://www.grid.ac/institutes/grid.19006.3e schema:alternateName University of California Los Angeles
324 schema:name Center for Nanoscience, Department of Physics & Astronomy, and Department of Chemistry & Biochemistry, University of Missouri-St Louis, Missouri 63121, USA
325 State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
326 rdf:type schema:Organization
327 https://www.grid.ac/institutes/grid.423905.9 schema:alternateName Dalian Institute of Chemical Physics
328 schema:name State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
329 State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
330 rdf:type schema:Organization
331 https://www.grid.ac/institutes/grid.450275.1 schema:alternateName Shanghai Institute of Applied Physics
332 schema:name Shanghai Synchrotron Radiation Facility, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201204, China
333 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...