Visible-light-enhanced catalytic oxidation reactions on plasmonic silver nanostructures View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-06

AUTHORS

Phillip Christopher, Hongliang Xin, Suljo Linic

ABSTRACT

Catalysis plays a critical role in chemical conversion, energy production and pollution mitigation. High activation barriers associated with rate-limiting elementary steps require most commercial heterogeneous catalytic reactions to be run at relatively high temperatures, which compromises energy efficiency and the long-term stability of the catalyst. Here we show that plasmonic nanostructures of silver can concurrently use low-intensity visible light (on the order of solar intensity) and thermal energy to drive catalytic oxidation reactions--such as ethylene epoxidation, CO oxidation, and NH₃ oxidation--at lower temperatures than their conventional counterparts that use only thermal stimulus. Based on kinetic isotope experiments and density functional calculations, we postulate that excited plasmons on the silver surface act to populate O₂ antibonding orbitals and so form a transient negative-ion state, which thereby facilitates the rate-limiting O₂-dissociation reaction. The results could assist the design of catalytic processes that are more energy efficient and robust than current processes. More... »

PAGES

467

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/nchem.1032

DOI

http://dx.doi.org/10.1038/nchem.1032

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1053372875

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/21602862


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