Ontology type: schema:ScholarlyArticle
2015-02-04
AUTHORSAnton A. Toutov, Wen-Bo Liu, Kerry N. Betz, Alexey Fedorov, Brian M. Stoltz, Robert H. Grubbs
ABSTRACTCarbon–hydrogen (C–H) bond functionalization catalysed by potassium tert-butoxide, which is abundant and inexpensive, offers a direct route to the silylation of aromatic heterocycles that both obviates the need for precious metal catalysts and overcomes the limitations of previous methods.
PAGES80-84
http://scigraph.springernature.com/pub.10.1038/nature14126
DOIhttp://dx.doi.org/10.1038/nature14126
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1036785057
PUBMEDhttps://www.ncbi.nlm.nih.gov/pubmed/25652999
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Inorganic Chemistry",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Physical Chemistry (incl. Structural)",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0399",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Other Chemical Sciences",
"type": "DefinedTerm"
},
{
"inDefinedTermSet": "https://www.nlm.nih.gov/mesh/",
"name": "Butanols",
"type": "DefinedTerm"
},
{
"inDefinedTermSet": "https://www.nlm.nih.gov/mesh/",
"name": "Carbon",
"type": "DefinedTerm"
},
{
"inDefinedTermSet": "https://www.nlm.nih.gov/mesh/",
"name": "Catalysis",
"type": "DefinedTerm"
},
{
"inDefinedTermSet": "https://www.nlm.nih.gov/mesh/",
"name": "Cyclization",
"type": "DefinedTerm"
},
{
"inDefinedTermSet": "https://www.nlm.nih.gov/mesh/",
"name": "Drug Discovery",
"type": "DefinedTerm"
},
{
"inDefinedTermSet": "https://www.nlm.nih.gov/mesh/",
"name": "Hydrogen",
"type": "DefinedTerm"
},
{
"inDefinedTermSet": "https://www.nlm.nih.gov/mesh/",
"name": "Indoles",
"type": "DefinedTerm"
},
{
"inDefinedTermSet": "https://www.nlm.nih.gov/mesh/",
"name": "Nitrogen",
"type": "DefinedTerm"
},
{
"inDefinedTermSet": "https://www.nlm.nih.gov/mesh/",
"name": "Oxygen",
"type": "DefinedTerm"
},
{
"inDefinedTermSet": "https://www.nlm.nih.gov/mesh/",
"name": "Potassium",
"type": "DefinedTerm"
},
{
"inDefinedTermSet": "https://www.nlm.nih.gov/mesh/",
"name": "Silanes",
"type": "DefinedTerm"
},
{
"inDefinedTermSet": "https://www.nlm.nih.gov/mesh/",
"name": "Silicon",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "Division of Chemistry and Chemical Engineering, California Institute of Technology, 91125, Pasadena, California, USA",
"id": "http://www.grid.ac/institutes/grid.20861.3d",
"name": [
"Division of Chemistry and Chemical Engineering, California Institute of Technology, 91125, Pasadena, California, USA"
],
"type": "Organization"
},
"familyName": "Toutov",
"givenName": "Anton A.",
"id": "sg:person.0743670506.74",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0743670506.74"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Division of Chemistry and Chemical Engineering, California Institute of Technology, 91125, Pasadena, California, USA",
"id": "http://www.grid.ac/institutes/grid.20861.3d",
"name": [
"Division of Chemistry and Chemical Engineering, California Institute of Technology, 91125, Pasadena, California, USA"
],
"type": "Organization"
},
"familyName": "Liu",
"givenName": "Wen-Bo",
"id": "sg:person.01104553521.38",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01104553521.38"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Division of Chemistry and Chemical Engineering, California Institute of Technology, 91125, Pasadena, California, USA",
"id": "http://www.grid.ac/institutes/grid.20861.3d",
"name": [
"Division of Chemistry and Chemical Engineering, California Institute of Technology, 91125, Pasadena, California, USA"
],
"type": "Organization"
},
"familyName": "Betz",
"givenName": "Kerry N.",
"id": "sg:person.01223171050.68",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01223171050.68"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Present address: Department of Chemistry and Applied Biosciences, ETH Z\u00fcrich, Vladimir Prelog Weg 2, CH-8093 Z\u00fcrich, Switzerland.",
"id": "http://www.grid.ac/institutes/grid.5801.c",
"name": [
"Division of Chemistry and Chemical Engineering, California Institute of Technology, 91125, Pasadena, California, USA",
"Present address: Department of Chemistry and Applied Biosciences, ETH Z\u00fcrich, Vladimir Prelog Weg 2, CH-8093 Z\u00fcrich, Switzerland."
],
"type": "Organization"
},
"familyName": "Fedorov",
"givenName": "Alexey",
"id": "sg:person.015062515063.19",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015062515063.19"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Division of Chemistry and Chemical Engineering, California Institute of Technology, 91125, Pasadena, California, USA",
"id": "http://www.grid.ac/institutes/grid.20861.3d",
"name": [
"Division of Chemistry and Chemical Engineering, California Institute of Technology, 91125, Pasadena, California, USA"
],
"type": "Organization"
},
"familyName": "Stoltz",
"givenName": "Brian M.",
"id": "sg:person.0754742372.07",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0754742372.07"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Division of Chemistry and Chemical Engineering, California Institute of Technology, 91125, Pasadena, California, USA",
"id": "http://www.grid.ac/institutes/grid.20861.3d",
"name": [
"Division of Chemistry and Chemical Engineering, California Institute of Technology, 91125, Pasadena, California, USA"
],
"type": "Organization"
},
"familyName": "Grubbs",
"givenName": "Robert H.",
"id": "sg:person.0767103710.37",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0767103710.37"
],
"type": "Person"
}
],
"citation": [
{
"id": "sg:pub.10.1038/nchem.1669",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1040221087",
"https://doi.org/10.1038/nchem.1669"
],
"type": "CreativeWork"
}
],
"datePublished": "2015-02-04",
"datePublishedReg": "2015-02-04",
"description": "Carbon\u2013hydrogen (C\u2013H) bond functionalization catalysed by potassium tert-butoxide, which is abundant and inexpensive, offers a direct route to the silylation of aromatic heterocycles that both obviates the need for precious metal catalysts and overcomes the limitations of previous methods.",
"genre": "article",
"id": "sg:pub.10.1038/nature14126",
"isAccessibleForFree": false,
"isFundedItemOf": [
{
"id": "sg:grant.3137367",
"type": "MonetaryGrant"
},
{
"id": "sg:grant.3139339",
"type": "MonetaryGrant"
}
],
"isPartOf": [
{
"id": "sg:journal.1018957",
"issn": [
"0028-0836",
"1476-4687"
],
"name": "Nature",
"publisher": "Springer Nature",
"type": "Periodical"
},
{
"issueNumber": "7537",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "518"
}
],
"keywords": [
"metal catalysts",
"aromatic heterocycles",
"carbon-hydrogen bond functionalization",
"earth-abundant metal catalysts",
"precious metal catalysts",
"potassium tert-butoxide",
"bond functionalization",
"H bonds",
"tert-butoxide",
"catalyst",
"heterocycles",
"silylation",
"direct route",
"functionalization",
"bonds",
"route",
"method",
"previous methods",
"limitations",
"need"
],
"name": "Silylation of C\u2013H bonds in aromatic heterocycles by an Earth-abundant metal catalyst",
"pagination": "80-84",
"productId": [
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1036785057"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1038/nature14126"
]
},
{
"name": "pubmed_id",
"type": "PropertyValue",
"value": [
"25652999"
]
}
],
"sameAs": [
"https://doi.org/10.1038/nature14126",
"https://app.dimensions.ai/details/publication/pub.1036785057"
],
"sdDataset": "articles",
"sdDatePublished": "2022-08-04T17:04",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-springernature-scigraph/baseset/20220804/entities/gbq_results/article/article_663.jsonl",
"type": "ScholarlyArticle",
"url": "https://doi.org/10.1038/nature14126"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1038/nature14126'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1038/nature14126'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1038/nature14126'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1038/nature14126'
This table displays all metadata directly associated to this object as RDF triples.
184 TRIPLES
21 PREDICATES
60 URIs
49 LITERALS
19 BLANK NODES