Hybrid organic–inorganic rotaxanes and molecular shuttles View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-03

AUTHORS

Chin-Fa Lee, David A. Leigh, Robin G. Pritchard, David Schultz, Simon J. Teat, Grigore A. Timco, Richard E. P. Winpenny

ABSTRACT

Rotaxanes show their metalRotaxane molecules contain interlocked parts: ring-shaped subunits encircle the 'axles' of molecular dumbbells. The rings can spin around and slide along the axle, and so rotaxanes are mooted as possible components of molecular machines. To date, most rotaxanes are organic. This could be a problem, because the physical properties that are most desirable in molecular machines — such as magnetism, or the ability to conduct electrons — are mostly found in inorganic compounds. Chin-Fa Lee et al. now report hybrid rotaxanes, in which inorganic heterometallic rings encircle the axles of organic dumbbells. These hybrids are expected to offer a far wider range of useful physical properties to molecular engineers than purely organic rotaxanes. More... »

PAGES

314-318

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/nature07847

DOI

http://dx.doi.org/10.1038/nature07847

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1042149207

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/19295605


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