Solid-state dye-sensitized mesoporous TiO2 solar cells with high photon-to-electron conversion efficiencies View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1998-10

AUTHORS

U. Bach, D. Lupo, P. Comte, J. E. Moser, F. Weissörtel, J. Salbeck, H. Spreitzer, M. Grätzel

ABSTRACT

Solar cells based on dye-sensitized mesoporous films of TiO2 arelow-cost alternatives to conventional solid-state devices1. Impressive solar-to-electrical energy conversion efficiencies have been achieved with such films when used in conjunction with liquid electrolytes2. Practical advantages may be gained by the replacement of the liquid electrolyte with a solid charge-transport material. Inorganic p-type semiconductors3,4 and organic materials5,6,7,8,9 have been tested in this regard, but in all cases the incident monochromatic photon-to-electron conversion efficiency remained low. Here we describe a dye-sensitized heterojunction of TiO2 with the amorphous organic hole-transport material 2,2′,7,7′-tetrakis(N,N-di-p-methoxyphenyl-amine)9,9′-spirobifluorene (OMeTAD; refs. 10 and 11). Photoinduced charge-carrier generation at the heterojunction is very efficient. A solar cell based on OMeTAD converts photons to electric current with a high yield of 33%. More... »

PAGES

583-585

Journal

TITLE

Nature

ISSUE

6702

VOLUME

395

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  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1038/26936

    DOI

    http://dx.doi.org/10.1038/26936

    DIMENSIONS

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