Nature of the Iron–Oxygen Bond in Oxyhæmoglobin View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1964-04

AUTHORS

JOSE J. WEISS

ABSTRACT

HÆMOGLOBIN (Hb) can combine with molecular oxygen to give oxyhæmoglobin (HbO2) in which one molecule of oxygen is associated with one hæmin group1. In hæmoglobin the iron is in the ferrous state, and it is generally assumed that the combination with molecular oxygen does not change its valency so that HbO2 is likewise supposed to be a ferrous compound. However, it would appear that many of the physical properties of oxyhæmoglobin are at variance with such a view. Principally these are1 : (1) magnetic properties ; (2) absorption spectrum ; (3) acid dissociation constant. These facts suggest that the conversion of hæmoglobin into oxyhæmoglobin is associated with a more profound electronic rearrangement. More... »

PAGES

83-84

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1038/202083b0

DOI

http://dx.doi.org/10.1038/202083b0

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1018908384

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/14166723


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Carbon Monoxide", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Chemical Phenomena", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Ferrocyanides", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Hemoglobins", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Hydrogen Peroxide", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Iron", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Oxygen", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Oxyhemoglobins", 
        "type": "DefinedTerm"
      }, 
      {
        "inDefinedTermSet": "https://www.nlm.nih.gov/mesh/", 
        "name": "Research", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "familyName": "WEISS", 
        "givenName": "JOSE J.", 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/bf02155128", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004587189", 
          "https://doi.org/10.1007/bf02155128"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02155128", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004587189", 
          "https://doi.org/10.1007/bf02155128"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/1911386a0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019643093", 
          "https://doi.org/10.1038/1911386a0"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1042/bj0350328", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045199671"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1042/bj0350328", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045199671"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.1749353", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057811348"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1964-04", 
    "datePublishedReg": "1964-04-01", 
    "description": "H\u00c6MOGLOBIN (Hb) can combine with molecular oxygen to give oxyh\u00e6moglobin (HbO2) in which one molecule of oxygen is associated with one h\u00e6min group1. In h\u00e6moglobin the iron is in the ferrous state, and it is generally assumed that the combination with molecular oxygen does not change its valency so that HbO2 is likewise supposed to be a ferrous compound. However, it would appear that many of the physical properties of oxyh\u00e6moglobin are at variance with such a view. Principally these are1 : (1) magnetic properties ; (2) absorption spectrum ; (3) acid dissociation constant. These facts suggest that the conversion of h\u00e6moglobin into oxyh\u00e6moglobin is associated with a more profound electronic rearrangement.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1038/202083b0", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1018957", 
        "issn": [
          "0090-0028", 
          "1476-4687"
        ], 
        "name": "Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "4927", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "202"
      }
    ], 
    "name": "Nature of the Iron\u2013Oxygen Bond in Oxyh\u00e6moglobin", 
    "pagination": "83-84", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "5a17d2774d1fc08b88fa80746c24484c6c9c4dbe5471e3a497bbf02fa4d7110d"
        ]
      }, 
      {
        "name": "pubmed_id", 
        "type": "PropertyValue", 
        "value": [
          "14166723"
        ]
      }, 
      {
        "name": "nlm_unique_id", 
        "type": "PropertyValue", 
        "value": [
          "0410462"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1038/202083b0"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1018908384"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1038/202083b0", 
      "https://app.dimensions.ai/details/publication/pub.1018908384"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T22:19", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8690_00000424.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://www.nature.com/articles/202083b0"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1038/202083b0'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1038/202083b0'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1038/202083b0'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1038/202083b0'


 

This table displays all metadata directly associated to this object as RDF triples.

118 TRIPLES      21 PREDICATES      43 URIs      31 LITERALS      19 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1038/202083b0 schema:about N0b42bb2509ca4098b2fd41f24d054f1d
2 N6bc789bb33424ed6ade02e3e91df58c3
3 N83625f1651b14ae8b0dccadf0aa2df63
4 Nacc85d674a6f461c88aed3ee885806f9
5 Naee47ec806cb447b96efc0a82fdb90f6
6 Nb6cb1e19e114428a9ffc3b4018574a15
7 Ncb001bf0f69c46acb3bf63fdf55ce9e3
8 Ndda4710bcaf24529b5bcd1ad7f71274f
9 Nf05f7dc2db8f46c3bd8b9efbc0b6cb2a
10 Nf17e7dc331d446729e8300c2c1d09af5
11 anzsrc-for:03
12 anzsrc-for:0302
13 schema:author N7138e5bb5f8b40698734ba76067cff38
14 schema:citation sg:pub.10.1007/bf02155128
15 sg:pub.10.1038/1911386a0
16 https://doi.org/10.1042/bj0350328
17 https://doi.org/10.1063/1.1749353
18 schema:datePublished 1964-04
19 schema:datePublishedReg 1964-04-01
20 schema:description HÆMOGLOBIN (Hb) can combine with molecular oxygen to give oxyhæmoglobin (HbO2) in which one molecule of oxygen is associated with one hæmin group1. In hæmoglobin the iron is in the ferrous state, and it is generally assumed that the combination with molecular oxygen does not change its valency so that HbO2 is likewise supposed to be a ferrous compound. However, it would appear that many of the physical properties of oxyhæmoglobin are at variance with such a view. Principally these are1 : (1) magnetic properties ; (2) absorption spectrum ; (3) acid dissociation constant. These facts suggest that the conversion of hæmoglobin into oxyhæmoglobin is associated with a more profound electronic rearrangement.
21 schema:genre research_article
22 schema:inLanguage en
23 schema:isAccessibleForFree false
24 schema:isPartOf N7ca3bd25bdc64fc3ab1aedf849590ea4
25 N7dc4abd5dfd3413994f177ebcdadacda
26 sg:journal.1018957
27 schema:name Nature of the Iron–Oxygen Bond in Oxyhæmoglobin
28 schema:pagination 83-84
29 schema:productId N1e8e7e1c8e754e68a3c2d47ecc79595d
30 N45bcc6ff09ff42e3aeb6fcd1ba0feb03
31 N4e00bdebcdc5465a91a96475a224c35e
32 Nb2ead7681cf24efab45499bb441d7679
33 Nc6eeee94ae66488d9708f8b0313decd1
34 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018908384
35 https://doi.org/10.1038/202083b0
36 schema:sdDatePublished 2019-04-10T22:19
37 schema:sdLicense https://scigraph.springernature.com/explorer/license/
38 schema:sdPublisher N6de442a447a34ff0b76fbdc06b44e25a
39 schema:url http://www.nature.com/articles/202083b0
40 sgo:license sg:explorer/license/
41 sgo:sdDataset articles
42 rdf:type schema:ScholarlyArticle
43 N0b42bb2509ca4098b2fd41f24d054f1d schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
44 schema:name Research
45 rdf:type schema:DefinedTerm
46 N1e8e7e1c8e754e68a3c2d47ecc79595d schema:name readcube_id
47 schema:value 5a17d2774d1fc08b88fa80746c24484c6c9c4dbe5471e3a497bbf02fa4d7110d
48 rdf:type schema:PropertyValue
49 N45bcc6ff09ff42e3aeb6fcd1ba0feb03 schema:name doi
50 schema:value 10.1038/202083b0
51 rdf:type schema:PropertyValue
52 N4e00bdebcdc5465a91a96475a224c35e schema:name pubmed_id
53 schema:value 14166723
54 rdf:type schema:PropertyValue
55 N654804e259a240a69c961a38793919b8 schema:familyName WEISS
56 schema:givenName JOSE J.
57 rdf:type schema:Person
58 N6bc789bb33424ed6ade02e3e91df58c3 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
59 schema:name Carbon Monoxide
60 rdf:type schema:DefinedTerm
61 N6de442a447a34ff0b76fbdc06b44e25a schema:name Springer Nature - SN SciGraph project
62 rdf:type schema:Organization
63 N7138e5bb5f8b40698734ba76067cff38 rdf:first N654804e259a240a69c961a38793919b8
64 rdf:rest rdf:nil
65 N7ca3bd25bdc64fc3ab1aedf849590ea4 schema:issueNumber 4927
66 rdf:type schema:PublicationIssue
67 N7dc4abd5dfd3413994f177ebcdadacda schema:volumeNumber 202
68 rdf:type schema:PublicationVolume
69 N83625f1651b14ae8b0dccadf0aa2df63 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
70 schema:name Hemoglobins
71 rdf:type schema:DefinedTerm
72 Nacc85d674a6f461c88aed3ee885806f9 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
73 schema:name Hydrogen Peroxide
74 rdf:type schema:DefinedTerm
75 Naee47ec806cb447b96efc0a82fdb90f6 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
76 schema:name Chemical Phenomena
77 rdf:type schema:DefinedTerm
78 Nb2ead7681cf24efab45499bb441d7679 schema:name dimensions_id
79 schema:value pub.1018908384
80 rdf:type schema:PropertyValue
81 Nb6cb1e19e114428a9ffc3b4018574a15 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
82 schema:name Oxygen
83 rdf:type schema:DefinedTerm
84 Nc6eeee94ae66488d9708f8b0313decd1 schema:name nlm_unique_id
85 schema:value 0410462
86 rdf:type schema:PropertyValue
87 Ncb001bf0f69c46acb3bf63fdf55ce9e3 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
88 schema:name Ferrocyanides
89 rdf:type schema:DefinedTerm
90 Ndda4710bcaf24529b5bcd1ad7f71274f schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
91 schema:name Iron
92 rdf:type schema:DefinedTerm
93 Nf05f7dc2db8f46c3bd8b9efbc0b6cb2a schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
94 schema:name Oxyhemoglobins
95 rdf:type schema:DefinedTerm
96 Nf17e7dc331d446729e8300c2c1d09af5 schema:inDefinedTermSet https://www.nlm.nih.gov/mesh/
97 schema:name Chemistry
98 rdf:type schema:DefinedTerm
99 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
100 schema:name Chemical Sciences
101 rdf:type schema:DefinedTerm
102 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
103 schema:name Inorganic Chemistry
104 rdf:type schema:DefinedTerm
105 sg:journal.1018957 schema:issn 0090-0028
106 1476-4687
107 schema:name Nature
108 rdf:type schema:Periodical
109 sg:pub.10.1007/bf02155128 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004587189
110 https://doi.org/10.1007/bf02155128
111 rdf:type schema:CreativeWork
112 sg:pub.10.1038/1911386a0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019643093
113 https://doi.org/10.1038/1911386a0
114 rdf:type schema:CreativeWork
115 https://doi.org/10.1042/bj0350328 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045199671
116 rdf:type schema:CreativeWork
117 https://doi.org/10.1063/1.1749353 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057811348
118 rdf:type schema:CreativeWork
 




Preview window. Press ESC to close (or click here)


...