Ontology type: schema:ScholarlyArticle
2004-03
AUTHORSA. M. Nesterenko, V. I. Staninets
ABSTRACTThe reaction paths for the transformations of substituted acetylenes (X—C≡C—Y; X, Y = H, Me, Ph, CN) in reaction with phenylsulfenium cation were studied by quantum-chemical methods. It was shown that the reactions take place with the formation of acyclic and cyclic cationic intermediates. The factor that determines the structure and characteristics of these cations is the induction and polarizing action of the substituents in the acetylenes and to a lesser degree their electron-donor characteristics. The resonance effect of the phenyl substituent has a predominantly levelling action on the distribution of charges. More... »
PAGES77-85
http://scigraph.springernature.com/pub.10.1023/b:thec.0000028901.13190.e7
DOIhttp://dx.doi.org/10.1023/b:thec.0000028901.13190.e7
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