Crystalline inclusion compounds derived from bulky organosilicon hosts – design, synthesis, structure and stability View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2003-01

AUTHORS

Silke I. Nitsche, Edwin Weber, Wilhelm Seichter, Nikoletta Báthori, Kayrat M. Beketov, Gerhard Roewer

ABSTRACT

New organosilicon compounds 1–3 featuring bulky triphenylsilyl moieties attached to rigid linear or trigonal spacer units have been synthesized and demonstrated to act as clathrate hosts, yielding crystalline inclusion compounds mostly with apolar and aprotic dipolar guest molecules, while the nonbulky dimethylphenylsilyl or trimethylsilyl substituted analogous compounds 4 and 5, which were also synthesized, proved inefficient. X-ray crystal structures of the inclusion compounds 1·DMF (1:1), 1·pyridine (1:1), 2·1,4-dioxane (2:1), 2·pyridine (2:1), 2·p-xylene (2:1), 2·H2O (2:1) as well as of the unsolvated compounds 2 and 5 are described, and thermal stability studies of selected clathrates are reported. More... »

PAGES

55-71

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/b:silc.0000047934.01345.7d

DOI

http://dx.doi.org/10.1023/b:silc.0000047934.01345.7d

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1043836309


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "name": [
            "Institut f\u00fcr Organische Chemie, Technische Universit\u00e4t Bergakademie Freiberg, Leipziger Str. 29, D-09596, Freiberg/Sachsen, Germany"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Nitsche", 
        "givenName": "Silke I.", 
        "id": "sg:person.011166431757.16", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011166431757.16"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Institut f\u00fcr Organische Chemie, Technische Universit\u00e4t Bergakademie Freiberg, Leipziger Str. 29, D-09596, Freiberg/Sachsen, Germany"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Weber", 
        "givenName": "Edwin", 
        "id": "sg:person.01016205541.34", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01016205541.34"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Institut f\u00fcr Organische Chemie, Technische Universit\u00e4t Bergakademie Freiberg, Leipziger Str. 29, D-09596, Freiberg/Sachsen, Germany"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Seichter", 
        "givenName": "Wilhelm", 
        "id": "sg:person.0750072341.09", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0750072341.09"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "MTA Research Centre for Natural Sciences", 
          "id": "https://www.grid.ac/institutes/grid.425578.9", 
          "name": [
            "Chemical Research Center, Institute of Chemistry, Hungarian Academy of Sciences, P.O. Box, 17, 1525, Budapest, Hungary"
          ], 
          "type": "Organization"
        }, 
        "familyName": "B\u00e1thori", 
        "givenName": "Nikoletta", 
        "id": "sg:person.0755131015.36", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0755131015.36"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "National Academy of Sciences of the Republic of Kazakhstan", 
          "id": "https://www.grid.ac/institutes/grid.425413.5", 
          "name": [
            "Institute of Chemical Sciences, Ualikhanov Str. 106, 480100, Almaty, Kazakstan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Beketov", 
        "givenName": "Kayrat M.", 
        "id": "sg:person.016077222245.39", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016077222245.39"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Institut f\u00fcr Organische Chemie, Technische Universit\u00e4t Bergakademie Freiberg, Leipziger Str. 29, D-09596, Freiberg/Sachsen, Germany"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Roewer", 
        "givenName": "Gerhard", 
        "id": "sg:person.0703324575.00", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0703324575.00"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1002/(sici)1521-3897(199904)341:3<252::aid-prac252>3.0.co;2-r", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005342271"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/00397919608004542", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011171991"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1023/a:1007960204731", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019750632", 
          "https://doi.org/10.1023/a:1007960204731"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/jhet.5570210268", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027078604"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/jhet.5570210268", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027078604"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/(sici)1521-3765(20000103)6:1<54::aid-chem54>3.0.co;2-y", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043363432"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jo00051a063", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055963418"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2003-01", 
    "datePublishedReg": "2003-01-01", 
    "description": "New organosilicon compounds 1\u20133 featuring bulky triphenylsilyl moieties attached to rigid linear or trigonal spacer units have been synthesized and demonstrated to act as clathrate hosts, yielding crystalline inclusion compounds mostly with apolar and aprotic dipolar guest molecules, while the nonbulky dimethylphenylsilyl or trimethylsilyl substituted analogous compounds 4 and 5, which were also synthesized, proved inefficient. X-ray crystal structures of the inclusion compounds 1\u00b7DMF (1:1), 1\u00b7pyridine (1:1), 2\u00b71,4-dioxane (2:1), 2\u00b7pyridine (2:1), 2\u00b7p-xylene (2:1), 2\u00b7H2O (2:1) as well as of the unsolvated compounds 2 and 5 are described, and thermal stability studies of selected clathrates are reported.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1023/b:silc.0000047934.01345.7d", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1146861", 
        "issn": [
          "1569-0660", 
          "1572-8994"
        ], 
        "name": "Silicon Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1-2", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "2"
      }
    ], 
    "name": "Crystalline inclusion compounds derived from bulky organosilicon hosts \u2013 design, synthesis, structure and stability", 
    "pagination": "55-71", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "d0cf187933d92b73cf987d923c9795726a3402d85d7c6603f63d50265578252f"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1023/b:silc.0000047934.01345.7d"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1043836309"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1023/b:silc.0000047934.01345.7d", 
      "https://app.dimensions.ai/details/publication/pub.1043836309"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T17:30", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8672_00000507.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1023%2FB%3ASILC.0000047934.01345.7d"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1023/b:silc.0000047934.01345.7d'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1023/b:silc.0000047934.01345.7d'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1023/b:silc.0000047934.01345.7d'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1023/b:silc.0000047934.01345.7d'


 

This table displays all metadata directly associated to this object as RDF triples.

126 TRIPLES      21 PREDICATES      33 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1023/b:silc.0000047934.01345.7d schema:about anzsrc-for:03
2 anzsrc-for:0302
3 schema:author N587055f008c64b4cb46cc89d6d7fd4c5
4 schema:citation sg:pub.10.1023/a:1007960204731
5 https://doi.org/10.1002/(sici)1521-3765(20000103)6:1<54::aid-chem54>3.0.co;2-y
6 https://doi.org/10.1002/(sici)1521-3897(199904)341:3<252::aid-prac252>3.0.co;2-r
7 https://doi.org/10.1002/jhet.5570210268
8 https://doi.org/10.1021/jo00051a063
9 https://doi.org/10.1080/00397919608004542
10 schema:datePublished 2003-01
11 schema:datePublishedReg 2003-01-01
12 schema:description New organosilicon compounds 1–3 featuring bulky triphenylsilyl moieties attached to rigid linear or trigonal spacer units have been synthesized and demonstrated to act as clathrate hosts, yielding crystalline inclusion compounds mostly with apolar and aprotic dipolar guest molecules, while the nonbulky dimethylphenylsilyl or trimethylsilyl substituted analogous compounds 4 and 5, which were also synthesized, proved inefficient. X-ray crystal structures of the inclusion compounds 1·DMF (1:1), 1·pyridine (1:1), 2·1,4-dioxane (2:1), 2·pyridine (2:1), 2·p-xylene (2:1), 2·H2O (2:1) as well as of the unsolvated compounds 2 and 5 are described, and thermal stability studies of selected clathrates are reported.
13 schema:genre research_article
14 schema:inLanguage en
15 schema:isAccessibleForFree false
16 schema:isPartOf N922040ee6c8e446bafb14788e78f8d23
17 Ncb65d5f9720a4768b39c0b30b2f99ca1
18 sg:journal.1146861
19 schema:name Crystalline inclusion compounds derived from bulky organosilicon hosts – design, synthesis, structure and stability
20 schema:pagination 55-71
21 schema:productId N1291868d03e1417d8d38d42960ee9012
22 N3266ec2201254ad1b748dc004ca93ec1
23 Nf650252df9c549aa9332de37a794f45d
24 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043836309
25 https://doi.org/10.1023/b:silc.0000047934.01345.7d
26 schema:sdDatePublished 2019-04-10T17:30
27 schema:sdLicense https://scigraph.springernature.com/explorer/license/
28 schema:sdPublisher Nddde30fca36946438519727ade01978c
29 schema:url http://link.springer.com/10.1023%2FB%3ASILC.0000047934.01345.7d
30 sgo:license sg:explorer/license/
31 sgo:sdDataset articles
32 rdf:type schema:ScholarlyArticle
33 N02aa87bba5be44f9a1b1e70ea48cc18a schema:name Institut für Organische Chemie, Technische Universität Bergakademie Freiberg, Leipziger Str. 29, D-09596, Freiberg/Sachsen, Germany
34 rdf:type schema:Organization
35 N1075ed232c0543b4af480880d2d0309f rdf:first sg:person.0750072341.09
36 rdf:rest N89bfd3436c8c4956b2d9a004a1cb48d3
37 N1291868d03e1417d8d38d42960ee9012 schema:name readcube_id
38 schema:value d0cf187933d92b73cf987d923c9795726a3402d85d7c6603f63d50265578252f
39 rdf:type schema:PropertyValue
40 N3266ec2201254ad1b748dc004ca93ec1 schema:name dimensions_id
41 schema:value pub.1043836309
42 rdf:type schema:PropertyValue
43 N4fcda2392c0644f5a2b5d59486dbb83a rdf:first sg:person.016077222245.39
44 rdf:rest Nfdefa60ba78f4d5f903a5bf883611148
45 N587055f008c64b4cb46cc89d6d7fd4c5 rdf:first sg:person.011166431757.16
46 rdf:rest N9381f3941ea74ee193c97169bc3ee7e8
47 N86632260ca7a4814811fb3009355d287 schema:name Institut für Organische Chemie, Technische Universität Bergakademie Freiberg, Leipziger Str. 29, D-09596, Freiberg/Sachsen, Germany
48 rdf:type schema:Organization
49 N89bfd3436c8c4956b2d9a004a1cb48d3 rdf:first sg:person.0755131015.36
50 rdf:rest N4fcda2392c0644f5a2b5d59486dbb83a
51 N922040ee6c8e446bafb14788e78f8d23 schema:issueNumber 1-2
52 rdf:type schema:PublicationIssue
53 N9381f3941ea74ee193c97169bc3ee7e8 rdf:first sg:person.01016205541.34
54 rdf:rest N1075ed232c0543b4af480880d2d0309f
55 N98882159cb5f4207825a2a7580920515 schema:name Institut für Organische Chemie, Technische Universität Bergakademie Freiberg, Leipziger Str. 29, D-09596, Freiberg/Sachsen, Germany
56 rdf:type schema:Organization
57 Ncb65d5f9720a4768b39c0b30b2f99ca1 schema:volumeNumber 2
58 rdf:type schema:PublicationVolume
59 Nddde30fca36946438519727ade01978c schema:name Springer Nature - SN SciGraph project
60 rdf:type schema:Organization
61 Nf614cb377486477e9d76a9b9d18d3563 schema:name Institut für Organische Chemie, Technische Universität Bergakademie Freiberg, Leipziger Str. 29, D-09596, Freiberg/Sachsen, Germany
62 rdf:type schema:Organization
63 Nf650252df9c549aa9332de37a794f45d schema:name doi
64 schema:value 10.1023/b:silc.0000047934.01345.7d
65 rdf:type schema:PropertyValue
66 Nfdefa60ba78f4d5f903a5bf883611148 rdf:first sg:person.0703324575.00
67 rdf:rest rdf:nil
68 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
69 schema:name Chemical Sciences
70 rdf:type schema:DefinedTerm
71 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
72 schema:name Inorganic Chemistry
73 rdf:type schema:DefinedTerm
74 sg:journal.1146861 schema:issn 1569-0660
75 1572-8994
76 schema:name Silicon Chemistry
77 rdf:type schema:Periodical
78 sg:person.01016205541.34 schema:affiliation N02aa87bba5be44f9a1b1e70ea48cc18a
79 schema:familyName Weber
80 schema:givenName Edwin
81 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01016205541.34
82 rdf:type schema:Person
83 sg:person.011166431757.16 schema:affiliation N98882159cb5f4207825a2a7580920515
84 schema:familyName Nitsche
85 schema:givenName Silke I.
86 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011166431757.16
87 rdf:type schema:Person
88 sg:person.016077222245.39 schema:affiliation https://www.grid.ac/institutes/grid.425413.5
89 schema:familyName Beketov
90 schema:givenName Kayrat M.
91 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016077222245.39
92 rdf:type schema:Person
93 sg:person.0703324575.00 schema:affiliation N86632260ca7a4814811fb3009355d287
94 schema:familyName Roewer
95 schema:givenName Gerhard
96 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0703324575.00
97 rdf:type schema:Person
98 sg:person.0750072341.09 schema:affiliation Nf614cb377486477e9d76a9b9d18d3563
99 schema:familyName Seichter
100 schema:givenName Wilhelm
101 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0750072341.09
102 rdf:type schema:Person
103 sg:person.0755131015.36 schema:affiliation https://www.grid.ac/institutes/grid.425578.9
104 schema:familyName Báthori
105 schema:givenName Nikoletta
106 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0755131015.36
107 rdf:type schema:Person
108 sg:pub.10.1023/a:1007960204731 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019750632
109 https://doi.org/10.1023/a:1007960204731
110 rdf:type schema:CreativeWork
111 https://doi.org/10.1002/(sici)1521-3765(20000103)6:1<54::aid-chem54>3.0.co;2-y schema:sameAs https://app.dimensions.ai/details/publication/pub.1043363432
112 rdf:type schema:CreativeWork
113 https://doi.org/10.1002/(sici)1521-3897(199904)341:3<252::aid-prac252>3.0.co;2-r schema:sameAs https://app.dimensions.ai/details/publication/pub.1005342271
114 rdf:type schema:CreativeWork
115 https://doi.org/10.1002/jhet.5570210268 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027078604
116 rdf:type schema:CreativeWork
117 https://doi.org/10.1021/jo00051a063 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055963418
118 rdf:type schema:CreativeWork
119 https://doi.org/10.1080/00397919608004542 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011171991
120 rdf:type schema:CreativeWork
121 https://www.grid.ac/institutes/grid.425413.5 schema:alternateName National Academy of Sciences of the Republic of Kazakhstan
122 schema:name Institute of Chemical Sciences, Ualikhanov Str. 106, 480100, Almaty, Kazakstan
123 rdf:type schema:Organization
124 https://www.grid.ac/institutes/grid.425578.9 schema:alternateName MTA Research Centre for Natural Sciences
125 schema:name Chemical Research Center, Institute of Chemistry, Hungarian Academy of Sciences, P.O. Box, 17, 1525, Budapest, Hungary
126 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...