Trinuclear Metal Chelates of β-Aminovinylimines View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2003-08

AUTHORS

A. S. Burlov, L. I. Kuznetsova, A. I. Uraev, V. P. Kurbatov, G. I. Bondarenko, I. S. Vasil'chenko, A. D. Garnovskii

ABSTRACT

The chemical and electrochemical syntheses of Cu(II), Ni(II), Co(II), Zn(II), and Cd(II) trinuclear metal chelates with a new tetradentate ligand system including bis[(2-hydroxy-, -mercapto-, and -N-tosylamino)anils] of nitro- and phenylmalonaldehyde were performed. Temperature dependences of magnetic and ESR spectral properties of the complexes were studied to show that the antiferromagnetic spin-spin exchange interactions between copper(II) ions are intra- and intermolecular in nature and depend on the composition and structure of the coordination units, steric effects, nature of the substituent in the malonaldehyde moiety of the ligand, as well as on the method of synthesis of the complex compounds. More... »

PAGES

1190-1197

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/b:rugc.0000007639.42616.88

DOI

http://dx.doi.org/10.1023/b:rugc.0000007639.42616.88

DIMENSIONS

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141 schema:name Research Institute of Physical and Organic Chemistry, Rostov State University, Rostov-on-Don, Russia
142 rdf:type schema:Organization
 




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