Copper(II) Chelate Complex with N′-(2,4-Dichlorophenoxy)acetyl-N,N-Dimethylhydrazine: Crystal and Molecular Structure View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2004-10

AUTHORS

V. F. Shul'gin, N. S. Pevzner, V. Ya. Zub, N. G. Strizhakova, Yu. A. Maletin

ABSTRACT

X-ray diffraction analysis of the copper(II) chelate complex CuL2 (where L is the deprotonated imid-ol form of N,N-dimethyl-2,4-dichlorophenoxyacetohydrazide (HL)) was performed (3826 reflections, R = 0.039, wR = 0.043). Crystals are monoclinic, a = 8.365(7) Å, b = 23.090(7)Å, c = 12.713(3) Å, β = 95.12(6)°, space group P21/c, Z = 4. The slightly distorted square environment of the copper cation is composed of two N atoms of the dimethylamino groups and two O atoms of the deprotonated imidol groups. Both N and O atoms are located in trans-positions relative to each other. Additional coordination of electron-donor atoms is prevented by methyl groups, in which the C atoms are at a distance of 2.837 to 2.918 Å from the central ion. More... »

PAGES

723-726

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/b:ruco.0000043898.36993.d4

DOI

http://dx.doi.org/10.1023/b:ruco.0000043898.36993.d4

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1000748724


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