Stabilization of [2.2]paracyclophane anion as a result of transannular interaction View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2004-06

AUTHORS

I. V. Fedyanin, K. A. Lyssenko, Z. A. Starikova, M. Yu. Antipin

ABSTRACT

Topological analysis of the electron density distribution in the [2.2]paracyclophane radical anion and radical cation based on the results of B3PW91/6-31+G(d) calculations revealed that reduction of the electron affinity energy down to –0.5 eV (more than a twofold decrease compared to benzene) is a result of transannular interaction between the benzene rings. More... »

PAGES

1153-1158

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/b:rucb.0000042267.48995.77

DOI

http://dx.doi.org/10.1023/b:rucb.0000042267.48995.77

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1013779880


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