An improved procedure for the synthesis of N-bromoacetyl-β-glycopyranosylamines, derivatives of mono- and disaccharides View Full Text


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Article Info

DATE

2004-03

AUTHORS

L. M. Likhosherstov, O. S. Novikova, A. O. Zheltova, V. N. Shibaev

ABSTRACT

An improved procedure for the synthesis of N-bromoacetyl-β-glycopyranosylamines from the corresponding β-glycosylamines was developed. The procedure is applicable to a wide range of derivatives of monosaccharides (hexoses, 2-acetamido-2-deoxyhexoses, hexuronamides, and 6-deoxyhexoses) and some disaccharides. For the derivatives of pentoses and 2-deoxyhexoses, the use of the corresponding β-glycosylammonium carbamates was found to be more convenient. N-Bromoacetyl-β-glycopyranosylamines derived from D-mannose, L-rhamnose, D-glucuronamide, 2-deoxy-D-arabino-hexose, 2-deoxy-D-lyxo-hexose, and melibiose were obtained for the first time. More... »

PAGES

709-713

References to SciGraph publications

  • 1913-10. Über die Eignung von Bromessigsäureestern für Grignard'sche Synthesen in MONATSHEFTE FÜR CHEMIE - CHEMICAL MONTHLY
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    http://scigraph.springernature.com/pub.10.1023/b:rucb.0000035661.45796.f7

    DOI

    http://dx.doi.org/10.1023/b:rucb.0000035661.45796.f7

    DIMENSIONS

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