Synthesis of 4-aminoisoxazole-3-carboxamides using base-promoted nitrosation of N-substituted cyanoacetamides View Full Text


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Article Info

DATE

2004-03

AUTHORS

V. P. Kislyi, E. B. Danilova, E. P. Zakharov, V. V. Semenov

ABSTRACT

The reactions of N-substituted cyanoacetamides with EtONO in the presence of an equimolar amount of EtONa afforded the corresponding sodium salts of hydroxyimino derivatives in 70—95% yields. The latter were transformed into 4-amino-5-(4-bromobenzoyl)isoxazole-3-carboxamides in 30—57% yields using the known method.

PAGES

622-625

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/b:rucb.0000035646.13790.8a

DOI

http://dx.doi.org/10.1023/b:rucb.0000035646.13790.8a

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1047101099


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