Reactions of 4-methylidenedioxolan-2-ones with 2-methyltryptamines. Synthesis of core analogs of aurantioclavine View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2004-03

AUTHORS

I. Yu. Titov, N. B. Chernysheva, A. A. Bogolyubov, V. V. Semenov, V. G. Nenajdenko, E. S. Balenkova

ABSTRACT

4-Hydroxy-4,5,5-trimethyl-3-[2-(2-methyl-7-R-1H-indol-3-yl)ethyl]-1,3-oxazolidin-2-ones (R = H or Alk), which were synthesized from 4-methylidene-1,3-dioxolan-2-one and substituted 2-methyltryptamines, undergo intramolecular amidoalkylation when treated with polyphosphoric acid. First representatives of a new heterocyclic system, viz., oxazolo[3",4":1,2]azepino[5,4,3-cd]indole, which are core analogs of aurantioclavine, were prepared.

PAGES

569-572

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/b:rucb.0000035639.83432.20

DOI

http://dx.doi.org/10.1023/b:rucb.0000035639.83432.20

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1003669862


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