Binuclear and polynuclear transition metal complexes with macrocyclic ligands. 3. New polydentate macrocyclic ligands in reactions of 4-alkyl-2,6-diformylphenols with 1,2-diaminobenzenes View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2004-01

AUTHORS

N. E. Borisova, M. D. Reshetova, Yu. A. Ustynyuk

ABSTRACT

The mechanism of abnormal condensation of 2,6-diformyl-4-R-phenols with 1,2-diaminobenzenes accompanied by the reduction of two of four double C=N bonds in macrocyclic Schiff"s bases formed was studied by DFT (gradient-corrected PBE functional, TZ2p basis set). In the first step, [1+1] Schiff"s base is formed and disproportionates further to afford amine and benzoimidazolylphenols. Two new macrocyclic polydentate ligands containing two CH2—NH moieties in the rings were synthesized. The reduction of one of these ligands with sodium borohydride gave the new macrocyclic ligand, whose structure and conformations were studied by the DFT method. More... »

PAGES

181-188

Journal

TITLE

Russian Chemical Bulletin

ISSUE

1

VOLUME

53

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/b:rucb.0000024848.03470.25

DOI

http://dx.doi.org/10.1023/b:rucb.0000024848.03470.25

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1027246694


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