Molecular Ionics of Anion Receptor Molecules: A Microcalorimetric Study View Full Text


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Article Info

DATE

2004-08

AUTHORS

D. Grell, E. Grell, P. Bugnon, B. Dietrich, J.-M. Lehn

ABSTRACT

The coordination of divalent and monovalent inorganic anions to synthetic polyammonium receptors is investigated in aqueous solution around neutral pH by titration calorimetry and NMR spectroscopy. High-affinity 1:1 complexes are formed by a pyrrole type cryptand (1) with sulfate and phosphate, characterized by association constants of almost 107 M-1. Affinities close to 105 M-1 are found for polyazacryptands (3 and 4) exhibiting F-/Cl- selectivity. The binding affinities and the anion selectivities are mainly caused by the charges of ligands and anions, which is discussed on the basis of simple calculations of the electrostatic contribution to the anion/receptor interactions. The binding of all investigated anions is exothermic at 298.2 K. The contribution of the large negative ΔH values to the free energy of anion binding of the pyrrole type ligand is partially compensated by marked negative ΔS values. These unfavorable entropic contributions are attributed to the additional inclusion of water molecules in the anion/receptor complexes. More... »

PAGES

483-495

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/b:jtan.0000038988.19849.bb

DOI

http://dx.doi.org/10.1023/b:jtan.0000038988.19849.bb

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1004672673


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