Dehydration and crystallization process in sol-gel zirconia View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2004-06

AUTHORS

M. Picquart, T. López, R. Gómez, E. Torres, A. Moreno, J. Garcia

ABSTRACT

Sol-gel zirconia was characterized using high-resolution thermogravimetry (Hi-Res TG) and differential scanning calorimetry (DSC) and compared with X-ray diffraction, Raman scattering, and UV-Vis spectroscopy. ZrO2-x(OH)2x·yH2O annealed below 400°C show typical behavior of amorphous material. As the annealing temperature is increased, the tetragonal and monoclinic phases crystallize. Typical Hi-Res TG curve shows that the samples are continuously dehydrated in a long temperature range, between room temperature and 600°C. The total mass loss relative to the initial mass is of about 29%. The DSC analysis coupled with TG and structural information, indicate that the exothermic processes about 355 and 447°C can be related to the nucleation process of the formation of tetragonal zirconia, with bulk crystallization at 447°C. More... »

PAGES

755-761

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/b:jtan.0000032260.31955.6e

DOI

http://dx.doi.org/10.1023/b:jtan.0000032260.31955.6e

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1040328823


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Departamento de F\u00edsica, Universidad Aut\u00f3noma Metropolitana, Apto Postal 55 534, 09340, M\u00e9xico DF, M\u00e9xico", 
          "id": "http://www.grid.ac/institutes/grid.7220.7", 
          "name": [
            "Departamento de F\u00edsica, Universidad Aut\u00f3noma Metropolitana, Apto Postal 55 534, 09340, M\u00e9xico DF, M\u00e9xico"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Picquart", 
        "givenName": "M.", 
        "id": "sg:person.0772163367.18", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0772163367.18"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Departamento de F\u00edsica, Universidad Aut\u00f3noma Metropolitana, Apto Postal 55 534, 09340, M\u00e9xico DF, M\u00e9xico", 
          "id": "http://www.grid.ac/institutes/grid.7220.7", 
          "name": [
            "Departamento de F\u00edsica, Universidad Aut\u00f3noma Metropolitana, Apto Postal 55 534, 09340, M\u00e9xico DF, M\u00e9xico"
          ], 
          "type": "Organization"
        }, 
        "familyName": "L\u00f3pez", 
        "givenName": "T.", 
        "id": "sg:person.01224263261.90", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01224263261.90"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Departamento de F\u00edsica, Universidad Aut\u00f3noma Metropolitana, Apto Postal 55 534, 09340, M\u00e9xico DF, M\u00e9xico", 
          "id": "http://www.grid.ac/institutes/grid.7220.7", 
          "name": [
            "Departamento de F\u00edsica, Universidad Aut\u00f3noma Metropolitana, Apto Postal 55 534, 09340, M\u00e9xico DF, M\u00e9xico"
          ], 
          "type": "Organization"
        }, 
        "familyName": "G\u00f3mez", 
        "givenName": "R.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Instituto Mexicano del Petr\u00f3leo Eje Central, Lazaro Cardenas No. 152, C.P. 07730, M\u00e9xico DF, M\u00e9xico", 
          "id": "http://www.grid.ac/institutes/grid.419156.e", 
          "name": [
            "Instituto Mexicano del Petr\u00f3leo Eje Central, Lazaro Cardenas No. 152, C.P. 07730, M\u00e9xico DF, M\u00e9xico"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Torres", 
        "givenName": "E.", 
        "id": "sg:person.07740754633.38", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07740754633.38"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Departamento de F\u00edsica, Universidad Aut\u00f3noma Metropolitana, Apto Postal 55 534, 09340, M\u00e9xico DF, M\u00e9xico", 
          "id": "http://www.grid.ac/institutes/grid.7220.7", 
          "name": [
            "Departamento de F\u00edsica, Universidad Aut\u00f3noma Metropolitana, Apto Postal 55 534, 09340, M\u00e9xico DF, M\u00e9xico"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Moreno", 
        "givenName": "A.", 
        "id": "sg:person.014722267613.11", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014722267613.11"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Departamento de F\u00edsica, Universidad Aut\u00f3noma Metropolitana, Apto Postal 55 534, 09340, M\u00e9xico DF, M\u00e9xico", 
          "id": "http://www.grid.ac/institutes/grid.7220.7", 
          "name": [
            "Departamento de F\u00edsica, Universidad Aut\u00f3noma Metropolitana, Apto Postal 55 534, 09340, M\u00e9xico DF, M\u00e9xico"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Garcia", 
        "givenName": "J.", 
        "id": "sg:person.011766015543.76", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011766015543.76"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1023/a:1019972125701", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039231819", 
          "https://doi.org/10.1023/a:1019972125701"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00357343", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045091348", 
          "https://doi.org/10.1007/bf00357343"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1023/a:1016113800165", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019643246", 
          "https://doi.org/10.1023/a:1016113800165"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1557/jmr.2001.0303", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033067410", 
          "https://doi.org/10.1557/jmr.2001.0303"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1023/a:1014957215646", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019288868", 
          "https://doi.org/10.1023/a:1014957215646"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1023/a:1016031517430", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033429515", 
          "https://doi.org/10.1023/a:1016031517430"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1557/jmr.1988.0787", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021637341", 
          "https://doi.org/10.1557/jmr.1988.0787"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2004-06", 
    "datePublishedReg": "2004-06-01", 
    "description": "Sol-gel zirconia was characterized using high-resolution thermogravimetry (Hi-Res TG) and differential scanning calorimetry (DSC) and compared with X-ray diffraction, Raman scattering, and UV-Vis spectroscopy. ZrO2-x(OH)2x\u00b7yH2O annealed below 400\u00b0C show typical behavior of amorphous material. As the annealing temperature is increased, the tetragonal and monoclinic phases crystallize. Typical Hi-Res TG curve shows that the samples are continuously dehydrated in a long temperature range, between room temperature and 600\u00b0C. The total mass loss relative to the initial mass is of about 29%. The DSC analysis coupled with TG and structural information, indicate that the exothermic processes about 355 and 447\u00b0C can be related to the nucleation process of the formation of tetragonal zirconia, with bulk crystallization at 447\u00b0C.", 
    "genre": "article", 
    "id": "sg:pub.10.1023/b:jtan.0000032260.31955.6e", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1294862", 
        "issn": [
          "1388-6150", 
          "1572-8943"
        ], 
        "name": "Journal of Thermal Analysis and Calorimetry", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "3", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "76"
      }
    ], 
    "keywords": [
      "sol-gel zirconia", 
      "differential scanning calorimetry", 
      "UV-Vis spectroscopy", 
      "X-ray diffraction", 
      "high-resolution thermogravimetry", 
      "long temperature range", 
      "DSC analysis", 
      "scanning calorimetry", 
      "exothermic process", 
      "Raman scattering", 
      "TG curves", 
      "structural information", 
      "monoclinic phase", 
      "crystallization process", 
      "tetragonal zirconia", 
      "zirconia", 
      "bulk crystallization", 
      "room temperature", 
      "amorphous materials", 
      "total mass loss", 
      "nucleation process", 
      "temperature range", 
      "spectroscopy", 
      "thermogravimetry", 
      "annealing temperature", 
      "diffraction", 
      "calorimetry", 
      "ZrO2", 
      "crystallization", 
      "temperature", 
      "mass loss", 
      "Tg", 
      "typical behavior", 
      "dehydration", 
      "materials", 
      "formation", 
      "process", 
      "scattering", 
      "phase", 
      "range", 
      "samples", 
      "behavior", 
      "initial mass", 
      "curves", 
      "analysis", 
      "mass", 
      "loss", 
      "information"
    ], 
    "name": "Dehydration and crystallization process in sol-gel zirconia", 
    "pagination": "755-761", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1040328823"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1023/b:jtan.0000032260.31955.6e"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1023/b:jtan.0000032260.31955.6e", 
      "https://app.dimensions.ai/details/publication/pub.1040328823"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-12-01T06:24", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20221201/entities/gbq_results/article/article_384.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1023/b:jtan.0000032260.31955.6e"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1023/b:jtan.0000032260.31955.6e'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1023/b:jtan.0000032260.31955.6e'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1023/b:jtan.0000032260.31955.6e'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1023/b:jtan.0000032260.31955.6e'


 

This table displays all metadata directly associated to this object as RDF triples.

170 TRIPLES      21 PREDICATES      80 URIs      65 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1023/b:jtan.0000032260.31955.6e schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N9865674e560247ffbe0c7566a3456b11
4 schema:citation sg:pub.10.1007/bf00357343
5 sg:pub.10.1023/a:1014957215646
6 sg:pub.10.1023/a:1016031517430
7 sg:pub.10.1023/a:1016113800165
8 sg:pub.10.1023/a:1019972125701
9 sg:pub.10.1557/jmr.1988.0787
10 sg:pub.10.1557/jmr.2001.0303
11 schema:datePublished 2004-06
12 schema:datePublishedReg 2004-06-01
13 schema:description Sol-gel zirconia was characterized using high-resolution thermogravimetry (Hi-Res TG) and differential scanning calorimetry (DSC) and compared with X-ray diffraction, Raman scattering, and UV-Vis spectroscopy. ZrO2-x(OH)2x·yH2O annealed below 400°C show typical behavior of amorphous material. As the annealing temperature is increased, the tetragonal and monoclinic phases crystallize. Typical Hi-Res TG curve shows that the samples are continuously dehydrated in a long temperature range, between room temperature and 600°C. The total mass loss relative to the initial mass is of about 29%. The DSC analysis coupled with TG and structural information, indicate that the exothermic processes about 355 and 447°C can be related to the nucleation process of the formation of tetragonal zirconia, with bulk crystallization at 447°C.
14 schema:genre article
15 schema:isAccessibleForFree false
16 schema:isPartOf N40e60f6a9ecf4e628bd9668055fc51ce
17 N744265bcfbcb46abb305ccf6f8c848c9
18 sg:journal.1294862
19 schema:keywords DSC analysis
20 Raman scattering
21 TG curves
22 Tg
23 UV-Vis spectroscopy
24 X-ray diffraction
25 ZrO2
26 amorphous materials
27 analysis
28 annealing temperature
29 behavior
30 bulk crystallization
31 calorimetry
32 crystallization
33 crystallization process
34 curves
35 dehydration
36 differential scanning calorimetry
37 diffraction
38 exothermic process
39 formation
40 high-resolution thermogravimetry
41 information
42 initial mass
43 long temperature range
44 loss
45 mass
46 mass loss
47 materials
48 monoclinic phase
49 nucleation process
50 phase
51 process
52 range
53 room temperature
54 samples
55 scanning calorimetry
56 scattering
57 sol-gel zirconia
58 spectroscopy
59 structural information
60 temperature
61 temperature range
62 tetragonal zirconia
63 thermogravimetry
64 total mass loss
65 typical behavior
66 zirconia
67 schema:name Dehydration and crystallization process in sol-gel zirconia
68 schema:pagination 755-761
69 schema:productId Nae1319f2aa52484e86b6f3834e0f8176
70 Nfb1dfc3e9e8b4d38a67ae5d406faa256
71 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040328823
72 https://doi.org/10.1023/b:jtan.0000032260.31955.6e
73 schema:sdDatePublished 2022-12-01T06:24
74 schema:sdLicense https://scigraph.springernature.com/explorer/license/
75 schema:sdPublisher N6b5435b904ac4b35a489053b191d9af0
76 schema:url https://doi.org/10.1023/b:jtan.0000032260.31955.6e
77 sgo:license sg:explorer/license/
78 sgo:sdDataset articles
79 rdf:type schema:ScholarlyArticle
80 N05545541cdd04aacba960f20e535de74 rdf:first sg:person.011766015543.76
81 rdf:rest rdf:nil
82 N40e60f6a9ecf4e628bd9668055fc51ce schema:issueNumber 3
83 rdf:type schema:PublicationIssue
84 N4f2fec47520d4275b840342067e596fd rdf:first sg:person.014722267613.11
85 rdf:rest N05545541cdd04aacba960f20e535de74
86 N6b5435b904ac4b35a489053b191d9af0 schema:name Springer Nature - SN SciGraph project
87 rdf:type schema:Organization
88 N744265bcfbcb46abb305ccf6f8c848c9 schema:volumeNumber 76
89 rdf:type schema:PublicationVolume
90 N9865674e560247ffbe0c7566a3456b11 rdf:first sg:person.0772163367.18
91 rdf:rest Ne270215e55484fb2a3710c0ba215e7ea
92 Nae1319f2aa52484e86b6f3834e0f8176 schema:name dimensions_id
93 schema:value pub.1040328823
94 rdf:type schema:PropertyValue
95 Ndebc203fa4a9448da95112afec2ba551 schema:affiliation grid-institutes:grid.7220.7
96 schema:familyName Gómez
97 schema:givenName R.
98 rdf:type schema:Person
99 Ne09972fa01fa4f60a8203946140f1d72 rdf:first Ndebc203fa4a9448da95112afec2ba551
100 rdf:rest Nf4c3103ab292436b9a0905416bc75bde
101 Ne270215e55484fb2a3710c0ba215e7ea rdf:first sg:person.01224263261.90
102 rdf:rest Ne09972fa01fa4f60a8203946140f1d72
103 Nf4c3103ab292436b9a0905416bc75bde rdf:first sg:person.07740754633.38
104 rdf:rest N4f2fec47520d4275b840342067e596fd
105 Nfb1dfc3e9e8b4d38a67ae5d406faa256 schema:name doi
106 schema:value 10.1023/b:jtan.0000032260.31955.6e
107 rdf:type schema:PropertyValue
108 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
109 schema:name Chemical Sciences
110 rdf:type schema:DefinedTerm
111 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
112 schema:name Physical Chemistry (incl. Structural)
113 rdf:type schema:DefinedTerm
114 sg:journal.1294862 schema:issn 1388-6150
115 1572-8943
116 schema:name Journal of Thermal Analysis and Calorimetry
117 schema:publisher Springer Nature
118 rdf:type schema:Periodical
119 sg:person.011766015543.76 schema:affiliation grid-institutes:grid.7220.7
120 schema:familyName Garcia
121 schema:givenName J.
122 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011766015543.76
123 rdf:type schema:Person
124 sg:person.01224263261.90 schema:affiliation grid-institutes:grid.7220.7
125 schema:familyName López
126 schema:givenName T.
127 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01224263261.90
128 rdf:type schema:Person
129 sg:person.014722267613.11 schema:affiliation grid-institutes:grid.7220.7
130 schema:familyName Moreno
131 schema:givenName A.
132 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014722267613.11
133 rdf:type schema:Person
134 sg:person.0772163367.18 schema:affiliation grid-institutes:grid.7220.7
135 schema:familyName Picquart
136 schema:givenName M.
137 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0772163367.18
138 rdf:type schema:Person
139 sg:person.07740754633.38 schema:affiliation grid-institutes:grid.419156.e
140 schema:familyName Torres
141 schema:givenName E.
142 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07740754633.38
143 rdf:type schema:Person
144 sg:pub.10.1007/bf00357343 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045091348
145 https://doi.org/10.1007/bf00357343
146 rdf:type schema:CreativeWork
147 sg:pub.10.1023/a:1014957215646 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019288868
148 https://doi.org/10.1023/a:1014957215646
149 rdf:type schema:CreativeWork
150 sg:pub.10.1023/a:1016031517430 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033429515
151 https://doi.org/10.1023/a:1016031517430
152 rdf:type schema:CreativeWork
153 sg:pub.10.1023/a:1016113800165 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019643246
154 https://doi.org/10.1023/a:1016113800165
155 rdf:type schema:CreativeWork
156 sg:pub.10.1023/a:1019972125701 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039231819
157 https://doi.org/10.1023/a:1019972125701
158 rdf:type schema:CreativeWork
159 sg:pub.10.1557/jmr.1988.0787 schema:sameAs https://app.dimensions.ai/details/publication/pub.1021637341
160 https://doi.org/10.1557/jmr.1988.0787
161 rdf:type schema:CreativeWork
162 sg:pub.10.1557/jmr.2001.0303 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033067410
163 https://doi.org/10.1557/jmr.2001.0303
164 rdf:type schema:CreativeWork
165 grid-institutes:grid.419156.e schema:alternateName Instituto Mexicano del Petróleo Eje Central, Lazaro Cardenas No. 152, C.P. 07730, México DF, México
166 schema:name Instituto Mexicano del Petróleo Eje Central, Lazaro Cardenas No. 152, C.P. 07730, México DF, México
167 rdf:type schema:Organization
168 grid-institutes:grid.7220.7 schema:alternateName Departamento de Física, Universidad Autónoma Metropolitana, Apto Postal 55 534, 09340, México DF, México
169 schema:name Departamento de Física, Universidad Autónoma Metropolitana, Apto Postal 55 534, 09340, México DF, México
170 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...