Thermal and photochemical behaviour of Zn(II) complexes of some cephalosporins View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2004-01

AUTHORS

A. A. M. Aly, A. H. Osman, N. Abo El-Maali, G. A. A. Al-Hazmi

ABSTRACT

Zn(II) complexes of some cephalosporin antibiotics namely cephalexin, cephapirin, cefamandole, cefuroxime, cefotaxime and ceftazidime were synthesised and characterized. The stoichiometrics and the mode of bonding of the complexes were deduced from their elemental analysis, IR and electronic spectroscopies. Thermal stabilities and the photochemical behaviour of the complexes were studied. The Zn(II) complex of cephalexin exhibited a high light sensitivity. The remaining Zn(II) complexes behaved similarly to their free antibiotics, upon irradiation. More... »

PAGES

159-168

References to SciGraph publications

  • 1995-08. Metal complexes of cephradine: Synthesis and equilibrium studies in MONATSHEFTE FÜR CHEMIE - CHEMICAL MONTHLY
  • 2003-05. Thermal stability of metronidazole drug and tablets in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 1991-03. Lewis acidity of coordinatively unsaturated bis(2-mercaptobenzothiazolato)nickel(II) towards azoles and morpholine in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2003-05. Thermal and dissolution kinetics of ampicillin drug and capsules in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 2000-12. Mixed Ligand Complexes of 5-arylazo-8-hydroxyquinoline and α-amino Acids with Co(II), Ni(II) and Cu(II) in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 1991-11. Thermal studies of some mixed complexes of Mn(II) with picrate and nitrogen donors in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1023/b:jtan.0000017338.52247.76

    DOI

    http://dx.doi.org/10.1023/b:jtan.0000017338.52247.76

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1003753491


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "about": [
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Inorganic Chemistry", 
            "type": "DefinedTerm"
          }, 
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Chemical Sciences", 
            "type": "DefinedTerm"
          }
        ], 
        "author": [
          {
            "affiliation": {
              "alternateName": "Assiut University", 
              "id": "https://www.grid.ac/institutes/grid.252487.e", 
              "name": [
                "Chemistry Department, Faculty of Science, Assiut University, Assiut, Egypt"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Aly", 
            "givenName": "A. A. M.", 
            "id": "sg:person.07435663271.68", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07435663271.68"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Assiut University", 
              "id": "https://www.grid.ac/institutes/grid.252487.e", 
              "name": [
                "Chemistry Department, Faculty of Science, Assiut University, Assiut, Egypt"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Osman", 
            "givenName": "A. H.", 
            "id": "sg:person.012320177412.00", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012320177412.00"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Assiut University", 
              "id": "https://www.grid.ac/institutes/grid.252487.e", 
              "name": [
                "Chemistry Department, Faculty of Science, Assiut University, Assiut, Egypt"
              ], 
              "type": "Organization"
            }, 
            "familyName": "El-Maali", 
            "givenName": "N. Abo", 
            "id": "sg:person.01051574671.34", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01051574671.34"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Assiut University", 
              "id": "https://www.grid.ac/institutes/grid.252487.e", 
              "name": [
                "Chemistry Department, Faculty of Science, Assiut University, Assiut, Egypt"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Al-Hazmi", 
            "givenName": "G. A. A.", 
            "id": "sg:person.01020220337.38", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01020220337.38"
            ], 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "sg:pub.10.1007/bf00811010", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1004770674", 
              "https://doi.org/10.1007/bf00811010"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1023/a:1024569414701", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1005671368", 
              "https://doi.org/10.1023/a:1024569414701"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf01912794", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1005923573", 
              "https://doi.org/10.1007/bf01912794"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf01912794", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1005923573", 
              "https://doi.org/10.1007/bf01912794"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1023/a:1026761007006", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1006669009", 
              "https://doi.org/10.1023/a:1026761007006"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf01913114", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1014925636", 
              "https://doi.org/10.1007/bf01913114"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf01913114", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1014925636", 
              "https://doi.org/10.1007/bf01913114"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1023/a:1024573515609", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1016904394", 
              "https://doi.org/10.1023/a:1024573515609"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/s0014-2999(02)01306-7", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1017024809"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1211/0022357991772556", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1029999532"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/s0009-2614(99)00309-7", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1039744482"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/s0039-9140(97)00089-1", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1043889284"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1128/aac.47.6.1882-1886.2003", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1044748668"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1080/00945710009351785", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1058289526"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1080/00945719809351663", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1058291816"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1080/00945719809351665", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1058291818"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1081/sim-120004445", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1058435645"
            ], 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "2004-01", 
        "datePublishedReg": "2004-01-01", 
        "description": "Zn(II) complexes of some cephalosporin antibiotics namely cephalexin, cephapirin, cefamandole, cefuroxime, cefotaxime and ceftazidime were synthesised and characterized. The stoichiometrics and the mode of bonding of the complexes were deduced from their elemental analysis, IR and electronic spectroscopies. Thermal stabilities and the photochemical behaviour of the complexes were studied. The Zn(II) complex of cephalexin exhibited a high light sensitivity. The remaining Zn(II) complexes behaved similarly to their free antibiotics, upon irradiation.", 
        "genre": "research_article", 
        "id": "sg:pub.10.1023/b:jtan.0000017338.52247.76", 
        "inLanguage": [
          "en"
        ], 
        "isAccessibleForFree": false, 
        "isPartOf": [
          {
            "id": "sg:journal.1294862", 
            "issn": [
              "1388-6150", 
              "1572-8943"
            ], 
            "name": "Journal of Thermal Analysis and Calorimetry", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "1", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "75"
          }
        ], 
        "name": "Thermal and photochemical behaviour of Zn(II) complexes of some cephalosporins", 
        "pagination": "159-168", 
        "productId": [
          {
            "name": "readcube_id", 
            "type": "PropertyValue", 
            "value": [
              "11e13985591b911787ac6df9b1ffecf4cb3a420fa74491a2e64ac3e559a41661"
            ]
          }, 
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1023/b:jtan.0000017338.52247.76"
            ]
          }, 
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1003753491"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1023/b:jtan.0000017338.52247.76", 
          "https://app.dimensions.ai/details/publication/pub.1003753491"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2019-04-10T14:07", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8660_00000503.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "http://link.springer.com/10.1023%2FB%3AJTAN.0000017338.52247.76"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1023/b:jtan.0000017338.52247.76'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1023/b:jtan.0000017338.52247.76'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1023/b:jtan.0000017338.52247.76'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1023/b:jtan.0000017338.52247.76'


     

    This table displays all metadata directly associated to this object as RDF triples.

    133 TRIPLES      21 PREDICATES      42 URIs      19 LITERALS      7 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1023/b:jtan.0000017338.52247.76 schema:about anzsrc-for:03
    2 anzsrc-for:0302
    3 schema:author Necec465c8935466cbd279aa80f508ece
    4 schema:citation sg:pub.10.1007/bf00811010
    5 sg:pub.10.1007/bf01912794
    6 sg:pub.10.1007/bf01913114
    7 sg:pub.10.1023/a:1024569414701
    8 sg:pub.10.1023/a:1024573515609
    9 sg:pub.10.1023/a:1026761007006
    10 https://doi.org/10.1016/s0009-2614(99)00309-7
    11 https://doi.org/10.1016/s0014-2999(02)01306-7
    12 https://doi.org/10.1016/s0039-9140(97)00089-1
    13 https://doi.org/10.1080/00945710009351785
    14 https://doi.org/10.1080/00945719809351663
    15 https://doi.org/10.1080/00945719809351665
    16 https://doi.org/10.1081/sim-120004445
    17 https://doi.org/10.1128/aac.47.6.1882-1886.2003
    18 https://doi.org/10.1211/0022357991772556
    19 schema:datePublished 2004-01
    20 schema:datePublishedReg 2004-01-01
    21 schema:description Zn(II) complexes of some cephalosporin antibiotics namely cephalexin, cephapirin, cefamandole, cefuroxime, cefotaxime and ceftazidime were synthesised and characterized. The stoichiometrics and the mode of bonding of the complexes were deduced from their elemental analysis, IR and electronic spectroscopies. Thermal stabilities and the photochemical behaviour of the complexes were studied. The Zn(II) complex of cephalexin exhibited a high light sensitivity. The remaining Zn(II) complexes behaved similarly to their free antibiotics, upon irradiation.
    22 schema:genre research_article
    23 schema:inLanguage en
    24 schema:isAccessibleForFree false
    25 schema:isPartOf N5328c0f9620c4d77a59d8d112153001b
    26 Nd468b427bee44d2e88b049d882a8a934
    27 sg:journal.1294862
    28 schema:name Thermal and photochemical behaviour of Zn(II) complexes of some cephalosporins
    29 schema:pagination 159-168
    30 schema:productId N1abb07ca59f6471dac59d22bc06536eb
    31 N69f6b2f6af3a4b2084367b6a3e5db612
    32 N71f947c792444db08f2efa12fbe6832b
    33 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003753491
    34 https://doi.org/10.1023/b:jtan.0000017338.52247.76
    35 schema:sdDatePublished 2019-04-10T14:07
    36 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    37 schema:sdPublisher Nb56bc1e958e74324b3f12734b71a0578
    38 schema:url http://link.springer.com/10.1023%2FB%3AJTAN.0000017338.52247.76
    39 sgo:license sg:explorer/license/
    40 sgo:sdDataset articles
    41 rdf:type schema:ScholarlyArticle
    42 N1abb07ca59f6471dac59d22bc06536eb schema:name readcube_id
    43 schema:value 11e13985591b911787ac6df9b1ffecf4cb3a420fa74491a2e64ac3e559a41661
    44 rdf:type schema:PropertyValue
    45 N5328c0f9620c4d77a59d8d112153001b schema:issueNumber 1
    46 rdf:type schema:PublicationIssue
    47 N69f6b2f6af3a4b2084367b6a3e5db612 schema:name dimensions_id
    48 schema:value pub.1003753491
    49 rdf:type schema:PropertyValue
    50 N71f947c792444db08f2efa12fbe6832b schema:name doi
    51 schema:value 10.1023/b:jtan.0000017338.52247.76
    52 rdf:type schema:PropertyValue
    53 N84ab3aa0706545d4b1aefa088f64f669 rdf:first sg:person.012320177412.00
    54 rdf:rest N8646025e33494f33bb5bc6c42fc5d2fa
    55 N8646025e33494f33bb5bc6c42fc5d2fa rdf:first sg:person.01051574671.34
    56 rdf:rest Ncfe87e52a8ed4924a474105e71f67f07
    57 Nb56bc1e958e74324b3f12734b71a0578 schema:name Springer Nature - SN SciGraph project
    58 rdf:type schema:Organization
    59 Ncfe87e52a8ed4924a474105e71f67f07 rdf:first sg:person.01020220337.38
    60 rdf:rest rdf:nil
    61 Nd468b427bee44d2e88b049d882a8a934 schema:volumeNumber 75
    62 rdf:type schema:PublicationVolume
    63 Necec465c8935466cbd279aa80f508ece rdf:first sg:person.07435663271.68
    64 rdf:rest N84ab3aa0706545d4b1aefa088f64f669
    65 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
    66 schema:name Chemical Sciences
    67 rdf:type schema:DefinedTerm
    68 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
    69 schema:name Inorganic Chemistry
    70 rdf:type schema:DefinedTerm
    71 sg:journal.1294862 schema:issn 1388-6150
    72 1572-8943
    73 schema:name Journal of Thermal Analysis and Calorimetry
    74 rdf:type schema:Periodical
    75 sg:person.01020220337.38 schema:affiliation https://www.grid.ac/institutes/grid.252487.e
    76 schema:familyName Al-Hazmi
    77 schema:givenName G. A. A.
    78 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01020220337.38
    79 rdf:type schema:Person
    80 sg:person.01051574671.34 schema:affiliation https://www.grid.ac/institutes/grid.252487.e
    81 schema:familyName El-Maali
    82 schema:givenName N. Abo
    83 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01051574671.34
    84 rdf:type schema:Person
    85 sg:person.012320177412.00 schema:affiliation https://www.grid.ac/institutes/grid.252487.e
    86 schema:familyName Osman
    87 schema:givenName A. H.
    88 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012320177412.00
    89 rdf:type schema:Person
    90 sg:person.07435663271.68 schema:affiliation https://www.grid.ac/institutes/grid.252487.e
    91 schema:familyName Aly
    92 schema:givenName A. A. M.
    93 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07435663271.68
    94 rdf:type schema:Person
    95 sg:pub.10.1007/bf00811010 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004770674
    96 https://doi.org/10.1007/bf00811010
    97 rdf:type schema:CreativeWork
    98 sg:pub.10.1007/bf01912794 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005923573
    99 https://doi.org/10.1007/bf01912794
    100 rdf:type schema:CreativeWork
    101 sg:pub.10.1007/bf01913114 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014925636
    102 https://doi.org/10.1007/bf01913114
    103 rdf:type schema:CreativeWork
    104 sg:pub.10.1023/a:1024569414701 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005671368
    105 https://doi.org/10.1023/a:1024569414701
    106 rdf:type schema:CreativeWork
    107 sg:pub.10.1023/a:1024573515609 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016904394
    108 https://doi.org/10.1023/a:1024573515609
    109 rdf:type schema:CreativeWork
    110 sg:pub.10.1023/a:1026761007006 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006669009
    111 https://doi.org/10.1023/a:1026761007006
    112 rdf:type schema:CreativeWork
    113 https://doi.org/10.1016/s0009-2614(99)00309-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039744482
    114 rdf:type schema:CreativeWork
    115 https://doi.org/10.1016/s0014-2999(02)01306-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017024809
    116 rdf:type schema:CreativeWork
    117 https://doi.org/10.1016/s0039-9140(97)00089-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043889284
    118 rdf:type schema:CreativeWork
    119 https://doi.org/10.1080/00945710009351785 schema:sameAs https://app.dimensions.ai/details/publication/pub.1058289526
    120 rdf:type schema:CreativeWork
    121 https://doi.org/10.1080/00945719809351663 schema:sameAs https://app.dimensions.ai/details/publication/pub.1058291816
    122 rdf:type schema:CreativeWork
    123 https://doi.org/10.1080/00945719809351665 schema:sameAs https://app.dimensions.ai/details/publication/pub.1058291818
    124 rdf:type schema:CreativeWork
    125 https://doi.org/10.1081/sim-120004445 schema:sameAs https://app.dimensions.ai/details/publication/pub.1058435645
    126 rdf:type schema:CreativeWork
    127 https://doi.org/10.1128/aac.47.6.1882-1886.2003 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044748668
    128 rdf:type schema:CreativeWork
    129 https://doi.org/10.1211/0022357991772556 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029999532
    130 rdf:type schema:CreativeWork
    131 https://www.grid.ac/institutes/grid.252487.e schema:alternateName Assiut University
    132 schema:name Chemistry Department, Faculty of Science, Assiut University, Assiut, Egypt
    133 rdf:type schema:Organization
     




    Preview window. Press ESC to close (or click here)


    ...