Synthesis and crystal structure of Na1.28Ni0.86Fe2(PO4)3 View Full Text


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Article Info

DATE

2004-10

AUTHORS

Mourad Hidouri, Besma Lajmi, Ahmed Driss, Mongi Ben Amara

ABSTRACT

A new monophosphate Na1.28Ni0.86Fe2(PO4)3 has been synthesized by a flux method and structurally characterized by single-crystal X-ray diffraction. The compound crystallizes in the orthorhombic space group Ibmm with the parameters: a = 6.438(2) Å, b = 10.515(3) Å, c = 13.166(3) Å, Z = 4. The structure is built up from Fe2O10 units of edge-sharing FeO6 octahedra, which are connected through the corners of MO6 (M = Ni2+ or a vacancy) octahedra and PO4 tetrahedra to form a three-dimensional framework analogous to that of α-CrPO4. Of the two crystallographically distinct Na+ sites contained in this structure, one is totally filled whereas the other is 28% occupied. More... »

PAGES

669-672

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/b:jocc.0000047641.37337.db

DOI

http://dx.doi.org/10.1023/b:jocc.0000047641.37337.db

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1012727435


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