Halocyclization of Substituted 2-(Alkenylthio)pyrimidin-6-ones View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2004-05

AUTHORS

N. Yu. Slivka, Yu. I. Gevaza, V. I. Staninets

ABSTRACT

Bromination and iodation of 2-(alkenylthio)pyrimidin-6-ones occur selectively and lead to formation of the corresponding 7-oxo-2,3-dihydrothiazolopyrimidinium or 8-oxo-3,4-dihydro-2H-pyrimidothiazinium salts. The selectivity of the reaction is controlled by the nature of the alkenyl substituent on the sulfur atom and the basicity of the N(1) and N(3) atoms of the pyrimidine ring. The iodation reaction rate increases as the basicity of the N(3) atom increases. More... »

PAGES

660-666

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/b:cohc.0000037323.22839.9f

DOI

http://dx.doi.org/10.1023/b:cohc.0000037323.22839.9f

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1044139014


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0202", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Atomic, Molecular, Nuclear, Particle and Plasma Physics", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/02", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "name": [
            "Lesya Ukrainka Volyn State University, 43025, Lutsk, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Slivka", 
        "givenName": "N. Yu.", 
        "id": "sg:person.013727230555.84", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013727230555.84"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.464621.3", 
          "name": [
            "Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 02094, Kiev"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Gevaza", 
        "givenName": "Yu. I.", 
        "id": "sg:person.016051701355.77", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016051701355.77"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.464621.3", 
          "name": [
            "Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 02094, Kiev"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Staninets", 
        "givenName": "V. I.", 
        "id": "sg:person.016653667731.06", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016653667731.06"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1080/00397919808005716", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017596297"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2004-05", 
    "datePublishedReg": "2004-05-01", 
    "description": "Bromination and iodation of 2-(alkenylthio)pyrimidin-6-ones occur selectively and lead to formation of the corresponding 7-oxo-2,3-dihydrothiazolopyrimidinium or 8-oxo-3,4-dihydro-2H-pyrimidothiazinium salts. The selectivity of the reaction is controlled by the nature of the alkenyl substituent on the sulfur atom and the basicity of the N(1) and N(3) atoms of the pyrimidine ring. The iodation reaction rate increases as the basicity of the N(3) atom increases.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1023/b:cohc.0000037323.22839.9f", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1356886", 
        "issn": [
          "0009-3122", 
          "1573-8353"
        ], 
        "name": "Chemistry of Heterocyclic Compounds", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "5", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "40"
      }
    ], 
    "name": "Halocyclization of Substituted 2-(Alkenylthio)pyrimidin-6-ones", 
    "pagination": "660-666", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "d23f9b995168d1a3f1398ae66a6248a50a0d30f49c54db6a915126d8ce6c9f43"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1023/b:cohc.0000037323.22839.9f"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1044139014"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1023/b:cohc.0000037323.22839.9f", 
      "https://app.dimensions.ai/details/publication/pub.1044139014"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T22:30", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8690_00000507.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1023%2FB%3ACOHC.0000037323.22839.9f"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1023/b:cohc.0000037323.22839.9f'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1023/b:cohc.0000037323.22839.9f'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1023/b:cohc.0000037323.22839.9f'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1023/b:cohc.0000037323.22839.9f'


 

This table displays all metadata directly associated to this object as RDF triples.

80 TRIPLES      21 PREDICATES      28 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1023/b:cohc.0000037323.22839.9f schema:about anzsrc-for:02
2 anzsrc-for:0202
3 schema:author N5e0a05fa2bb04f2d9bffde06c0d028be
4 schema:citation https://doi.org/10.1080/00397919808005716
5 schema:datePublished 2004-05
6 schema:datePublishedReg 2004-05-01
7 schema:description Bromination and iodation of 2-(alkenylthio)pyrimidin-6-ones occur selectively and lead to formation of the corresponding 7-oxo-2,3-dihydrothiazolopyrimidinium or 8-oxo-3,4-dihydro-2H-pyrimidothiazinium salts. The selectivity of the reaction is controlled by the nature of the alkenyl substituent on the sulfur atom and the basicity of the N(1) and N(3) atoms of the pyrimidine ring. The iodation reaction rate increases as the basicity of the N(3) atom increases.
8 schema:genre research_article
9 schema:inLanguage en
10 schema:isAccessibleForFree false
11 schema:isPartOf N07817b695f804cca8aa8243de18f51d4
12 N693b97d272ce410485a0f7aa7bbcc632
13 sg:journal.1356886
14 schema:name Halocyclization of Substituted 2-(Alkenylthio)pyrimidin-6-ones
15 schema:pagination 660-666
16 schema:productId N0f32829964b04de09acce7a69178aad6
17 N2a0d7832b02b484baf2360e58e465e4a
18 N73aeea66d9244d1a8231eca08547f031
19 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044139014
20 https://doi.org/10.1023/b:cohc.0000037323.22839.9f
21 schema:sdDatePublished 2019-04-10T22:30
22 schema:sdLicense https://scigraph.springernature.com/explorer/license/
23 schema:sdPublisher Ne699d29e87f34de4a56ca18da5f49d40
24 schema:url http://link.springer.com/10.1023%2FB%3ACOHC.0000037323.22839.9f
25 sgo:license sg:explorer/license/
26 sgo:sdDataset articles
27 rdf:type schema:ScholarlyArticle
28 N07817b695f804cca8aa8243de18f51d4 schema:volumeNumber 40
29 rdf:type schema:PublicationVolume
30 N0f32829964b04de09acce7a69178aad6 schema:name dimensions_id
31 schema:value pub.1044139014
32 rdf:type schema:PropertyValue
33 N2a0d7832b02b484baf2360e58e465e4a schema:name readcube_id
34 schema:value d23f9b995168d1a3f1398ae66a6248a50a0d30f49c54db6a915126d8ce6c9f43
35 rdf:type schema:PropertyValue
36 N5e0a05fa2bb04f2d9bffde06c0d028be rdf:first sg:person.013727230555.84
37 rdf:rest N9d570115fab5433c9aa2e0cd6bc3efee
38 N693b97d272ce410485a0f7aa7bbcc632 schema:issueNumber 5
39 rdf:type schema:PublicationIssue
40 N73aeea66d9244d1a8231eca08547f031 schema:name doi
41 schema:value 10.1023/b:cohc.0000037323.22839.9f
42 rdf:type schema:PropertyValue
43 N9d570115fab5433c9aa2e0cd6bc3efee rdf:first sg:person.016051701355.77
44 rdf:rest Nc90a597efce14222877a57c3db0a3210
45 Nc90a597efce14222877a57c3db0a3210 rdf:first sg:person.016653667731.06
46 rdf:rest rdf:nil
47 Ndf97a8692a6343ab9393fdf30794437f schema:name Lesya Ukrainka Volyn State University, 43025, Lutsk, Ukraine
48 rdf:type schema:Organization
49 Ne699d29e87f34de4a56ca18da5f49d40 schema:name Springer Nature - SN SciGraph project
50 rdf:type schema:Organization
51 anzsrc-for:02 schema:inDefinedTermSet anzsrc-for:
52 schema:name Physical Sciences
53 rdf:type schema:DefinedTerm
54 anzsrc-for:0202 schema:inDefinedTermSet anzsrc-for:
55 schema:name Atomic, Molecular, Nuclear, Particle and Plasma Physics
56 rdf:type schema:DefinedTerm
57 sg:journal.1356886 schema:issn 0009-3122
58 1573-8353
59 schema:name Chemistry of Heterocyclic Compounds
60 rdf:type schema:Periodical
61 sg:person.013727230555.84 schema:affiliation Ndf97a8692a6343ab9393fdf30794437f
62 schema:familyName Slivka
63 schema:givenName N. Yu.
64 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013727230555.84
65 rdf:type schema:Person
66 sg:person.016051701355.77 schema:affiliation https://www.grid.ac/institutes/grid.464621.3
67 schema:familyName Gevaza
68 schema:givenName Yu. I.
69 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016051701355.77
70 rdf:type schema:Person
71 sg:person.016653667731.06 schema:affiliation https://www.grid.ac/institutes/grid.464621.3
72 schema:familyName Staninets
73 schema:givenName V. I.
74 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016653667731.06
75 rdf:type schema:Person
76 https://doi.org/10.1080/00397919808005716 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017596297
77 rdf:type schema:CreativeWork
78 https://www.grid.ac/institutes/grid.464621.3 schema:alternateName Institute of Organic Chemistry
79 schema:name Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 02094, Kiev
80 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...