Halocyclization of Substituted 2-(Alkenylthio)pyrimidin-6-ones View Full Text


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Article Info

DATE

2004-05

AUTHORS

N. Yu. Slivka, Yu. I. Gevaza, V. I. Staninets

ABSTRACT

Bromination and iodation of 2-(alkenylthio)pyrimidin-6-ones occur selectively and lead to formation of the corresponding 7-oxo-2,3-dihydrothiazolopyrimidinium or 8-oxo-3,4-dihydro-2H-pyrimidothiazinium salts. The selectivity of the reaction is controlled by the nature of the alkenyl substituent on the sulfur atom and the basicity of the N(1) and N(3) atoms of the pyrimidine ring. The iodation reaction rate increases as the basicity of the N(3) atom increases. More... »

PAGES

660-666

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/b:cohc.0000037323.22839.9f

DOI

http://dx.doi.org/10.1023/b:cohc.0000037323.22839.9f

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1044139014


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