Heterocyclization Reactions of 2-(2-Propynylthio)-4(1H)-quinazolinone Derivatives when Treated with Electrophilic and Nucleophilic Reagents View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2003-08

AUTHORS

Yu. L. Zborovskii, V. V. Orysyk, A. A. Dobosh, V. I. Staninets, V. V. Pirozhenko, A. N. Chernega

ABSTRACT

Reaction of the potassium salt of 2-thioquinazolin-4-one with propargyl halides leads to formation of 2-propargylthioquinazolin-4-one derivatives, which undergo heterocyclization when they are treated with electrophilic or nucleophilic reagents and, depending on the nature of the cyclization agent, leads to formation of tricyclic systems with angular or linear structure.

PAGES

1099-1106

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/b:cohc.0000003532.58469.cc

DOI

http://dx.doi.org/10.1023/b:cohc.0000003532.58469.cc

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1004138425


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0305", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Organic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.464621.3", 
          "name": [
            "National Academy of Sciences of Ukraine, Institute of Organic Chemistry, 02094, Kiev"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zborovskii", 
        "givenName": "Yu. L.", 
        "id": "sg:person.010120771367.48", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010120771367.48"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Uzhhorod National University", 
          "id": "https://www.grid.ac/institutes/grid.77512.36", 
          "name": [
            "Uzhgorod National University, 88000, Uzhgorod, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Orysyk", 
        "givenName": "V. V.", 
        "id": "sg:person.015771447007.77", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015771447007.77"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Uzhhorod National University", 
          "id": "https://www.grid.ac/institutes/grid.77512.36", 
          "name": [
            "Uzhgorod National University, 88000, Uzhgorod, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Dobosh", 
        "givenName": "A. A.", 
        "id": "sg:person.013465126233.59", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013465126233.59"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.464621.3", 
          "name": [
            "National Academy of Sciences of Ukraine, Institute of Organic Chemistry, 02094, Kiev"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Staninets", 
        "givenName": "V. I.", 
        "id": "sg:person.016653667731.06", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016653667731.06"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.464621.3", 
          "name": [
            "National Academy of Sciences of Ukraine, Institute of Organic Chemistry, 02094, Kiev"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Pirozhenko", 
        "givenName": "V. V.", 
        "id": "sg:person.012241771317.04", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012241771317.04"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.464621.3", 
          "name": [
            "National Academy of Sciences of Ukraine, Institute of Organic Chemistry, 02094, Kiev"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Chernega", 
        "givenName": "A. N.", 
        "id": "sg:person.013701677755.94", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013701677755.94"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "2003-08", 
    "datePublishedReg": "2003-08-01", 
    "description": "Reaction of the potassium salt of 2-thioquinazolin-4-one with propargyl halides leads to formation of 2-propargylthioquinazolin-4-one derivatives, which undergo heterocyclization when they are treated with electrophilic or nucleophilic reagents and, depending on the nature of the cyclization agent, leads to formation of tricyclic systems with angular or linear structure.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1023/b:cohc.0000003532.58469.cc", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1356886", 
        "issn": [
          "0009-3122", 
          "1573-8353"
        ], 
        "name": "Chemistry of Heterocyclic Compounds", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "8", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "39"
      }
    ], 
    "name": "Heterocyclization Reactions of 2-(2-Propynylthio)-4(1H)-quinazolinone Derivatives when Treated with Electrophilic and Nucleophilic Reagents", 
    "pagination": "1099-1106", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "13b865456f154cec4fdc0475f0640e07b81ef61ab5e79118d18aebfbdc643430"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1023/b:cohc.0000003532.58469.cc"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1004138425"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1023/b:cohc.0000003532.58469.cc", 
      "https://app.dimensions.ai/details/publication/pub.1004138425"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T21:34", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8687_00000503.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1023%2FB%3ACOHC.0000003532.58469.cc"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1023/b:cohc.0000003532.58469.cc'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1023/b:cohc.0000003532.58469.cc'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1023/b:cohc.0000003532.58469.cc'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1023/b:cohc.0000003532.58469.cc'


 

This table displays all metadata directly associated to this object as RDF triples.

99 TRIPLES      20 PREDICATES      27 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1023/b:cohc.0000003532.58469.cc schema:about anzsrc-for:03
2 anzsrc-for:0305
3 schema:author N645f64849cf1454889dcd97b7595cee5
4 schema:datePublished 2003-08
5 schema:datePublishedReg 2003-08-01
6 schema:description Reaction of the potassium salt of 2-thioquinazolin-4-one with propargyl halides leads to formation of 2-propargylthioquinazolin-4-one derivatives, which undergo heterocyclization when they are treated with electrophilic or nucleophilic reagents and, depending on the nature of the cyclization agent, leads to formation of tricyclic systems with angular or linear structure.
7 schema:genre research_article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf N0f6a44ccb72c488d9b0de1f81bc43c93
11 Nac659cf4407a42e384e09d6b598317fb
12 sg:journal.1356886
13 schema:name Heterocyclization Reactions of 2-(2-Propynylthio)-4(1H)-quinazolinone Derivatives when Treated with Electrophilic and Nucleophilic Reagents
14 schema:pagination 1099-1106
15 schema:productId N3da9a5ba1e934b81b8100c337230a7bc
16 N9d412075ba394e27b2c89d9d7ab8dc24
17 Ne8191d0ed1f64f2cb1e34da438273496
18 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004138425
19 https://doi.org/10.1023/b:cohc.0000003532.58469.cc
20 schema:sdDatePublished 2019-04-10T21:34
21 schema:sdLicense https://scigraph.springernature.com/explorer/license/
22 schema:sdPublisher Nc452e9e8985049bba8ada2dbc27097c6
23 schema:url http://link.springer.com/10.1023%2FB%3ACOHC.0000003532.58469.cc
24 sgo:license sg:explorer/license/
25 sgo:sdDataset articles
26 rdf:type schema:ScholarlyArticle
27 N0f6a44ccb72c488d9b0de1f81bc43c93 schema:volumeNumber 39
28 rdf:type schema:PublicationVolume
29 N3da9a5ba1e934b81b8100c337230a7bc schema:name dimensions_id
30 schema:value pub.1004138425
31 rdf:type schema:PropertyValue
32 N645f64849cf1454889dcd97b7595cee5 rdf:first sg:person.010120771367.48
33 rdf:rest Nad43e91088ec4b0eb3f56f0401cea8ba
34 N84a9adae76f740898d1929f904b8bd39 rdf:first sg:person.013465126233.59
35 rdf:rest Nc4528ef8211744958e4625fe11f2ba09
36 N99c05b1ffd0f45709cbbd20ffbd2938c rdf:first sg:person.012241771317.04
37 rdf:rest N9ae96dd334fa49349b10db00f5194dff
38 N9ae96dd334fa49349b10db00f5194dff rdf:first sg:person.013701677755.94
39 rdf:rest rdf:nil
40 N9d412075ba394e27b2c89d9d7ab8dc24 schema:name readcube_id
41 schema:value 13b865456f154cec4fdc0475f0640e07b81ef61ab5e79118d18aebfbdc643430
42 rdf:type schema:PropertyValue
43 Nac659cf4407a42e384e09d6b598317fb schema:issueNumber 8
44 rdf:type schema:PublicationIssue
45 Nad43e91088ec4b0eb3f56f0401cea8ba rdf:first sg:person.015771447007.77
46 rdf:rest N84a9adae76f740898d1929f904b8bd39
47 Nc4528ef8211744958e4625fe11f2ba09 rdf:first sg:person.016653667731.06
48 rdf:rest N99c05b1ffd0f45709cbbd20ffbd2938c
49 Nc452e9e8985049bba8ada2dbc27097c6 schema:name Springer Nature - SN SciGraph project
50 rdf:type schema:Organization
51 Ne8191d0ed1f64f2cb1e34da438273496 schema:name doi
52 schema:value 10.1023/b:cohc.0000003532.58469.cc
53 rdf:type schema:PropertyValue
54 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
55 schema:name Chemical Sciences
56 rdf:type schema:DefinedTerm
57 anzsrc-for:0305 schema:inDefinedTermSet anzsrc-for:
58 schema:name Organic Chemistry
59 rdf:type schema:DefinedTerm
60 sg:journal.1356886 schema:issn 0009-3122
61 1573-8353
62 schema:name Chemistry of Heterocyclic Compounds
63 rdf:type schema:Periodical
64 sg:person.010120771367.48 schema:affiliation https://www.grid.ac/institutes/grid.464621.3
65 schema:familyName Zborovskii
66 schema:givenName Yu. L.
67 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010120771367.48
68 rdf:type schema:Person
69 sg:person.012241771317.04 schema:affiliation https://www.grid.ac/institutes/grid.464621.3
70 schema:familyName Pirozhenko
71 schema:givenName V. V.
72 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012241771317.04
73 rdf:type schema:Person
74 sg:person.013465126233.59 schema:affiliation https://www.grid.ac/institutes/grid.77512.36
75 schema:familyName Dobosh
76 schema:givenName A. A.
77 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013465126233.59
78 rdf:type schema:Person
79 sg:person.013701677755.94 schema:affiliation https://www.grid.ac/institutes/grid.464621.3
80 schema:familyName Chernega
81 schema:givenName A. N.
82 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013701677755.94
83 rdf:type schema:Person
84 sg:person.015771447007.77 schema:affiliation https://www.grid.ac/institutes/grid.77512.36
85 schema:familyName Orysyk
86 schema:givenName V. V.
87 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015771447007.77
88 rdf:type schema:Person
89 sg:person.016653667731.06 schema:affiliation https://www.grid.ac/institutes/grid.464621.3
90 schema:familyName Staninets
91 schema:givenName V. I.
92 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016653667731.06
93 rdf:type schema:Person
94 https://www.grid.ac/institutes/grid.464621.3 schema:alternateName Institute of Organic Chemistry
95 schema:name National Academy of Sciences of Ukraine, Institute of Organic Chemistry, 02094, Kiev
96 rdf:type schema:Organization
97 https://www.grid.ac/institutes/grid.77512.36 schema:alternateName Uzhhorod National University
98 schema:name Uzhgorod National University, 88000, Uzhgorod, Ukraine
99 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...