Ortho-metalation and carboxylate coordination in the reaction between the dipotassium salt of phthalic acid and Cp*Ir(PMe3)Cl2: X-ray diffraction structure of ... View Full Text


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Article Info

DATE

2003-12

AUTHORS

William H. Watson, Ming-Jaw Don, Michael G. Richmond

ABSTRACT

The cyclopentadienyl complex Cp*Ir(PMe3)Cl2 reacts with the dipotassium salt of phthalic acid in the presence of AgPF6 via chloride substitution to give the ortho-metalated compound Cp*Ir(PMe3)[C6H3(CO2)(CO2H)]. This new compound has been isolated by recrystallization and has been characterized in solution by 1H and 13C NMR spectroscopies, and the solid-state structure has been verified by X-ray crystallography. Cp*Ir(PMe3)[C6H3(CO2)(CO2H)] crystallizes in the monoclinic space group P21/c, a = 9.1010(6) Å, b = 16.715(1) Å, c = 14.3965(9) Å, β = 108.24(1)°, V = 2080.0(2) Å3, Z = 4, and dcalc = 1.813 mg/m3; R = 0.0276, Rw = 0.0810 for 2730 reflections with I > 2σ(I). Coordination of the benzene ring to the iridium center via one of the carboxylate groups and ortho-metalation of the C–H moiety that was α to the iridium-bound carboxylate group is confirmed. More... »

PAGES

963-968

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1027442117715

DOI

http://dx.doi.org/10.1023/a:1027442117715

DIMENSIONS

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