Rational Combination of the Dissolution of Some Inorganic Compounds of Rare-Earth Elements with the Determination of Chemical Forms of Major ... View Full Text


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Article Info

DATE

2003-11

AUTHORS

V. P. Antonovich, N. A. Chivireva, I. V. Stoyanova, V. F. Zinchenko, N. P. Efryushina, O. N. Lasovskaya, N. N. Golik

ABSTRACT

It was found that the major constituents (F– and S2–) in fluorides, sulfides, and sulfofluorides of rare-earth elements, and europium(II) in europium fluoride, can be determined titrimetrically. Peculiarities of the decomposition and analysis of initial samples of these compounds and samples after high-temperature treatment in vacuum were considered. The analytical procedures are based on the combination of the decomposition of the test materials using solutions of iodine (determination of S2–), boric acid (determination of F–), and vanadium(V) salts (determination of europium(II) salts) and the final titration of excess reagents that selectively reacted with a chemical form of the analyte. Potentiometry with an ion-selective electrode was also used in the determination of fluoride ions. The total concentration of rare-earth elements was determined by chelatometry. More... »

PAGES

1042-1048

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1023/a:1027377104668

DOI

http://dx.doi.org/10.1023/a:1027377104668

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1019662644


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